公开(公告)号：US20100167160A1

公开(公告)日：2010-07-01

申请号：US12594961

申请日：2008-02-26

申请人： Tomoyuki Takane ,  Hiroshi Kato ,  Hiroyoshi Fujimoto ,  Masahiko Ishikawa

发明人： Tomoyuki Takane ,  Hiroshi Kato ,  Hiroyoshi Fujimoto ,  Masahiko Ishikawa

IPC分类号： H01M8/10

CPC分类号： H01M4/926 ,  H01M4/921 ,  H01M8/0289 ,  H01M8/1039 ,  H01M8/1048 ,  H01M8/1051 ,  H01M8/1053 ,  H01M8/1067

摘要： The durability of a solid polymer electrolyte fuel cell can be enhanced by inhibiting deterioration of a polymer electrolyte membrane of a solid polymer electrolyte fuel cell without impairing power generation performance. The production process of a polymer electrolyte membrane for a solid polymer electrolyte fuel cell of the present invention is characterized by preparing a solution or dispersion of an alkoxide of a transition element or a rare earth element having a catalytic ability that decomposes peroxides, and (1) preparing a solution of a polymer electrolyte, uniformly mixing the solution or dispersion of the alkoxide with the solution of the polymer electrolyte, and forming a polymer electrolyte membrane, in which the transition metal or the rare earth metal is uniformly dispersed, from the mixed solution, or (2) preparing a polymer electrolyte membrane for a solid polymer electrolyte fuel cell, uniformly permeating the solution or dispersion of the alkoxide into the polymer electrolyte membrane, and forming a polymer electrolyte membrane in which the transition element or rare earth element is uniformly dispersed by hydrolyzing and condensing the alkoxide.

摘要翻译： 固体聚合物电解质燃料电池的耐久性可以通过抑制固体聚合物电解质燃料电池的聚合物电解质膜的劣化而不损害发电性能来提高。 本发明的固体高分子电解质型燃料电池用高分子电解质膜的制造方法的特征在于，制备具有分解过氧化物的催化能力的过渡元素或稀土元素的醇盐的溶液或分散液，（1 ）制备聚合物电解质溶液，均匀混合醇盐溶液或分散液与聚合物电解质溶液，并从混合物中形成过渡金属或稀土金属均匀分散的聚合物电解质膜 溶液或（2）制备用于固体聚合物电解质燃料电池的聚合物电解质膜，均匀地将醇盐的溶液或分散体渗透到聚合物电解质膜中，并且形成其中过渡元素或稀土元素为 通过水解和缩合醇盐来均匀分散。

公开(公告)号：US20100203419A1

公开(公告)日：2010-08-12

申请号：US12600889

申请日：2008-05-20

申请人： Masahiko Ishikawa ,  Tomoyuki Takane

发明人： Masahiko Ishikawa ,  Tomoyuki Takane

IPC分类号： H01M8/10

CPC分类号： H01M8/106 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1062 ,  H01M8/1067 ,  H01M8/109 ,  Y02P70/56

摘要： The invention provides a method for fabricating a reinforced polymer electrolyte membrane having greatly enhanced durability against a dry/wet cycle or freeze/defreeze cycle. In a method for fabricating a reinforced polymer electrolyte membrane according to the present invention, (1) a polymer electrolyte precursor is caused to infiltrate into a sheet-like porous reinforcing member, in the absence of a solvent, at a temperature higher than the melting point of the sheet-like porous reinforcing member, or (2) the polymer electrolyte precursor is first caused to infiltrate into the sheet-like porous reinforcing member, in the absence of a solvent, at a first temperature lower than the melting point of the sheet-like porous reinforcing member, and then heat-treated at a second temperature higher than the melting point of the sheet-like porous reinforcing member; thereafter, the polymer electrolyte precursor is transformed into a polymer electrolyte by hydrolyzing the polymer electrolyte precursor.

摘要翻译： 本发明提供一种制造强化聚合物电解质膜的方法，其具有大大增强的耐干湿循环或冷冻/解冻循环的耐久性。 在本发明的增强高分子电解质膜的制造方法中，（1）使高分子电解质前体在不存在溶剂的情况下，在高于熔融温度的温度下渗入片状多孔质增强部件 或（2）首先使聚合物电解质前体在不存在溶剂的情况下渗透到片状多孔质增强部件中，所述第一温度低于所述片状多孔质增强部件的熔点 片状多孔质增强部件，然后在高于片状多孔质增强部件的熔点的第二温度下热处理; 此后，通过水解聚合物电解质前体将聚合物电解质前体转变成聚合物电解质。

公开(公告)号：US20110070521A1

公开(公告)日：2011-03-24

申请号：US12672131

申请日：2008-08-08

申请人： Masahiko Ishikawa ,  Tomoyuki Takane

发明人： Masahiko Ishikawa ,  Tomoyuki Takane

IPC分类号： H01M8/10

CPC分类号： H01M8/1016 ,  H01M8/0289 ,  H01M8/0293 ,  H01M8/0637 ,  H01M2300/0094 ,  Y02E60/521 ,  Y02E60/566

摘要： The invention provides a solid polymer fuel cell whose operational stability over time has been enhanced. A reinforced solid polymer electrolyte composite membrane for a solid polymer fuel cell according to the present invention comprises two or more polymer electrolyte membranes and one or more layers of a sheet-like porous reinforcing member, wherein the polymer electrolyte membranes provide both the upper and lower surfaces of the composite membrane, and pores in the sheet-like porous reinforcing member are substantially filled with the electrolyte from the polymer electrolyte membranes, and wherein the sheet-like porous reinforcing member contains a peroxide decomposition catalyst.

摘要翻译： 本发明提供了一种固体聚合物燃料电池，其操作稳定性随时间增加。 本发明的固体高分子型燃料电池用强化固体高分子电解质复合膜含有2种以上的高分子电解质膜和1层以上的片状多孔质增强材料，其中，上述聚合物电解质膜 复合膜的表面和片状多孔质增强构件中的孔基本上由聚合物电解质膜填充电解质，并且其中片状多孔增强构件含有过氧化物分解催化剂。

公开(公告)号：US08906573B2

公开(公告)日：2014-12-09

申请号：US12672131

申请日：2008-08-08

申请人： Masahiko Ishikawa ,  Tomoyuki Takane

发明人： Masahiko Ishikawa ,  Tomoyuki Takane

IPC分类号： H01M8/10 ,  H01M8/02 ,  H01M8/06

CPC分类号： H01M8/1016 ,  H01M8/0289 ,  H01M8/0293 ,  H01M8/0637 ,  H01M2300/0094 ,  Y02E60/521 ,  Y02E60/566

摘要： The invention provides a solid polymer fuel cell whose operational stability over time has been enhanced. A reinforced solid polymer electrolyte composite membrane for a solid polymer fuel cell according to the present invention comprises two or more polymer electrolyte membranes and one or more layers of a sheet-like porous reinforcing member, wherein the polymer electrolyte membranes provide both the upper and lower surfaces of the composite membrane, and pores in the sheet-like porous reinforcing member are substantially filled with the electrolyte from the polymer electrolyte membranes, and wherein the sheet-like porous reinforcing member contains a peroxide decomposition catalyst.

摘要翻译： 本发明提供了一种固体聚合物燃料电池，其操作稳定性随时间增加。 本发明的固体高分子型燃料电池用强化固体高分子电解质复合膜含有2种以上的高分子电解质膜和1层以上的片状多孔质增强材料，其中，上述聚合物电解质膜 复合膜的表面和片状多孔质增强构件中的孔基本上由聚合物电解质膜填充电解质，并且其中片状多孔增强构件含有过氧化物分解催化剂。

公开(公告)号：US09711815B2

公开(公告)日：2017-07-18

申请号：US13822763

申请日：2011-10-05

申请人： Tomoyuki Takane ,  Naoko Matsuura

发明人： Tomoyuki Takane ,  Naoko Matsuura

IPC分类号： H01M8/10 ,  H01M8/1004 ,  H01M8/02 ,  H01M8/1051 ,  H01M8/1018 ,  H01M8/1023 ,  H01M8/1039

CPC分类号： H01M8/1004 ,  H01M8/02 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1051 ,  H01M2008/1095

摘要： An object of the invention is to provide a fuel cell having improved long-term durability.The patent provides a fuel cell comprising a peroxide decomposition catalyst immobilized on a support, wherein the fuel cell is constituted of a membrane electrode assembly comprising a polyelectrolyte membrane, electrode layers placed on both the sides of the electrolyte membrane, and gas diffusion layers placed on the side opposite to the electrolyte membrane of the electrode layers, a gas sealing material placed surrounding the membrane electrode assembly, and separators sandwiching the foregoing.

公开(公告)号：US20130330649A1

公开(公告)日：2013-12-12

申请号：US13822763

申请日：2011-10-05

申请人： Tomoyuki Takane ,  Naoko Matsuura

发明人： Tomoyuki Takane ,  Naoko Matsuura

IPC分类号： H01M8/10

CPC分类号： H01M8/1004 ,  H01M8/02 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1051 ,  H01M2008/1095

摘要： An object of the invention is to provide a fuel cell having improved long-term durability.The patent provides a fuel cell comprising a peroxide decomposition catalyst immobilized on a support, wherein the fuel cell is constituted of a membrane electrode assembly comprising a polyelectrolyte membrane, electrode layers placed on both the sides of the electrolyte membrane, and gas diffusion layers placed on the side opposite to the electrolyte membrane of the electrode layers, a gas sealing material placed surrounding the membrane electrode assembly, and separators sandwiching the foregoing.

摘要翻译： 本发明的目的是提供具有改进的长期耐久性的燃料电池。 该专利提供了一种燃料电池，其包含固定在载体上的过氧化物分解催化剂，其中燃料电池由包含聚电解质膜的膜电极组件，放置在电解质膜两侧的电极层和放置在电解质膜上的气体扩散层构成 与电极层的电解质膜相反的一侧，围绕膜电极组件放置的气体密封材料和夹着上述的隔板。

公开(公告)号：US20120034548A1

公开(公告)日：2012-02-09

申请号：US13265088

申请日：2010-04-27

申请人： Yozo Okuyama ,  Manabu Sugino ,  Takanori Oku ,  Isao Ehama ,  Kazufumi Kodama ,  Hiroshi Kato ,  Haruo Nomi ,  Takafumi Namba ,  Tomoyuki Takane

发明人： Yozo Okuyama ,  Manabu Sugino ,  Takanori Oku ,  Isao Ehama ,  Kazufumi Kodama ,  Hiroshi Kato ,  Haruo Nomi ,  Takafumi Namba ,  Tomoyuki Takane

IPC分类号： H01M4/86

CPC分类号： H01M4/8807 ,  H01M4/8605 ,  H01M8/0234 ,  H01M8/0241 ,  H01M8/1007

摘要： To provide a means of further improving the cell's start-up capability (below-freezing-point-start-up capability) in a low temperature environment in the gas diffusion layer used in the fuel cell. It is a gas diffusion layer for fuel cell having a pore volume of micropores of 2.0×10−4 cm3/cm2 or higher.

摘要翻译： 提供在燃料电池中使用的气体扩散层的低温环境中进一步提高电池的起动能力（低于起点启动能力）的手段。 作为微孔的孔体积为2.0×10 -4 cm 3 / cm 2以上的燃料电池用气体扩散层。