公开(公告)号：US4839241A

公开(公告)日：1989-06-13

申请号：US183779

申请日：1988-04-20

申请人： Masaki Abe ,  Yukimitsu Shiohara ,  Takeshi Adaniya ,  Hiroshi Naemura

发明人： Masaki Abe ,  Yukimitsu Shiohara ,  Takeshi Adaniya ,  Hiroshi Naemura

IPC分类号： B32B15/01 ,  C25D15/02

CPC分类号： C25D15/02 ,  B32B15/013 ,  Y10S428/935 ,  Y10T428/12799

摘要： A composite zinc-silica electro-galvanized steel sheet excellent in corrosion resistance, having on at least one surface thereof a zinciferous plating layer, preferably in an amount of from 5 to 100 g/m.sup.2 per side thereof, into which silica particles are dispersed. The above-mentioned plating layer consists essentially of:silica particles: from 0.1 to 20 wt. %,nitrogen compounds: from 0.0005 to 0.5 wt. % as converted into nitrogen,and the balance being zinc and incidental impurities.The above-mentioned plating layer further additionally contains as required at least one element selected from the group consisting of:iron: from 2 to 80 wt. %,nickel: from 2 to 25 wt. %,cobalt: from 0.1 to 5 wt. %, andchromium: from 0.5 to 20 wt. %.The total amount of the above-mentioned at least one element thus additionally contained is limited to up to 80 wt. %.

公开(公告)号：US5186812A

公开(公告)日：1993-02-16

申请号：US654065

申请日：1991-02-11

申请人： Yukimitsu Shiohara ,  Masaki Abe

发明人： Yukimitsu Shiohara ,  Masaki Abe

IPC分类号： C25D15/02

CPC分类号： C25D15/02

摘要： A method for manufacturing a zinc-silica composite electroplated steel sheet, which comprises the steps of: adding, to a zinciferous acidic electroplating solution containing silica particles and nitric acid ions, a complexing agent, which is capable of forming a stable complex with zinc, in an amount within a range of from 0.001 to 10 moles per liter of the electroplating solution, or a pH buffer, which has a pH buffering effect in a solution having a pH value within a range of from 5 to 12, in an amount within a range of from 1 to 50 g per liter of the electroplating solution; and electroplating a steel sheet in the resultant electroplating solution containing the complexing agent of the pH buffer in addition to the silica particles and the nitric acid ions, to form, on the surface of the steel sheet, a zinciferous plating layer in which silica particles are uniformly dispersed.

公开(公告)号：US5203986A

公开(公告)日：1993-04-20

申请号：US657665

申请日：1991-02-19

申请人： Yukimitsu Shiohara ,  Masaki Abe

发明人： Yukimitsu Shiohara ,  Masaki Abe

IPC分类号： C25D3/22

CPC分类号： C25D3/22

摘要： A method for manufacturing an electrogalvanized steel sheet excellent in spot weldability, which comprises the steps of: adding, into an acidic electrogalvanizing solution containing an oxidizer, a complexing agent, which is capable of forming a stable complex with zinc, in an amount within a range of from 0.001 to 10 moles per liter of the electrogalvanizing solution, or a pH buffer, which has a pH buffering effect in a solution having a pH value within a range of from 5 to 12, in an amount within a range of from 1 to 50 g per liter of the electrogalvanizing solution; and electrogalvanizing a steel sheet in the resultant acidic electrogalvanizing solution containing the complexing agent or the pH buffer in addition to the oxidizer, to form a galvanizing layer comprising zinc oxide or zinc hydroxide on the surface of the steel sheet.

公开(公告)号：US5202012A

公开(公告)日：1993-04-13

申请号：US835202

申请日：1992-02-13

申请人： Masaki Abe ,  Yukimitsu Shiohara ,  Masaru Sagiyama

发明人： Masaki Abe ,  Yukimitsu Shiohara ,  Masaru Sagiyama

IPC分类号： C22C38/00 ,  C25D3/22 ,  C25D5/26 ,  C25D15/02

CPC分类号： C25D15/02

摘要： A method for manufacturing a zinciferous electroplated steel sheet excellent in press-formability, which comprises the steps of: electroplating a steel sheet in a zinciferous acidic electroplating solution, which contains nitric acid ions or nitrous acid ions in an amount within a range of from 0.1 to 50 g per liter of the electroplating solution, and oxide particles of a metal or a semimetal, uniformly dispersible into the electroplating solution, in an amount within a range of from 0.1 to under 0.5 g per liter of the electroplating solution, to form, on at least one surface of the steel sheet, a zinciferous electroplating layer in which zinc hydroxide particles having the oxide particles as nuclei thereof are uniformly dispersed.

公开(公告)号：US5500290A

公开(公告)日：1996-03-19

申请号：US265239

申请日：1994-06-24

申请人： Satoru Udagawa ,  Masaki Abe ,  Satoru Ando ,  Yasuhiro Matsuki ,  Toyofumi Watanabe ,  Yukimitsu Shiohara ,  Masaya Morita ,  Akimasa Kido

发明人： Satoru Udagawa ,  Masaki Abe ,  Satoru Ando ,  Yasuhiro Matsuki ,  Toyofumi Watanabe ,  Yukimitsu Shiohara ,  Masaya Morita ,  Akimasa Kido

IPC分类号： C21D8/04 ,  C23C2/02 ,  B32B15/18

CPC分类号： C21D8/0426 ,  C23C2/02 ,  C21D8/0436 ,  C21D8/0478 ,  Y10S428/941 ,  Y10T428/12458 ,  Y10T428/12792 ,  Y10T428/12799 ,  Y10T428/12937

摘要： A surface treated steel sheet comprises: a steel sheet containing C, Si, Mn, P, S, Ni, Ti, Cu and B; a diffused alloy layer containing Fe, Ni, and P; and a zinc coating layer formed on the diffused alloy layer.A method for producing a surface treated steel sheet comprises the steps of: preparing a steel sheet; coating the steel sheet with a Ni-P coating layer; heat-treating the steel sheet coated with the Ni-P coating layer; and forming a zinc coating layer on the diffused alloy layer.

摘要翻译： 表面处理钢板包括：含有C，Si，Mn，P，S，Ni，Ti，Cu和B的钢板; 含Fe，Ni和P的扩散合金层; 以及形成在扩散合金层上的锌涂层。 一种表面处理钢板的制造方法，其特征在于，包括以下工序：制造钢板; 用Ni-P涂层涂覆钢板; 对涂覆有Ni-P涂层的钢板进行热处理; 并在扩散合金层上形成锌涂层。

公开(公告)号：US5494706A

公开(公告)日：1996-02-27

申请号：US263088

申请日：1994-06-21

申请人： Masaki Abe ,  Satoru Ando ,  Toyofumi Watanabe ,  Yukimitsu Shiohara

发明人： Masaki Abe ,  Satoru Ando ,  Toyofumi Watanabe ,  Yukimitsu Shiohara

IPC分类号： C23C2/02 ,  C25D15/02

CPC分类号： C23C2/02

摘要： A method for producing zinc coated steel sheet comprises the steps of: forming a Ni--P alloy coating layer containing P of 8 to 15 wt. % on at least one surface of a steel sheet; heat-treating the steel sheet coated with the alloy layer in a non-oxidizing atmosphere to form an Fe--Ni--P diffused alloy layer at an interface of the steel sheet and the alloy coating layer; and zinc coating the steel sheet coated with the diffused alloy layer to form a zinc coating layer.

摘要翻译： 制造镀锌钢板的方法包括以下步骤：形成含有8〜15重量％的P的Ni-P合金涂层。 ％在钢板的至少一个表面上; 在非氧化性气氛中对涂有合金层的钢板进行热处理，在钢板和合金涂层的界面形成Fe-Ni-P扩散合金层; 并涂覆涂有扩散合金层的钢板以形成锌涂层。

公开(公告)号：US4904545A

公开(公告)日：1990-02-27

申请号：US215032

申请日：1988-07-05

申请人： Masaru Sagiyama ,  Yukimitsu Shiohara

发明人： Masaru Sagiyama ,  Yukimitsu Shiohara

IPC分类号： C25D15/02

CPC分类号： C25D15/02 ,  Y10S428/935 ,  Y10T428/12486 ,  Y10T428/12799

摘要： A composite electroplated steel sheet comprises Zn being a matrix metal of a plating layer; and codeposited particles of a plating layer of at least one selected from the group consisting of Mg.sub.2 Si.sub.3 O.sub.8, CaSiO.sub.3 and BaTiO.sub.3. A composite electroplated steel sheet comprises Zn alloy containing at least one selected from the group consisting of Fe, Co, Ni, Mn, Cr and Ti being a matrix metal of a plating layer; and codeposited particles of a plating layer comprising at least one selected from the group consisting of Mg.sub.2 Si.sub.3 O.sub.8, CaSiO.sub.3 and BaTiO.sub.3. The codeposited particles are contained within the range of from 0.1 to 5.0 wt.% in a plating layer.