公开(公告)号：US07429291B2

公开(公告)日：2008-09-30

申请号：US11546973

申请日：2006-10-13

申请人： Masako Udagawa ,  Sadayuki Sugama ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Sadayuki Sugama ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： C09D11/02

CPC分类号： C09D11/32 ,  B41M3/144 ,  C09D11/50

摘要： The present invention provides a fluorescence ink having a high fluorescence intensity, and an ink jet recording method using the same. The ink contains a first fluorescent coloring material that emits fluorescence at a predetermined fluorescence wavelength to be used for measurement or determination with excitation at a predetermined excitation wavelength, a second fluorescent coloring material that emits fluorescence on excitation at the predetermined excitation wavelength, where the excitation spectrum of the first coloring material in the ink to obtain the fluorescence at the predetermined emission wavelength has a peak wavelength range next to the predetermined fluorescence wavelength, and the emission fluorescence spectrum of the second coloring material has an emission wavelength region substantially including at least the above peak wavelength range.

摘要翻译： 本发明提供了具有高荧光强度的荧光油墨和使用该荧光强度的喷墨记录方法。 油墨含有第一荧光着色材料，其以预定的荧光波长发射荧光，以用于以预定激发波长的激发进行测量或测定;第二荧光着色材料，其以预定激发波长发射荧光，其中激发 油墨中的第一着色材料的光谱以获得预定发射波长的荧光具有与预定荧光波长相邻的峰值波长范围，并且第二着色材料的发射荧光光谱具有基本上至少包括 高于峰值波长范围。

公开(公告)号：US20070029522A1

公开(公告)日：2007-02-08

申请号：US11546973

申请日：2006-10-13

申请人： Masako Udagawa ,  Sadayuki Sugama ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Sadayuki Sugama ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： C09D11/00 ,  C09K11/06

CPC分类号： C09D11/32 ,  B41M3/144 ,  C09D11/50

摘要： The present invention provides a fluorescence ink having a high fluorescence intensity, and an ink jet recording method using the same. The ink contains a first fluorescent coloring material that emits fluorescence at a predetermined fluorescence wavelength to be used for measurement or determination with excitation at a predetermined excitation wavelength, a second fluorescent coloring material that emits fluorescence on excitation at the predetermined excitation wavelength, where the excitation spectrum of the first coloring material in the ink to obtain the fluorescence at the predetermined emission wavelength has a peak wavelength range next to the predetermined fluorescence wavelength, and the emission fluorescence spectrum of the second coloring material has an emission wavelength region substantially including at least the above peak wavelength range.

摘要翻译： 本发明提供了具有高荧光强度的荧光油墨和使用该荧光强度的喷墨记录方法。 油墨含有第一荧光着色材料，其以预定的荧光波长发射荧光，以用于以预定激发波长的激发进行测量或测定;第二荧光着色材料，其以预定激发波长发射荧光，其中激发 油墨中的第一着色材料的光谱以获得预定发射波长的荧光具有与预定荧光波长相邻的峰值波长范围，并且第二着色材料的发射荧光光谱具有基本上至少包括 高于峰值波长范围。

公开(公告)号：US07144449B2

公开(公告)日：2006-12-05

申请号：US10866116

申请日：2004-06-14

申请人： Masako Udagawa ,  Sadayuki Sugama ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Sadayuki Sugama ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： C09D11/02 ,  C09K11/02

CPC分类号： C09D11/32 ,  B41M3/144 ,  C09D11/50

摘要： The present invention provides a fluorescence ink having a high fluorescence intensity, and an ink jet recording method using the same. The ink contains a first fluorescent coloring material that emits fluorescence at a predetermined fluorescence wavelength to be used for measurement or determination with excitation at a predetermined excitation wavelength, a second fluorescent coloring material that emits fluorescence on excitation at the predetermined excitation wavelength, where the excitation spectrum of the first coloring material in the ink to obtain the fluorescence at the predetermined emission wavelength has a peak wavelength range next to the predetermined fluorescence wavelength, and the emission fluorescence spectrum of the second coloring material has an emission wavelength region substantially including at least the above peak wavelength range.

摘要翻译： 本发明提供了具有高荧光强度的荧光油墨和使用该荧光强度的喷墨记录方法。 油墨含有第一荧光着色材料，其以预定的荧光波长发射荧光，以用于以预定激发波长的激发进行测量或测定;第二荧光着色材料，其以预定激发波长发射荧光，其中激发 油墨中的第一着色材料的光谱以获得预定发射波长的荧光具有与预定荧光波长相邻的峰值波长范围，并且第二着色材料的发射荧光光谱具有基本上至少包括 高于峰值波长范围。

公开(公告)号：US20070034114A1

公开(公告)日：2007-02-15

申请号：US11582456

申请日：2006-10-18

申请人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： C09D11/00 ,  D06L3/12

CPC分类号： C09D11/50 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/24901

摘要： The present invention relates to a water-based fluorescent ink for the purpose of measurement or judgment of the fluorescence emission in a visible light region by an excitation wavelength in a predetermined ultraviolet range, containing water, a coloring material dissolved or dispersed in water, and an organic solvent, having a plurality of fluorescent groups in the coloring material structure of the coloring material, and using a water-soluble coloring material having a sulfonic acid group as the water-soluble group in the state of a free acid, capable of improving the water resistance and the light resistance, dramatically increasing the content of the fluorescent coloring material in the ink, which has conventionally been included only by a small amount in the ink due to the concentration quenching problem, obtaining preferable fluorescence emission and water resistance of the recorded image, and providing preferable adhesion resistance to the recording medium of the coloring material and reliability.

摘要翻译： 本发明涉及一种水性荧光墨水，其目的在于测量或判断可见光区域中的荧光发射是否在预定的紫外线范围内的激发波长，包含水，溶解或分散在水中的着色材料，以及 有机溶剂，在着色材料的着色材料结构中具有多个荧光基团，并且使用具有磺酸基作为游离酸状态的水溶性基团的水溶性着色材料，能够改善 耐水性和耐光性，显着增加了由于浓度骤冷问题而在墨中常规包含的油墨中的荧光着色材料的含量，获得了优选的荧光发射和耐水性 记录图像，并且对着色剂的记录介质提供优选的粘合性 可靠性和可靠性。

公开(公告)号：US07464965B2

公开(公告)日：2008-12-16

申请号：US11582456

申请日：2006-10-18

申请人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： B42D15/00

CPC分类号： C09D11/50 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/24901

摘要： The present invention relates to a water-based fluorescent ink for the purpose of measurement or judgment of the fluorescence emission in a visible light region by an excitation wavelength in a predetermined ultraviolet range, containing water, a coloring material dissolved or dispersed in water, and an organic solvent, having a plurality of fluorescent groups in the coloring material structure of the coloring material, and using a water-soluble coloring material having a sulfonic acid group as the water-soluble group in the state of a free acid, capable of improving the water resistance and the light resistance, dramatically increasing the content of the fluorescent coloring material in the ink, which has conventionally been included only by a small amount in the ink due to the concentration quenching problem, obtaining preferable fluorescence emission and water resistance of the recorded image, and providing preferable adhesion resistance to the recording medium of the coloring material and reliability.

摘要翻译： 本发明涉及一种水性荧光墨水，其目的在于测量或判断可见光区域中的荧光发射是否在预定的紫外线范围内的激发波长，包含水，溶解或分散在水中的着色材料，以及 有机溶剂，在着色材料的着色材料结构中具有多个荧光基团，并且使用具有磺酸基作为游离酸状态的水溶性基团的水溶性着色材料，能够改善 耐水性和耐光性，显着增加了由于浓度骤冷问题而在墨中常规包含的油墨中的荧光着色材料的含量，获得了优选的荧光发射和耐水性 记录图像，并且对着色剂的记录介质提供优选的粘合性 可靠性和可靠性。

公开(公告)号：US20090078889A1

公开(公告)日：2009-03-26

申请号：US12272194

申请日：2008-11-17

申请人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： A61N5/06

CPC分类号： C09D11/50 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/24901

摘要： The present invention relates to a water-based fluorescent ink for the purpose of measurement or judgment of the fluorescence emission in a visible light region by an excitation wavelength in a predetermined ultraviolet range, containing water, a coloring material dissolved or dispersed in water, and an organic solvent, having a plurality of fluorescent groups in the coloring material structure of the coloring material, and using a water-soluble coloring material having a sulfonic acid group as the water-soluble group in the state of a free acid, capable of improving the water resistance and the light resistance, dramatically increasing the content of the fluorescent coloring material in the ink, which has conventionally been included only by a small amount in the ink due to the concentration quenching problem, obtaining preferable fluorescence emission and water resistance of the recorded image, and providing preferable adhesion resistance to the recording medium of the coloring material and reliability.

摘要翻译： 本发明涉及一种水性荧光墨水，其目的在于测量或判断可见光区域中的荧光发射是否在预定的紫外线范围内的激发波长，包含水，溶解或分散在水中的着色材料，以及 有机溶剂，在着色材料的着色材料结构中具有多个荧光基团，并且使用具有磺酸基作为游离酸状态的水溶性基团的水溶性着色材料，能够改善 耐水性和耐光性，显着增加了由于浓度骤冷问题而在墨中常规包含的油墨中的荧光着色材料的含量，获得了优选的荧光发射和耐水性 记录图像，并且对着色剂的记录介质提供优选的粘合性 可靠性和可靠性。

公开(公告)号：US08308198B2

公开(公告)日：2012-11-13

申请号：US12272194

申请日：2008-11-17

申请人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： A61N5/06 ,  G01J3/10 ,  H05G2/00

CPC分类号： C09D11/50 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/24901

摘要： The present invention relates to a water-based fluorescent ink for the purpose of measurement or judgment of the fluorescence emission in a visible light region by an excitation wavelength in a predetermined ultraviolet range, containing water, a coloring material dissolved or dispersed in water, and an organic solvent, having a plurality of fluorescent groups in the coloring material structure of the coloring material, and using a water-soluble coloring material having a sulfonic acid group as the water-soluble group in the state of a free acid, capable of improving the water resistance and the light resistance, dramatically increasing the content of the fluorescent coloring material in the ink, which has conventionally been included only by a small amount in the ink due to the concentration quenching problem, obtaining preferable fluorescence emission and water resistance of the recorded image, and providing preferable adhesion resistance to the recording medium of the coloring material and reliability.

摘要翻译： 本发明涉及一种水性荧光墨水，其目的在于测量或判断可见光区域中的荧光发射是否在预定的紫外线范围内的激发波长，包含水，溶解或分散在水中的着色材料，以及 有机溶剂，在着色材料的着色材料结构中具有多个荧光基团，并且使用具有磺酸基作为游离酸状态的水溶性基团的水溶性着色材料，能够改善 耐水性和耐光性，显着增加了由于浓度骤冷问题而在墨中常规包含的油墨中的荧光着色材料的含量，获得了优选的荧光发射和耐水性 记录图像，并且对着色剂的记录介质提供优选的粘合性 可靠性和可靠性。

公开(公告)号：US07141105B2

公开(公告)日：2006-11-28

申请号：US10975396

申请日：2004-10-29

申请人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： C09D11/02

CPC分类号： C09D11/50 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/24901

摘要： The present invention relates to a water-based fluorescent ink for the purpose of measurement or judgment of the fluorescence emission in a visible light region by an excitation wavelength in a predetermined ultraviolet range, containing water, a coloring material dissolved or dispersed in water, and an organic solvent, having a plurality of fluorescent groups in the coloring material structure of the coloring material, and using a water-soluble coloring material having a sulfonic acid group as the water-soluble group in the state of a free acid, capable of improving the water resistance and the light resistance, dramatically increasing the content of the fluorescent coloring material in the ink, which has conventionally been included only by a small amount in the ink due to the concentration quenching problem, obtaining preferable fluorescence emission and water resistance of the recorded image, and providing preferable adhesion resistance to the recording medium of the coloring material and reliability.

摘要翻译： 本发明涉及一种水性荧光墨水，其目的在于测量或判断可见光区域中的荧光发射是否在预定的紫外线范围内的激发波长，包含水，溶解或分散在水中的着色材料，以及 有机溶剂，在着色材料的着色材料结构中具有多个荧光基团，并且使用具有磺酸基作为游离酸状态的水溶性基团的水溶性着色材料，能够改善 耐水性和耐光性，显着增加了由于浓度骤冷问题而在墨中常规包含的油墨中的荧光着色材料的含量，获得了优选的荧光发射和耐水性 记录图像，并且对着色剂的记录介质提供优选的粘合性 可靠性和可靠性。

公开(公告)号：US20050109952A1

公开(公告)日：2005-05-26

申请号：US10975396

申请日：2004-10-29

申请人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

发明人： Masako Udagawa ,  Shoji Koike ,  Makoto Aoki ,  Akira Nagashima ,  Shinichi Hakamada

IPC分类号： B41J2/01 ,  B41M3/14 ,  C09D11/00 ,  G01N21/64

CPC分类号： C09D11/50 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/24901

摘要： The present invention relates to a water-based fluorescent ink for the purpose of measurement or judgment of the fluorescence emission in a visible light region by an excitation wavelength in a predetermined ultraviolet range, containing water, a coloring material dissolved or dispersed in water, and an organic solvent, having a plurality of fluorescent groups in the coloring material structure of the coloring material, and using a water-soluble coloring material having a sulfonic acid group as the water-soluble group in the state of a free acid, capable of improving the water resistance and the light resistance, dramatically increasing the content of the fluorescent coloring material in the ink, which has conventionally been included only by a small amount in the ink due to the concentration quenching problem, obtaining preferable fluorescence emission and water resistance of the recorded image, and providing preferable adhesion resistance to the recording medium of the coloring material and reliability.

摘要翻译： 本发明涉及一种水性荧光墨水，其目的在于测量或判断可见光区域中的荧光发射是否在预定的紫外线范围内的激发波长，包含水，溶解或分散在水中的着色材料，以及 有机溶剂，在着色材料的着色材料结构中具有多个荧光基团，并且使用具有磺酸基作为游离酸状态的水溶性基团的水溶性着色材料，能够改善 耐水性和耐光性，显着增加了由于浓度骤冷问题而在墨中常规包含的油墨中的荧光着色材料的含量，获得了优选的荧光发射和耐水性 记录图像，并且对着色剂的记录介质提供优选的粘合性 可靠性和可靠性。

公开(公告)号：US07185978B2

公开(公告)日：2007-03-06

申请号：US10634825

申请日：2003-08-06

申请人： Akira Nagashima ,  Shoji Koike ,  Shinichi Hakamada

发明人： Akira Nagashima ,  Shoji Koike ,  Shinichi Hakamada

IPC分类号： G01D11/00

CPC分类号： C09D11/50 ,  B41J2002/14169 ,  B41J2002/14475 ,  C09D11/30

摘要： A recording method including the step of providing an ink from a recording head to a recording medium through a gap provided between the recording head and the recording medium, the ink being supplied to the recording head from an ink tank including an ink contact member and the ink contacting the ink contact member, wherein the ink comprises: (i) a fluorescent coloring material; (ii) a nonionic surfactant; (iii) a compound which is not compatible with (ii); and (iv) a liquid medium for dissolving or dispersing (i), (ii) and (iii), and wherein the ink contact member comprises at least one compound selected from the group consisting of polyacetate and polyolefin.

摘要翻译： 一种记录方法，包括通过设置在记录头和记录介质之间的间隙从记录头向记录介质提供墨水的步骤，所述墨水从包括墨接触部件的墨罐供应到记录头， 油墨接触墨接触构件，其中油墨包括：（i）荧光着色材料; （ii）非离子表面活性剂; （iii）与（ii）不相容的化合物; 和（iv）用于溶解或分散（i），（ii）和（iii）的液体介质，并且其中所述油墨接触构件包含至少一种选自聚乙酸酯和聚烯烃的化合物。