公开(公告)号：US5395952A

公开(公告)日：1995-03-07

申请号：US179123

申请日：1994-01-10

申请人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

发明人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

IPC分类号： A01N43/90 ,  C07D491/04 ,  C07D317/46

CPC分类号： C07D491/04 ,  A01N43/90

摘要： A benzimidazole derivative having the formula, ##STR1## wherein R is cyano or thiocarbamoyl; Q is lower alkyl or a group represented by the formula NQ.sup.1 Q.sup.2, in which Q.sup.1 and Q.sup.2 are independently lower alkyl, lower alkyl substituted with phenyl, lower alkenyl or lower alkynyl, or they form a lower alkylene ring when taken together at their ends which ring may include a hetero atom; X is hydrogen or halogen; and Z is a group which consists of (a) one oxygen atom or two non-adjacent oxygen atom, (b) --CF.sub.2 --group and (c) any one of a single bond, --CF.sub.2 --, --CFH--, CFCl-- and --CH.sub.2 --groups and forms a five-membered or six membered ring together with two adjacent carbon atoms of the benzene ring; is obtained by reacting a corresponding 2-cyanobenzimidazole compound and a sulfamoyl chloride derivative. The benzimidazole derivative is incorporated into agricultural and horticultural fungicides as an active ingredient.

摘要翻译： 具有下式的苯并咪唑衍生物，其中R是氰基或硫代氨基甲酰基; Q是低级烷基或由式NQ1Q2表示的基团，其中Q1和Q2独立地是低级烷基，被苯基，低级链烯基或低级炔基取代的低级烷基，或者当它们的末端相互结合时，它们形成低级亚烷基环 可以包括杂原子; X是氢或卤素; 和Z是由（a）一个氧原子或两个不相邻的氧原子组成的基团，（b）-CF 2 - 基团和（c）单键-CF2-，-CFH-，CFCl- 和-CH 2 - 基，并与苯环的两个相邻碳原子一起形成五元或六元环; 是通过使相应的2-氰基苯并咪唑化合物和氨磺酰氯衍生物反应得到的。 苯并咪唑衍生物作为活性成分掺入农业和园艺杀真菌剂中。

公开(公告)号：US5472974A

公开(公告)日：1995-12-05

申请号：US175763

申请日：1993-12-30

申请人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

发明人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

IPC分类号： A01N43/90 ,  C07D491/04 ,  C07D491/044

CPC分类号： C07D491/04 ,  A01N43/90

摘要： A benzimidazole derivative having the formula, ##STR1## wherein R is cyano or thiocarbamoyl; Q is lower alkyl or a group represented by the formula NQ.sup.1 Q.sup.2, in which Q.sup.1 and Q.sup.2 are independently lower alkyl, lower alkyl substituted with phenyl, lower alkenyl or lower alkynyl, or they form a lower alkylene ring when taken together at their ends which ring may include a hereto atom; X is hydrogen or halogen; and Z is a group which consists of (a) one oxygen atom or two non-adjacent oxygen atom, (b) --CF.sub.2 -- group and (c) any one of a single bond, --CF.sub.2 --, --CFH--, CFCl-- and --CH.sub.2 -- groups and forms a five-membered or six membered ring together with two adjacent carbon atoms of the benzene ring; is obtained by reacting a corresponding 2-cyanobenzimidazole compound and a sulfamoyl chloride derivative. The benzimidazole derivative is incorporated into agricultural and horticultural fungicides as an active ingredient.

摘要翻译： 具有下式的苯并咪唑衍生物，其中R是氰基或硫代氨基甲酰基; Q是低级烷基或由式NQ1Q2表示的基团，其中Q1和Q2独立地是低级烷基，被苯基，低级链烯基或低级炔基取代的低级烷基，或者当它们的末端相互结合时，它们形成低级亚烷基环 可能包括一个原子; X是氢或卤素; Z为由（a）一个氧原子或两个不相邻氧原子组成的基团，（b）-CF2-基团和（c）单键，-CF2-，-CFH-，CFCl- 和-CH 2 - 基团，并与苯环的两个相邻碳原子一起形成五元或六元环; 是通过使相应的2-氰基苯并咪唑化合物和氨磺酰氯衍生物反应得到的。 苯并咪唑衍生物作为活性成分掺入农业和园艺杀真菌剂中。

公开(公告)号：US5310747A

公开(公告)日：1994-05-10

申请号：US894007

申请日：1992-06-02

申请人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

发明人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

IPC分类号： C07D235/24 ,  A01N43/12 ,  A01N43/30 ,  A01N43/52 ,  A01N43/90 ,  A01P3/00 ,  C07D491/04 ,  C07D491/048 ,  C07D491/056 ,  C07D235/02

CPC分类号： C07D491/04 ,  A01N43/90

摘要： A benzimidazole derivative having the formula, ##STR1## wherein R is cyano or thiocarbamoyl; Q is lower alkyl or a group represented by the formula NQ.sup.1 Q.sup.2, in which Q.sup.1 and Q.sup.2 are independently lower alkyl, lower alkyl substituted with phenyl, lower alkenyl or lower alkynyl, or they form a lower alkylene ring when taken together at their ends which ring may include a hetero atom; X is hydrogen or halogen; and Z is a group which consists of (a) one oxygen atom or two non-adjacent oxygen atom, (b) --CF.sub.2 -- group and (c) any one of a single bond, --CF.sub.2 --, --CFH--, CFCl-- and --CH.sub.2 -- groups and forms a five-membered or six membered ring together with two adjacent carbon atoms of the benzene ring; is obtained by reacting a corresponding 2-cyanobenzimidazole compound and a sulfamoyl chloride derivative. The benzimidazole derivative is incorporated into agricultural and horticultural fungicides as an active ingredient.

摘要翻译： 具有下式的苯并咪唑衍生物，其中R是氰基或硫代氨基甲酰基; Q是低级烷基或由式NQ1Q2表示的基团，其中Q1和Q2独立地是低级烷基，被苯基，低级链烯基或低级炔基取代的低级烷基，或者当它们的末端相互结合时，它们形成低级亚烷基环 可以包括杂原子; X是氢或卤素; Z为由（a）一个氧原子或两个不相邻氧原子组成的基团，（b）-CF2-基团和（c）单键，-CF2-，-CFH-，CFCl- 和-CH 2 - 基团，并与苯环的两个相邻碳原子一起形成五元或六元环; 是通过使相应的2-氰基苯并咪唑化合物和氨磺酰氯衍生物反应得到的。 苯并咪唑衍生物作为活性成分掺入农业和园艺杀真菌剂中。

公开(公告)号：US5234938A

公开(公告)日：1993-08-10

申请号：US792477

申请日：1991-11-15

申请人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

发明人： Masayuki Enomoto ,  Junya Takahashi ,  Tomoyuki Kusaba ,  Masayo Sugano ,  Rei Matsunaga ,  Masahiro Tamaki

IPC分类号： A01N43/52 ,  C07C217/84 ,  C07D235/10 ,  C07D235/24

CPC分类号： C07D235/24 ,  C07C217/84 ,  C07D235/10

摘要： A benzimidazole derivative having the formula, ##STR1## wherein X is halogen, is produced by reacting a compound having the formula, ##STR2## wherein X is halogen, with dimethylsulfamoyl chloride. The benzimidazole derivative can be used as an active ingredient in agricultural and horticultural fungicides.

公开(公告)号：US09265254B2

公开(公告)日：2016-02-23

申请号：US11256002

申请日：2005-10-24

申请人： Toshiro Otsubo ,  Rei Matsunaga ,  Eriko Takeko

发明人： Toshiro Otsubo ,  Rei Matsunaga ,  Eriko Takeko

IPC分类号： A61K31/4152 ,  C07D231/52 ,  A01N43/56

CPC分类号： A01N43/56 ,  A01N2300/00

摘要： A granular pesticidal composition which comprises a pyrazolinone compound given by the formula (1): wherein R1 represents a chlorine atom etc.; R2 represents a chlorine atom etc.; R3 represents a 1-methylethyl group etc.; and R4 represents a C1-C4 alkoxy group etc. and a salt of ligninsulfonic acid, and the amount of the salt of ligninsulfonic acid in the granular pesticidal composition is 10-60% by weight has good disintegrability in water when it is diluted with water.

摘要翻译： 一种颗粒状农药组合物，其含有式（1）所示的吡唑啉酮化合物：其中R1表示氯原子等; R2代表氯原子等; R3代表1-甲基乙基等; R4表示C1〜C4烷氧基等，木素磺酸盐，粒状杀虫剂组合物中木质素磺酸盐的含量为10〜60重量％时，用水稀释后，水中崩解性好 。

公开(公告)号：US08833130B2

公开(公告)日：2014-09-16

申请号：US13357954

申请日：2012-01-25

申请人： Rei Matsunaga ,  Masatoshi Sato ,  Kunihide Kaji ,  Shinji Takahashi

发明人： Rei Matsunaga ,  Masatoshi Sato ,  Kunihide Kaji ,  Shinji Takahashi

IPC分类号： B21D11/14 ,  B21F3/04 ,  B21F35/00 ,  B21F45/00 ,  A61B17/064 ,  A61B17/11 ,  A61B17/00

CPC分类号： A61B17/0644 ,  A61B17/1114 ,  A61B2017/00526 ,  A61B2017/00862 ,  A61B2017/00867 ,  A61B2017/0645 ,  A61B2017/0649 ,  B21F3/04 ,  B21F35/00 ,  B21F45/008

摘要： A tissue fastener production method of clamping two living tissues together by bringing the two living tissues into close contact includes the following steps: fixing one end of a wire material made of a metal to a shaft body, and winding the wire material around an outer periphery of the shaft body while twisting the wire material round an axis of the wire material, thereby forming a coil on which a predetermined force is exerted in the winding direction; heat treating the wire material to impart superelasticity thereto; and deforming the wire material to which the superelasticity is imparted in a range in which the wire material is elastically deformable, and reversing the winding direction of the coil in a direction reverse to the winding direction of the coil wound in the step of forming the coil so as to obtain an initial tension corresponding to the predetermined force.

摘要翻译： 通过使两个活组织紧密接触将两个活组织夹在一起的组织紧固件制造方法包括以下步骤：将由金属制成的线材的一端固定到轴体上，并将线材绕在外周 使线材绕线材的轴线旋转，从而形成在卷绕方向上施加预定力的线圈; 对线材进行热处理以赋予其超弹性; 并且在线材可弹性变形的范围内使施加超弹性的线材变形，并且在形成线圈的步骤中缠绕的线圈的缠绕方向与卷绕方向相反的方向使线圈的卷绕方向反转 以获得对应于预定力的初始张力。

公开(公告)号：US5863932A

公开(公告)日：1999-01-26

申请号：US812503

申请日：1997-03-07

申请人： Rei Matsunaga

发明人： Rei Matsunaga

IPC分类号： A01N37/32 ,  A01N47/14 ,  A01N47/42 ,  A01N59/02 ,  A01N37/52 ,  A01N43/64 ,  A01N55/00

CPC分类号： A01N47/42

摘要： There is disclosed a microbicidal composition comprising as active ingredients:(I) a dithiocarbonimide compound represented by the general formula: ##STR1## wherein Z represents CH group or nitrogen, R.sup.1 and R.sup.2 are the same or different and represent hydrogen, C.sub.1 -C.sub.6 alkyl group, halogen, C.sub.1 -C.sub.6 alkoxy group, C.sub.1 -C.sub.6 haloalkyl group or C.sub.1 -C.sub.6 haloalkoxy group, or R.sup.1 and R.sup.2 are taken together to form methylenedioxy group optionally substituted with fluorine, and(II) at least one compound selected from the group consisting of azole microbicidal compound, cyclic amine microbicidal compound, N-(3,5-dichlorophenyl)imide microbicidal compound, anilinopyrimidine microbicidal compound, cyanopyrrole microbicidal compound, benzimidazole microbicidal compound, fluazinam, thiram and sulfur.

摘要翻译： 公开了包含作为活性成分的杀微生物组合物：（I）由以下通式表示的二硫代碳酰亚胺化合物：en，R 1和R 2相同或不同，表示氢，C 1 -C 6烷基，卤素，C 1 -C 6烷氧基 ，C1-C6卤代烷基或C1-C6卤代烷氧基，或R1和R2一起形成任选被氟取代的亚甲二氧基，和（II）至少一种选自唑类杀微生物化合物，环胺杀微生物剂 化合物，N-（3,5-二氯苯基）酰亚胺杀微生物化合物，苯胺基嘧啶杀微生物化合物，氰基吡咯杀微生物化合物，苯并咪唑杀微生物化合物，氟啶胺，丝氨酸和硫。

公开(公告)号：US5798384A

公开(公告)日：1998-08-25

申请号：US808552

申请日：1997-02-28

申请人： Rei Matsunaga

发明人： Rei Matsunaga

IPC分类号： A01N47/42 ,  A01N37/34 ,  A01N37/52

CPC分类号： A01N47/42

摘要： There is disclosed a microbicidal composition comprising as active ingredients: (I) a dithiocarbonimide compound represented by the general formula: ##STR1## wherein Z represents CH group or nitrogen atom, R.sup.1 and R.sup.2 are the same or different and represent hydrogen atom, C.sub.1 -C.sub.6 alkyl group, halogen atom, C.sub.1 -C.sub.6 alkoxy group, C.sub.1 -C.sub.6 haloalkyl group or C.sub.1 -C.sub.6 haloalkoxy group, or R.sup.1 and R.sup.2 are taken together to form methylenedioxy group optionally substituted with fluorine atom, and (II) at least one compound selected from the group consisting of ethylenebis(dithiocarbamate) compound, copper compound, phthalimide microbicidal compound, chlorothalonil, anilide microbicidal compound, cymoxanil, dimethomorph and fosetyl.

摘要翻译： 公开了包含作为活性成分的杀微生物组合物：（I）由以下通式表示的二硫代碳酰亚胺化合物：原子，R 1和R 2相同或不同，表示氢原子，C 1 -C 6烷基，卤素原子，C 1 -C 6 烷氧基，C1-C6卤代烷基或C1-C6卤代烷氧基，或R1和R2一起形成任选被氟原子取代的亚甲二氧基，和（II）选自亚乙基双（二硫代氨基甲酸酯） 化合物，铜化合物，邻苯二甲酰亚胺杀微生物化合物，百菌清，苯胺杀微生物化合物，cymoxanil，烯酰吗啉和fosetyl。

公开(公告)号：US08696657B2

公开(公告)日：2014-04-15

申请号：US12340861

申请日：2008-12-22

申请人： Rei Matsunaga ,  Masahiro Ishikawa

发明人： Rei Matsunaga ,  Masahiro Ishikawa

IPC分类号： A61B18/04 ,  A61B18/18

CPC分类号： A61B18/1492 ,  A61B2018/1407

摘要： A treatment tool for an endoscope which is transendoscopically inserted into a body cavity for use, and which includes: a sheath at least partially composed of mixed material in which thermoplastic resin and a crosslinking promoter are mixed; a manipulation wire inserted through the aforementioned sheath so as to be capable of advancing and retracting; a treatment part attached to a first end of the aforementioned manipulation wire; and a manipulation part attached to a second end of the aforementioned manipulation wire; wherein said sheath has a crosslinked part where said thermoplastic resin is crosslinked by irradiating said mixed material with ionizing radiation, and a non-crosslinked region where said thermoplastic resin is not crosslinked.

摘要翻译： 一种用于内窥镜的内窥镜治疗工具，其通过内窥镜插入体腔内使用，并且包括：至少部分地由混合材料构成的鞘，其中混合有热塑性树脂和交联促进剂; 通过上述护套插入的操作线能够前进和后退; 附接到上述操作线的第一端的处理部; 以及附接到上述操作线的第二端的操作部分; 其中所述护套具有交联部分，其中所述热塑性树脂通过用电离辐射照射所述混合材料而交联，以及所述热塑性树脂未交联的非交联区域。

公开(公告)号：US20100160727A1

公开(公告)日：2010-06-24

申请号：US12340861

申请日：2008-12-22

申请人： Rei Matsunaga ,  Masahiro Ishikawa

发明人： Rei Matsunaga ,  Masahiro Ishikawa

IPC分类号： A61B1/018

CPC分类号： A61B18/1492 ,  A61B2018/1407

摘要： A treatment tool for an endoscope which is transendoscopically inserted into a body cavity for use, and which includes: a sheath at least partially composed of mixed material in which thermoplastic resin and a crosslinking promoter are mixed; a manipulation wire inserted through the aforementioned sheath so as to be capable of advancing and retracting; a treatment part attached to a first end of the aforementioned manipulation wire; and a manipulation part attached to a second end of the aforementioned manipulation wire; wherein said sheath has a crosslinked part where said thermoplastic resin is crosslinked by irradiating said mixed material with ionizing radiation, and a non-crosslinked region where said thermoplastic resin is not crosslinked.

摘要翻译： 一种用于内窥镜的内窥镜治疗工具，其通过内窥镜插入体腔内使用，并且包括：至少部分地由混合材料构成的鞘，其中混合有热塑性树脂和交联促进剂; 通过上述护套插入的操作线能够前进和后退; 附接到上述操作线的第一端的处理部; 以及附接到上述操作线的第二端的操作部分; 其中所述护套具有交联部分，其中所述热塑性树脂通过用电离辐射照射所述混合材料而交联，以及所述热塑性树脂未交联的非交联区域。