Process for preparing alkyl tert-alkyl ethers
    2.
    发明授权
    Process for preparing alkyl tert-alkyl ethers 失效
    烷基叔烷基醚的制备方法

    公开(公告)号:US5030768A

    公开(公告)日:1991-07-09

    申请号:US502585

    申请日:1990-03-30

    CPC分类号: C07C41/36 C07C41/06

    摘要: A process for preparing an alkyl-tert-alkyl ether wherein an olefin having a double bond on a tertiary carbon atom and a primary alcohol are reacted in the presence of a catalyst under conditions sufficient to produce an azeotropic alcohol/ether/hydrocarbon mixture containing the alkyl-tert-alkyl ether. The azeotropic alcohol/ether/hydrocarbon mixture is subjected to a cyclic liquid phase adsorption process sequence to selectively remove the alcohol. The resulting non-azeotropic ether/hydrocarbon stream can then be easily separated by distillation to provide the desired alkyl-tert-alkyl ether product and a hydrocarbon product. The cyclic adsorption process employed to separate the alcohol from the ether/hydrocarbon mixture comprises introducing the alcohol/ether/hydrocarbon mixture into a plurality of adsorption colums containing an alcohol selective adsorbent, wherein each respective absorption column undergoes successive steps of adsorption and desorption.

    Separation of azeotropes in poly(vinyl alcohol) process
    5.
    发明授权
    Separation of azeotropes in poly(vinyl alcohol) process 失效
    聚(乙烯醇)工艺中共沸物的分离

    公开(公告)号:US5292804A

    公开(公告)日:1994-03-08

    申请号:US764412

    申请日:1991-09-23

    申请人: Michael S. Chen

    发明人: Michael S. Chen

    IPC分类号: C08F8/12 C08F116/06

    CPC分类号: C08F8/12

    摘要: In a process for preparing poly(vinyl alcohol), an improved method for separating the methanol/acetate azeotropes that result from said process. The azeotropes are separated by selective adsorption of methanol on an adsorbent followed by regeneration of the adsorbent with hot methanol vapor.

    摘要翻译: 在制备聚(乙烯醇)的方法中,用于分离由所述方法产生的甲醇/乙酸酯共沸物的改进方法。 通过在吸附剂上选择性吸附甲醇来分离共沸物,然后用热的甲醇蒸气再生吸附剂。