公开(公告)号：US20120034478A1

公开(公告)日：2012-02-09

申请号：US13206139

申请日：2011-08-09

申请人： Michel Pepers ,  Klaus Wendel ,  Davy Roger Suwier ,  Norbert Nießner

发明人： Michel Pepers ,  Klaus Wendel ,  Davy Roger Suwier ,  Norbert Nießner

IPC分类号： B32B15/082 ,  B29C71/00 ,  B32B27/28 ,  C08L51/00 ,  B05D7/00

CPC分类号： C08F279/02 ,  C08F212/10 ,  C08F222/08 ,  C08L25/12 ,  C08L55/02 ,  Y10T428/31696 ,  Y10T428/31699 ,  C08L35/06 ,  C08F220/44 ,  C08F212/08

摘要： A thermoplastic moulding composition with improved metal plating properties is provided. This thermoplastic moulding composition is produced from a graft copolymer (A) a thermoplastic polymer (B) and a thermoplastic polymer (C) that is not, or only to a limited amount miscible with the thermoplastic polymer (B). The thermoplastic polymer (C) contains from 1.2 to 3% by weight of at least one monoethylenically unsaturated monomer, like acrylic acid, methacrylic acid, or dicarboxylic acids, such as maleic acid and fumaric acid and their anhydrides, such as maleic anhydride. The vinyl aromatic content of component (C) is at least 5 units lower compared to that of component (B).The graft copolymer is produced from a soft elastomeric particulate graft base with a glass transition temperature below 0° C. obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer or of at least one C1-8-alkyl acrylate, or of mixtures of these, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer.

摘要翻译： 提供了具有改善的金属电镀性能的热塑性模塑组合物。 这种热塑性模塑组合物是由热塑性聚合物（B）和热塑性聚合物（C）的接枝共聚物（A）制成的，该热塑性聚合物（C）不是或只有与热塑性聚合物（B）可混溶的有限量。 所述热塑性聚合物（C）含有1.2至3重量％的至少一种单烯属不饱和单体，如丙烯酸，甲基丙烯酸或二羧酸，如马来酸和富马酸及其酸酐，如马来酸酐。 组分（C）的乙烯基芳族化合物含量比组分（B）的乙烯基芳族化合物含量低5个单位。 接枝共聚物由玻璃化转变温度低于0℃的软弹性体颗粒接枝基质制备，通过共轭二烯单独或与少量的单烯键式不饱和单体或至少一种C 1-8 - 丙烯酸烷基酯或它们的混合物，其上接枝乙烯基芳族单体和丙烯腈以及任选的另一种单烯属不饱和单体。

公开(公告)号：US20110275763A1

公开(公告)日：2011-11-10

申请号：US13102409

申请日：2011-05-06

申请人： Norbert Nießner

发明人： Norbert Nießner

IPC分类号： C08L51/04

CPC分类号： C08L51/04 ,  C08K3/04 ,  C08L25/12 ,  C08L2205/025 ,  C08L2205/03

摘要： The present invention relates to a molding composition comprising (A) from 30 to 85% by weight of a copolymer containing at least one α,β-unsaturated monocarbonitrile in amounts of at least 30% by weight, and at least one aromatic vinyl monomer, as component (A), (B) from 10 to 40% by weight of a graft rubber with an average particle size of from 100 to 280 nm, comprising a graft base b1, composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell b2, composed of at least one aromatic vinyl monomer and of at least one α,β-unsaturated monocarbonitrile, as component (B), (C) from 5 to 30% by weight of a graft rubber with an average particle size of from 410 to 1000 nm, comprising a graft base c1, composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell c2, composed of at least one aromatic vinyl polymer and of at least one α,β-unsaturated monocarbonitrile, as component (C), and wherein the ratio by weight of component (B) to component (C) is in the range from 3:1 to 1:1, and the content of the α,β-unsaturated monocarbonitrile in component (B), in % by weight, and in component (C), in % by weight based on the total weight of the graft shell c2, is in each case from 5 to 10 percentage points below the content of α,β-unsaturated monocarbonitrile in component (A), in % by weight based on the total weight of component (A). The invention also relates to the process of producing the molding composition and its use.

摘要翻译： 本发明涉及一种模塑组合物，其包含（A）30至85重量％的含有至少30重量％的α，β-不饱和单腈的共聚物和至少一种芳族乙烯基单体 作为成分（A），（B），10〜40重量％的平均粒径为100〜280nm的接枝橡胶，包含由至少一种α，β-不饱和的 单羧酸酯和至少一种由至少一种芳族乙烯基单体和至少一种α，β-不饱和单甲腈组成的接枝壳b2作为组分（B），（C）5-30重量％的 平均粒度为410〜1000nm的接枝橡胶，包含由至少一种α，β-不饱和单羧酸酯构成的接枝基质c1和至少一种由至少一种芳香族乙烯基聚合物构成的接枝壳体c2 和至少一种α，β-不饱和单腈，作为组分（C），并且其中b 组分（B）与组分（C）的重量比在3:1至1:1的范围内，组分（B）中α，bgr-不饱和单腈的含量，以重量％计，和 组分（C）占移植壳c2总重量的重量百分数在每种情况下比组分（A）中α，bgr-不饱和单腈的含量低5至10个百分点，以％ 基于组分（A）的总重量的重量。 本发明还涉及生产模塑组合物的方法及其用途。