Process for producing high impact polystyrene
    2.
    发明授权
    Process for producing high impact polystyrene 失效
    生产高抗冲聚苯乙烯的方法

    公开(公告)号:US4482677A

    公开(公告)日:1984-11-13

    申请号:US290338

    申请日:1981-08-05

    IPC分类号: C08F279/00 C08F279/02

    CPC分类号: C08F279/02

    摘要: A process for producing a high impact polystyrene characterized by polymerizing a conjugated diene (preferably, 1,3-butadiene) by the use of an organolithium-based catalyst containing a polyfunctional organolithium compound (preferably, said organolithium-based cataylst is a mixture of a polyfunctional organolithium compound and a monofunctional organolithium compound at such a mixing ratio that the amount of lithium atom in the polyfunctional organolithium compound is 5% by weight or more based on the total sum of the lithium atoms in the respective compounds), coupling the resulting polymer molecules with a polyfunctional treating agent having at least two (preferably, 2-4 on the average) reactive sites capable of reacting with the active lithium terminal of the polymer, dissolving in styrene the conjugated diene polymer thus obtained, which has substantially a network structure and is substantially soluble in styrene, preferably in a proportion of 2-30% by weight, and then radical-polymerizing the resulting solution by bulk polymerization or bulk-suspension polymerization.

    摘要翻译: 一种制造高抗冲聚苯乙烯的方法,其特征在于通过使用含有多官能有机锂化合物的有机锂基催化剂(优选所述有机锂基催化剂)是共轭二烯(优选1,3-丁二烯) 多功能有机锂化合物和单官能有机锂化合物,其混合比例,多官能有机锂化合物中的锂原子的量相对于各化合物中的锂原子总量为5重量%以上),将所得聚合物 具有多官能处理剂的分子,其具有能够与聚合物的活性锂末端反应的至少两个(优选2-4个平均)反应性位点,将由此获得的共轭二烯聚合物溶解在苯乙烯中,所述共轭二烯聚合物具有基本上网络结构 并且基本上可溶于苯乙烯,优选2-30重量%的比例,然后是自由基-p 通过本体聚合或本体悬浮聚合将所得溶液醇化。