公开(公告)号：US08299196B2

公开(公告)日：2012-10-30

申请号：US13085510

申请日：2011-04-13

申请人： Mikio Shiono ,  Noriyuki Koike

发明人： Mikio Shiono ,  Noriyuki Koike

IPC分类号： C08G77/08

CPC分类号： C09D183/08 ,  C08G77/24 ,  C08L71/02

摘要： An adhesive composition is provided comprising (A) a fluorinated amide compound containing at least two vinyl groups and having a polyfluoro structure, (B) a fluorinated organosilicon compound containing a fluorinated organic group, at least two SiH groups, and an alkyl, aryl or aralkyl group, and (C) a platinum catalyst, and (D) an organosiloxane containing a SiH group and an epoxy and/or trialkoxysilyl group. The composition is cured on brief heating into a product which achieves adhesion to various substrates and has solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability, electric insulation, and acid resistance.

摘要翻译： 提供一种粘合剂组合物，其包含（A）含有至少两个乙烯基并具有多氟结构的氟化酰胺化合物，（B）含氟化有机基团的氟化有机硅化合物，至少两个SiH基团和烷基，芳基或 芳族烷基，（C）铂催化剂，（D）含有SiH基和环氧基和/或三烷氧基甲硅烷基的有机硅氧烷。 该组合物在短暂加热下固化成实现对各种基材的粘合性的产品，并具有耐溶剂性，耐化学性，耐热性，低温性，低透湿性，电绝缘性和耐酸性。

公开(公告)号：US20110257315A1

公开(公告)日：2011-10-20

申请号：US13085510

申请日：2011-04-13

申请人： Mikio Shiono ,  Noriyuki Koike

发明人： Mikio Shiono ,  Noriyuki Koike

IPC分类号： C09J183/07 ,  C09J185/00 ,  C09J11/06

CPC分类号： C09D183/08 ,  C08G77/24 ,  C08L71/02

摘要： An adhesive composition is provided comprising (A) a fluorinated amide compound containing at least two vinyl groups and having a polyfluoro structure, (B) a fluorinated organosilicon compound containing a fluorinated organic group, at least two SiH groups, and an alkyl, aryl or aralkyl group, and (C) a platinum catalyst, and (D) an organosiloxane containing a SiH group and an epoxy and/or trialkoxysilyl group. The composition is cured on brief heating into a product which achieves adhesion to various substrates and has solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability, electric insulation, and acid resistance.

摘要翻译： 提供一种粘合剂组合物，其包含（A）含有至少两个乙烯基并具有多氟结构的氟化酰胺化合物，（B）含氟化有机基团的氟化有机硅化合物，至少两个SiH基团和烷基，芳基或 芳族烷基，（C）铂催化剂，（D）含有SiH基和环氧基和/或三烷氧基甲硅烷基的有机硅氧烷。 该组合物在短暂加热下固化成实现对各种基材的粘合性的产品，并具有耐溶剂性，耐化学性，耐热性，低温性，低透湿性，电绝缘性和耐酸性。

公开(公告)号：US08492478B2

公开(公告)日：2013-07-23

申请号：US13180966

申请日：2011-07-12

申请人： Kenichi Fukuda ,  Noriyuki Koike ,  Mikio Shiono

发明人： Kenichi Fukuda ,  Noriyuki Koike ,  Mikio Shiono

IPC分类号： C08F290/14 ,  C08F283/00 ,  A61K9/70 ,  B60C1/00 ,  C08G18/77 ,  C08K5/24

CPC分类号： C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C08L71/00

摘要： A curable perfluoropolyether gel composition is provided. The composition comprises (A) a straight chain fluorine-containing polymer represented by the following formula (1): (B) a polyfluoromonoalkenyl compound containing one alkenyl group per molecule and having a perfluoropolyether structure in its backbone, (C) an organosilicon compound containing at least two hydrogen atoms bonded to the silicon atom per molecule, and (D) a hydrosilylation catalyst. The composition can be produced into a cured product having excellent heat resistance, solvent resistance, chemical resistance, weatherability, releasability, water repellency, oil repellency, and the like as well as an improved acid resistance.

摘要翻译： 提供可固化的全氟聚醚凝胶组合物。 该组合物包含（A）由下式（1）表示的直链含氟聚合物：（B）每分子含有一个烯基并在其主链上具有全氟聚醚结构的多氟单链烯基化合物，（C）含有 每分子与硅原子键合的至少两个氢原子，和（D）氢化硅烷化催化剂。 可以将该组合物制成具有优异的耐热性，耐溶剂性，耐化学性，耐候性，脱模性，防水性，拒油性等的固化产品，以及改进的耐酸性。

公开(公告)号：US20120016081A1

公开(公告)日：2012-01-19

申请号：US13180966

申请日：2011-07-12

申请人： Kenichi Fukuda ,  Noriyuki Koike ,  Mikio Shiono

发明人： Kenichi Fukuda ,  Noriyuki Koike ,  Mikio Shiono

IPC分类号： C08G65/48 ,  C08G79/00 ,  C08G77/00 ,  C08G69/00

CPC分类号： C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C08L71/00

摘要： A curable perfluoropolyether gel composition is provided. The composition comprises (A) a straight chain fluorine-containing polymer represented by the following formula (1): (B) a polyfluoromonoalkenyl compound containing one alkenyl group per molecule and having a perfluoropolyether structure in its backbone, (C) an organosilicon compound containing at least two hydrogen atoms bonded to the silicon atom per molecule, and (D) a hydrosilylation catalyst. The composition can be produced into a cured product having excellent heat resistance, solvent resistance, chemical resistance, weatherability, releasability, water repellency, oil repellency, and the like as well as an improved acid resistance.

摘要翻译： 提供可固化的全氟聚醚凝胶组合物。 该组合物包含（A）由下式（1）表示的直链含氟聚合物：（B）每分子含有一个烯基并在其主链上具有全氟聚醚结构的多氟单链烯基化合物，（C）含有 每分子与硅原子键合的至少两个氢原子，和（D）氢化硅烷化催化剂。 可以将该组合物制成具有优异的耐热性，耐溶剂性，耐化学性，耐候性，脱模性，防水性，拒油性等的固化产品，以及改进的耐酸性。

公开(公告)号：US20120077041A1

公开(公告)日：2012-03-29

申请号：US13226987

申请日：2011-09-07

申请人： Yuji Yamane ,  Yasunori Sakano ,  Koichi Yamaguchi ,  Noriyuki Koike ,  Hirofumi Kishita

发明人： Yuji Yamane ,  Yasunori Sakano ,  Koichi Yamaguchi ,  Noriyuki Koike ,  Hirofumi Kishita

IPC分类号： C08L71/00 ,  C08L67/00 ,  B32B27/32 ,  C09D171/00

CPC分类号： C08G77/46 ,  C08G65/007 ,  C08G65/336 ,  C08G77/24 ,  C08G2650/48 ,  C09D171/02 ,  Y10T428/3154

摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.

摘要翻译： 含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物 由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％ ，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。

公开(公告)号：US20110218351A1

公开(公告)日：2011-09-08

申请号：US13111647

申请日：2011-05-19

申请人： Yasunori SAKANO ,  Takashi Matsuda ,  Noriyuki Koike

发明人： Yasunori SAKANO ,  Takashi Matsuda ,  Noriyuki Koike

IPC分类号： C07F7/10

CPC分类号： C07F7/0836 ,  C08G65/007 ,  C08G65/336

摘要： Disclosed is a method of storing a fluorine-containing disilanol compound represented by the following formula (3) in the presence of a tertiary amine in such an amount that a molar ratio of the tertiary amine to a silanol group of the fluorine-containing disilanol compound ranges from 0.001 to 20, HO—Z—R1—Rf—R1—Z—OH  (3) wherein Rf is a divalent fluorinated hydrocarbon group or a divalent fluorinated polyether group, R1 may be the same with or different from each other and is a substituted or unsubstituted divalent hydrocarbon group which may have at least one atom selected from the group consisting of oxygen, nitrogen, silicon, and sulfur atoms, and Z is a group represented by the following formula (2) —SiR2R3—  (2) wherein R2 and R3 may be the same with or different from each other and are monovalent organic groups.

摘要翻译： 本发明公开了一种在叔胺存在下，使下式（3）表示的含氟二硅烷醇化合物的存在量使得含氟二硅烷醇化合物的叔胺与硅烷醇基的摩尔比 范围为0.001〜20，HO-Z-R1-Rf-R1-Z-OH（3）其中Rf为二价氟化烃基或二价氟化聚醚基，R 1可以相同或不同， 可以具有选自氧，氮，硅和硫原子中的至少一个原子的取代或未取代的二价烃基，Z是由下式（2）-SiR 2 R 3 - （2）表示的基团，其中 R2和R3可以彼此相同或不同，并且是一价有机基团。

公开(公告)号：US08011717B2

公开(公告)日：2011-09-06

申请号：US12396543

申请日：2009-03-03

申请人： Toyokazu Endo ,  Masahiko Hara ,  Hiroyuki Kojima ,  Sumiaki Tanaka ,  Shinya Hashimoto ,  Noriyuki Koike

发明人： Toyokazu Endo ,  Masahiko Hara ,  Hiroyuki Kojima ,  Sumiaki Tanaka ,  Shinya Hashimoto ,  Noriyuki Koike

IPC分类号： B60J5/04 ,  B60R21/02

CPC分类号： B60J5/0451 ,  B60R21/0428 ,  B60R2021/0039

摘要： There is provided an automotive interior component including an impact absorber mounted to an interior side of a side wall panel of a vehicle, and the shape and structure of the impact absorber that can undergo buckling deformation and absorb an impact load in a side collision are improved to increase an impact absorbing function. The impact absorber 30 mounted on a back surface of an impact area IA in the automotive interior component (door trim) 10 is formed as a hollow box body having an opening 31 on one side and a bottom surface wall 32 on the other side, and improvement such as providing corner cut portions 34 at four corner portions of the bottom surface wall 32, forming a chamfered portion 333 at a corner portion of a side wall 33, or forming a cam groove portion 334, a triangular rib 36, or an inner surface rib 321 is made to adjust a reaction force in a side collision to increase an impact absorbing function.

摘要翻译： 提供了一种汽车内部部件，其包括安装在车辆的侧壁面板的内侧的冲击吸收件，并且能够经受弯曲变形并且吸收侧面碰撞中的冲击载荷的冲击吸收体的形状和结构得到改善 以增加冲击吸收功能。 安装在汽车内部部件（车门装饰件）10中的冲击区域IA的后表面上的冲击吸收器30形成为具有一侧的开口31和另一侧的底壁32的中空箱体， 在底壁32的四个角部设置角部切割部34，在侧壁33的角部形成倒角部333，或形成凸轮槽部334，三角肋36，内侧 制造表面肋321以调节侧面碰撞中的反作用力，以增加冲击吸收功能。

公开(公告)号：US20100317875A1

公开(公告)日：2010-12-16

申请号：US12797103

申请日：2010-06-09

申请人： Yasunori Sakano ,  Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita

发明人： Yasunori Sakano ,  Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita

IPC分类号： C07D307/04 ,  C07F7/10

CPC分类号： C08G77/50 ,  C07F7/21 ,  C08F230/08 ,  C08G77/388 ,  C08G77/46 ,  C09D183/12 ,  C09D183/14

摘要： The present invention relates to a photo-curable perfluoropolyether group-containing acrylate compound represented by the following formula (1): X1—[Z—Rf—Z—X2]v—Z—Rf—Z—X1  (1) wherein Rf is a divalent perfluoropolyether group; X1 is a group represented by the following formula (2): R2 is a group represented by the following formula (4): X2 is a group represented by the following formula (5): and Z is a divalent organic group.

摘要翻译： 本发明涉及由下式（1）表示的可光固化的全氟聚醚基丙烯酸酯化合物：X1- [Z-Rf-Z-X2] v-Z-Rf-Z-X1（1）其中Rf为 二价全氟聚醚基团; X1是由下式（2）表示的基团：R2是由下式（4）表示的基团：X2是由下式（5）表示的基团：Z是二价有机基团。

公开(公告)号：US20100160588A1

公开(公告)日：2010-06-24

申请号：US12620782

申请日：2009-11-18

申请人： Noriyuki Koike ,  Takashi Matsuda ,  Hirofumi Kishita

发明人： Noriyuki Koike ,  Takashi Matsuda ,  Hirofumi Kishita

IPC分类号： C08F130/08 ,  C07F7/10

CPC分类号： C07F7/081

摘要： The purpose of the present invention is to provide an organic silicon compound which has a vinyl group more reactive than those of the conventional organic silicon compounds and can be bonded with another compound.The present organic silicon compound is represented by the following formula (1), wherein R1 is, independently of each other, a vinyl group or an alkyl group having 1 to 4 carbon atoms, R2 is an alkylene group having 3 to 6 carbon atoms, and R3 is, independently of each other, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and optionally substituted with one or more fluorine atoms.

摘要翻译： 本发明的目的是提供一种有机硅化合物，其具有比常规有机硅化合物更具反应活性的乙烯基，并可与另一种化合物结合。 本发明的有机硅化合物由下式（1）表示，其中R 1彼此独立地为乙烯基或具有1至4个碳原子的烷基，R 2为具有3至6个碳原子的亚烷基， 并且R 3彼此独立地为氢原子或具有1至4个碳原子并且任选被一个或多个氟原子取代的烷基。

公开(公告)号：US07332538B2

公开(公告)日：2008-02-19

申请号：US10791861

申请日：2004-03-04

申请人： Hidenori Koshikawa ,  Noriyuki Koike

发明人： Hidenori Koshikawa ,  Noriyuki Koike

IPC分类号： C08L27/12

CPC分类号： C08K3/36 ,  C08K3/04 ,  C08K9/04 ,  C08L71/02

摘要： A heat-curable fluoropolyether rubber composition comprising (A) 100 pbw of a straight-chain perfluoropolyether compound having at least two alkenyl groups in a molecule, (B) 1-100 pbw of a reinforcing filler, and (C) 0.1-5 pbw of an organic peroxide is freed from cure inhibition by catalyst poisons, and its cured rubber has improved properties including heat resistance, chemical resistance, solvent resistance, parting property, water repellency, oil repellency and low-temperature properties.

摘要翻译： 一种可热固化的氟聚醚橡胶组合物，其包含（A）100pbw的在分子中具有至少两个烯基的直链全氟聚醚化合物，（B）1-100pbw的增强填料和（C）0.1-5pbw 的有机过氧化物不受催化剂毒物的固化抑制，其固化橡胶具有改进的性能，包括耐热性，耐化学性，耐溶剂性，脱模性，防水性，拒油性和低温性能。