公开(公告)号：US08765016B2

公开(公告)日：2014-07-01

申请号：US13574409

申请日：2010-02-26

申请人： Mingjie Zhou ,  Xiaofang Liang ,  Jun Liu ,  Qiurong Liao

发明人： Mingjie Zhou ,  Xiaofang Liang ,  Jun Liu ,  Qiurong Liao

IPC分类号： C09K11/77

CPC分类号： C09K11/778

摘要： A green luminescent material of terbium doped gadolinium borate is provided. The luminescent material has a formula of M3Gd1-xTbx(BO3)3, wherein, M is alkaline earth metal element and x is 0.005-0.5. The method for preparing the luminescent material comprises the following steps: selecting the source compounds of alkaline earth metal ion, boric acid radical ion (BO33−), Gd3+ and Tb3+ by the stoichiometric ratio, wherein, the stoichiometric ratio is the molar ratio of the corresponding element in the formula of M3Gd1-xTbx(BO3)3, and the source compound of BO33− is over 10%-30% by the molar ratio; mixing; pre-treatment by sintering; cooling; grinding; calcination; and cooling to obtain the luminescent material.

摘要翻译： 提供掺铽硼酸钆的绿色发光材料。 发光材料具有M3Gd1-xTbx（BO3）3的式，其中M是碱土金属元素，x是0.005-0.5。 制备发光材料的方法包括以化学计量比选择碱土金属离子，硼酸根离子（BO33-），Gd3 +和Tb3 +的源化合物，其中化学计量比是 M3Gd1-xTbx（BO3）3中的相应元素，BO33-的源化合物的摩尔比为10％-30％以上; 混合; 烧结预处理; 冷却; 研磨 煅烧; 并冷却以获得发光材料。

公开(公告)号：US08986573B2

公开(公告)日：2015-03-24

申请号：US13574528

申请日：2010-02-04

申请人： Mingjie Zhou ,  Jun Liu ,  Xiaofang Liang ,  Shiliang Liu ,  Qiurong Liao

发明人： Mingjie Zhou ,  Jun Liu ,  Xiaofang Liang ,  Shiliang Liu ,  Qiurong Liao

IPC分类号： C09K11/71 ,  C01F17/00 ,  C01F7/16 ,  C01B25/45 ,  C09K11/77

CPC分类号： C01F7/168 ,  C01B25/45 ,  C01F7/16 ,  C09K11/7778

摘要： Terbium doped phosphate-based green luminescent material and preparation method thereof are provided. The chemical formula of the material is M3RE1-xTbx(PO4)3, wherein, M is alkaline-earth metals, RE is rare-earth elements, x is in a range of 0.001 to 1. The preparation method of the material includes the following steps; providing the compound used as the source of alkaline earth metal, the compound used as the source of phosphate, the compound used as the source of rare-earth, and the compound used as the source of Tb3+ according to the molar ratio of the elements in M3RE1-xTbx(PO4)3, wherein, the compound used as the source of phosphate is added at excess molar ratio in a range of 10% to 30%; mixing and grinding the compound to get mixture; sintering the mixture as pre-treatment, and then cooling the mixture to get a sintered matter; grinding; calcining in reducing atmosphere, and then cooling them.

摘要翻译： 提供掺铒磷酸盐绿色发光材料及其制备方法。 该材料的化学式为M3RE1-xTbx（PO4）3，其中M为碱土金属，RE为稀土元素，x为0.001〜1。该材料的制备方法包括以下 脚步; 提供用作碱土金属源的化合物，用作磷酸盐源的化合物，用作稀土源的化合物，以及用作Tb 3+源的化合物，根据元素的摩尔比 M3RE1-xTbx（PO4）3，其中，用作磷酸盐源的化合物以10％至30％的过量摩尔比加入; 混合和研磨该化合物以得到混合物; 烧结混合物作为预处理，然后冷却混合物得到烧结物质; 研磨 在还原气氛中煅烧，然后冷却。

公开(公告)号：US20120286206A1

公开(公告)日：2012-11-15

申请号：US13574409

申请日：2010-02-26

申请人： Mingjie Zhou ,  Xiaofang Liang ,  Jun Liu ,  Qiurong Liao

发明人： Mingjie Zhou ,  Xiaofang Liang ,  Jun Liu ,  Qiurong Liao

IPC分类号： C09K11/78

CPC分类号： C09K11/778

摘要： A green luminescent material of terbium doped gadolinium borate is provided. The luminescent material has a formula of M3Gd1-xTbx(BO3)3, wherein, M is alkaline earth metal element and x is 0.005-0.5. The method for preparing the luminescent material comprises the following steps: selecting the source compounds of alkaline earth metal ion, boric acid radical ion (BO33−), Gd3+ and Tb3+ by the stoichiometric ratio, wherein, the stoichiometric ratio is the molar ratio of the corresponding element in the formula of M3Gd1-xTbx(BO3)3, and the source compound of BO33 is over 10%-30% by the molar ratio; mixing; pre-treatment by sintering; cooling; grinding; calcination; and cooling to obtain the luminescent material.

摘要翻译： 提供掺铽硼酸钆的绿色发光材料。 发光材料具有M3Gd1-xTbx（BO3）3的式，其中M是碱土金属元素，x是0.005-0.5。 制备发光材料的方法包括以化学计量比选择碱土金属离子，硼酸根离子（BO33-），Gd3 +和Tb3 +的源化合物，其中化学计量比是 M3Gd1-xTbx（BO3）3式中的相应元素，BO33的源化合物的摩尔比为10％-30％以上; 混合; 烧结预处理; 冷却; 研磨 煅烧; 并冷却以获得发光材料。

公开(公告)号：US08961826B2

公开(公告)日：2015-02-24

申请号：US13702151

申请日：2010-06-09

申请人： Mingjie Zhou ,  Xiaofang Liang ,  Wenbo Ma

发明人： Mingjie Zhou ,  Xiaofang Liang ,  Wenbo Ma

IPC分类号： C09K11/66 ,  C09K11/77

CPC分类号： C09K11/7787

摘要： A luminescent material and a preparation method thereof are provided. The said luminescent material is represented by the following chemical formula: Ln2-xEuxSn2O7, wherein Ln is selected from one of Gd, Y and La, 0.1≦x≦1.5. The said luminescent material has good electrical performance, anti-electron bombardment and stable luminescent property. It is appropriate to be used in field emission light-emitting devices. The said preparation method has simple technique, no pollution, manageable process conditions, low preparation temperature and low equipment requirement, and is beneficial to industry production.

摘要翻译： 提供发光材料及其制备方法。 所述发光材料由以下化学式表示：Ln2-xEuxSn2O7，其中Ln选自Gd，Y和La中的一种，0.1＆nlE; x＆nlE; 1.5。 所述发光材料具有良好的电性能，抗电子轰击和稳定的发光性能。 适用于场发射发光装置。 所述制备方法技术简单，无污染，工艺条件可控，制备温度低，设备要求低，有利于工业生产。

公开(公告)号：US20130075656A1

公开(公告)日：2013-03-28

申请号：US13702151

申请日：2010-06-09

申请人： Mingjie Zhou ,  Xiaofang Liang ,  Wenbo Ma

发明人： Mingjie Zhou ,  Xiaofang Liang ,  Wenbo Ma

IPC分类号： C09K11/77

CPC分类号： C09K11/7787

摘要： A luminescent material and a preparation method thereof are provided. The said luminescent material is represented by the following chemical formula: Ln2−EuxSn2O7, wherein Ln is selected from one of Gd, Y and La, 0.1≦x≦1.5. The said luminescent material has good electrical performance, anti-electron bombardment and stable luminescent property. It is appropriate to be used in field emission light-emitting devices. The said preparation method has simple technique, no pollution, manageable process conditions, low preparation temperature and low equipment requirement, and is beneficial to industry production.

摘要翻译： 提供发光材料及其制备方法。 所述发光材料由以下化学式表示：Ln2-EuxSn2O7，其中Ln选自Gd，Y和La中的一种，0.1＆nlE; x＆amp; ll; 1.5。 所述发光材料具有良好的电性能，抗电子轰击和稳定的发光性能。 适用于场发射发光装置。 所述制备方法技术简单，无污染，工艺条件可控，制备温度低，设备要求低，有利于工业生产。