公开(公告)号：US20090076312A1

公开(公告)日：2009-03-19

申请号：US11857160

申请日：2007-09-18

申请人： Mitchell E. Loescher ,  Lawrence A. Smith, JR.

发明人： Mitchell E. Loescher ,  Lawrence A. Smith, JR.

IPC分类号： C07C41/09 ,  B01J8/02

CPC分类号： C07C41/06 ,  C07C43/046

摘要： A process for the conversion of tertiary butyl alcohol to ethyl tertiary butyl ether, including: dehydrating tertiary butyl alcohol to form a product stream comprising isobutylene and water; separating the product stream to form an isobutylene-rich fraction and a water-rich fraction; separating the water-rich fraction to recover a hydrocarbon fraction and a water fraction having less than 1 ppm hydrocarbon content; reacting isobutylene in the isobutylene-rich fraction with ethanol to form a reaction product comprising ethyl tertiary butyl ether; separating the reaction product to recover unreacted ethanol and an ethyl tertiary butyl ether stream; and recycling at least a portion of the unreacted ethanol to the reacting; wherein the ethyl tertiary butyl ether stream comprises at least 99 weight percent ethyl tertiary butyl ether.

摘要翻译： 一种将叔丁醇转化为乙基叔丁基醚的方法，包括：脱水叔丁醇以形成包含异丁烯和水的产物流; 分离产物流以形成富含异丁烯的级分和富水级分; 分离富水馏分以回收烃馏分和具有小于1ppm烃含量的水馏分; 使富含异丁烯的馏分中的异丁烯与乙醇反应，形成包含乙基叔丁基醚的反应产物; 分离反应产物以回收未反应的乙醇和乙基叔丁基醚料流; 并将至少一部分未反应的乙醇再循环到反应中; 其中乙基叔丁基醚流包含至少99重量％的乙基叔丁基醚。

公开(公告)号：US20100076241A1

公开(公告)日：2010-03-25

申请号：US12234153

申请日：2008-09-19

申请人： Mitchell E. Loescher ,  William M. Cross, JR. ,  Lawrence A. Smith, JR.

发明人： Mitchell E. Loescher ,  William M. Cross, JR. ,  Lawrence A. Smith, JR.

IPC分类号： C07C2/58

CPC分类号： C07C9/16 ,  C07C2/868 ,  C07C2527/054 ,  C10G29/205

摘要： A process for alkylation of propylene, the process including: contacting a stream comprising propylene and propane with sulfuric acid in a first reaction zone under conditions to form propylene sulfate esters; contacting the propylene sulfate esters with isoparaffin and sulfuric acid in an alkylation reaction zone under conditions to react the propylene sulfate esters and the isoparaffin to form a reactor effluent comprising an acid phase and a hydrocarbon phase comprising unreacted isoparaffin and alkylate product; separating the hydrocarbon phase from the sulfuric acid; separating the hydrocarbon phase to form a fraction comprising unreacted isoparaffin and a fraction comprising the alkylate product.

摘要翻译： 一种用于丙烯烷基化的方法，该方法包括：在条件下使第一反应区中包含丙烯和丙烷的物流与硫酸接触以形成丙烯硫酸酯; 在使丙烯硫酸酯和异链烷烃反应的条件下使烷基化反应区中的丙烯硫酸酯与异链烷烃和硫酸接触以形成包含酸相和包含未反应的异链烷烃和烷基化物产物的烃相的反应器流出物; 从硫酸中分离烃相; 分离烃相以形成包含未反应的异链烷烃的馏分和包含烷基化产物的级分。

公开(公告)号：US20100081854A1

公开(公告)日：2010-04-01

申请号：US12243459

申请日：2008-10-01

申请人： William M. Cross, JR. ,  Lawrence A. Smith, JR. ,  Gary G. Podrebarac

发明人： William M. Cross, JR. ,  Lawrence A. Smith, JR. ,  Gary G. Podrebarac

IPC分类号： C07C2/00

CPC分类号： C07C7/10 ,  Y02P20/127 ,  C07C11/02

摘要： A process for treating an alkylation feedstock comprising olefins, n-alkanes, iso-alkanes, and impurities including one or more of butadiene, oxygenates, nitrogen-containing compounds, and sulfur-containing compounds, the process including: contacting an alkylation feedstock containing at least one of oxygenates and nitrogen-containing compounds with water to produce a hydrocarbon fraction having a reduced concentration of the at least one of oxygenates and nitrogen-containing compounds and an aqueous fraction comprising at least a portion of the at least one of oxygenates and nitrogen-containing compounds; separating water from the hydrocarbon fraction having a reduced concentration to produce a hydrocarbon fraction having a reduced water content; contacting the hydrocarbon fraction having a reduced water content with an oligomerization catalyst in a first oligomerization reaction zone under oligomerization conditions to react at least a portion of the olefins to form a reactor effluent comprising olefin oligomers; and feeding at least a portion of the reactor effluent to an alkylation unit.

摘要翻译： 一种处理包含烯烃，正烷烃，异烷烃和包括丁二烯，含氧化合物，含氮化合物和含硫化合物中的一种或多种的杂质的烷基化原料的方法，所述方法包括：将含有 含氧化合物和含氮化合物中的至少一种与水一起产生具有降低的含氧化合物和含氮化合物中的至少一种的浓度的烃馏分和含有至少一部分含氧化合物和氮气的含水部分 含有化合物; 从具有降低的浓度的烃馏分中分离水以产生具有降低的水含量的烃馏分; 在低聚反应条件下使第一低聚反应区中的含低级烃含量的烃馏分与低聚催化剂接触，使至少一部分烯烃反应形成包含烯烃低聚物的反应器流出物; 并将至少一部分反应器流出物进料至烷基化单元。

公开(公告)号：US20090200205A1

公开(公告)日：2009-08-13

申请号：US12029109

申请日：2008-02-11

申请人： Lawrence A. Smith, JR. ,  William M. Cross, JR.

发明人： Lawrence A. Smith, JR. ,  William M. Cross, JR.

IPC分类号： C10G17/02

CPC分类号： C10G17/06

摘要： A process for reducing the sulfur content of a gasoline fraction comprising one or more organic sulfur compounds including mercaptans, thiophenes, and mono- and di-sulfides, the process including: contacting a gasoline fraction having an initial organic sulfur content with a sulfuric acid-rich composition to extract organic sulfur compounds from the gasoline fraction and produce a gasoline fraction having reduced sulfur content and a sulfuric acid fraction having increased organic sulfur content; and separating the gasoline fraction having reduced organic sulfur content and the sulfuric acid-rich fraction having increased organic sulfur content.

摘要翻译： 一种降低包含一种或多种有机硫化合物的汽油馏分的硫含量的方法，所述有机硫化合物包括硫醇，噻吩和一硫化物和二硫化物，该方法包括：将具有初始有机硫含量的汽油馏分与硫酸 - 从汽油馏分提取有机硫化合物并产生具有降低的硫含量的汽油馏分和具有增加的有机硫含量的硫酸馏分; 并且分离具有降低的有机硫含量的汽油馏分和具有增加的有机硫含量的富含硫酸的馏分。

公开(公告)号：US20120203039A1

公开(公告)日：2012-08-09

申请号：US12931521

申请日：2011-02-03

申请人： Lawrence A. Smith, JR.

发明人： Lawrence A. Smith, JR.

IPC分类号： C10L1/16

CPC分类号： C10L1/04 ,  C10G9/36 ,  C10G45/08 ,  C10G45/38 ,  C10G69/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2400/02

摘要： A single stage process for treating pyrolysis gasoline containing acetylene, diolefins, sulfur compounds and nitrogen compounds to react a sufficient amount of said acetylene and diolefins with hydrogen to produce saturated products and hydrogen sulfide to provide a pyrolysis gasoline product suitably for use as gasoline blending stock comprising: feeding pyrolysis gasoline and hydrogen at a mol ratio of hydrogen to pyrolysis gasoline of at least 0.5:1 and preferably in the range of 1:1 to 3:1 to a hydrodesulfurization zone containing a hydrodesulfurization catalyst such as cobalt/molybdenum under vapor phase conditions at a pressure in the range of 200 to 500 psig at a temperature in the range of 550° F. to 850° F. The operating temperature is at least above the dew point of the mixture of pyrolysis gasoline and hydrogen, preferably in a range 50 to 400° F. above said dew point.

摘要翻译： 用于处理含有乙炔，二烯烃，硫化合物和氮化合物的裂解汽油的单阶段方法，以使足够量的所述乙炔和二烯烃与氢反应以产生饱和产物和硫化氢，以提供适合用作汽油混合原料的热解汽油产物 包括：以高于摩尔比的氢气将热解汽油和氢气与至少0.5:1，优选在1:1至3:1范围内的热解汽油加入到含有加氢脱硫催化剂例如钴/钼的加氢脱硫区 在550°F至850°F范围内的温度下，在200至500psig范围内的压力下的相位条件。工作温度至少高于热解汽油和氢气的混合物的露点，优选在 在所述露点以上50至400°F的范围。

公开(公告)号：US20090105513A1

公开(公告)日：2009-04-23

申请号：US12251623

申请日：2008-10-15

申请人： Lawrence A. Smith, JR. ,  William M. Cross, JR.

发明人： Lawrence A. Smith, JR. ,  William M. Cross, JR.

IPC分类号： C07C2/56

CPC分类号： C10G57/005 ,  C07C2/62 ,  C10G29/205 ,  C10G57/00 ,  C10G57/02 ,  C10G69/12 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/4081 ,  C07C9/16

摘要： A process for the alkylation of isobutane is disclosed wherein isobutane is fed to two separate alkylation systems. The effluent from the first alkylation system is fed to an interim debutanizer where the C4's are separated from the alkylate product. The overhead C4 product is then fed to the second alkylation system to provide the isobutane. The effluent from the second alkylation system is fed to a traditional deisobutanizer to prevent any build up of normal butanes in the system.

摘要翻译： 公开了一种用于异丁烷烷基化的方法，其中将异丁烷进料至两个单独的烷基化体系。 将来自第一烷基化系统的流出物进料到临时脱丁烷塔，其中C4与烷基化产物分离。 然后将塔顶C4产物进料至第二烷基化系统以提供异丁烷。 来自第二烷基化系统的流出物被供给到传统的去异丁烷化器以防止系统中正常丁烷的任何积聚。

公开(公告)号：US20100063334A1

公开(公告)日：2010-03-11

申请号：US12206039

申请日：2008-09-08

申请人： Montri Vichailak ,  Purvis K. Ho ,  Martinus J. Almering ,  Arvids Judzis, JR. ,  Willibrord A. Groten ,  Lawrence A. Smith, JR. ,  Yongqiang Xu

发明人： Montri Vichailak ,  Purvis K. Ho ,  Martinus J. Almering ,  Arvids Judzis, JR. ,  Willibrord A. Groten ,  Lawrence A. Smith, JR. ,  Yongqiang Xu

IPC分类号： C07C7/163

CPC分类号： C10G45/44 ,  C10G35/04 ,  C10G65/04 ,  Y02P20/127 ,  Y02P20/132

摘要： A process for reducing the concentration of benzene in a hydrocarbon stream, the process including: fractionating a reformate to form a benzene concentrate fraction comprising benzene and other C6 hydrocarbons, and a heavies fraction comprising C7+ hydrocarbons; and hydrogenating the benzene concentrate fraction to form a hydrocarbon fraction having a reduced benzene concentration.

摘要翻译： 一种用于降低烃流中苯浓度的方法，该方法包括：将重整产物分馏以形成含有苯和其它C 6烃的苯浓缩物馏分，以及包含C7 +烃的重馏分; 并将苯浓缩物馏分氢化以形成苯浓度降低的烃馏分。

公开(公告)号：US20100048970A1

公开(公告)日：2010-02-25

申请号：US12195118

申请日：2008-08-20

申请人： Christopher C. Boyer ,  Lawrence A. Smith, JR. ,  Arvids Judzis, JR. ,  John R. Adams

发明人： Christopher C. Boyer ,  Lawrence A. Smith, JR. ,  Arvids Judzis, JR. ,  John R. Adams

IPC分类号： C07C2/64

CPC分类号： C07C2/66 ,  Y02P20/127 ,  C07C15/085 ,  C07C15/02

摘要： A process for reformate benzene reduction, the process including: feeding a light reformate fraction, an olefin feed, and an alkylation catalyst to an alkylation reaction zone; contacting the light reformate fraction and the olefin feed in the presence of the alkylation catalyst in the alkylation reaction zone to convert at least a portion of the benzene and the olefin to a monoalkylate; recovering a catalyst fraction from an alkylation reaction zone effluent; and recovering a light reformate product having a reduced benzene content.

摘要翻译： 一种重整苯还原的方法，该方法包括：将轻质重整油馏分，烯烃进料和烷基化催化剂进料至烷基化反应区; 在烷基化反应区中在烷基化催化剂存在下使轻重整油馏分和烯烃进料接触，将至少一部分苯和烯烃转化成单烷基化物; 从烷基化反应区流出物回收催化剂级分; 并回收苯含量降低的轻质重整产物。

公开(公告)号：US20090069607A1

公开(公告)日：2009-03-12

申请号：US11852923

申请日：2007-09-10

申请人： Lawrence A. Smith, JR. ,  Abraham P. Gelbein ,  Christopher C. Boyer

发明人： Lawrence A. Smith, JR. ,  Abraham P. Gelbein ,  Christopher C. Boyer

IPC分类号： C07C41/01

CPC分类号： C07C41/09 ,  Y02P20/127 ,  C07C43/043

摘要： A process for the production of dialkyl ether, the process including: feeding a stream comprising an alkyl alcohol to a distillation column reactor system; concurrently in the distillation column reactor system: i) contacting the alkyl alcohol with a catalytic distillation structure in a distillation reaction zone thereby catalytically reacting at least a portion of the alkyl alcohol to form a corresponding dialkyl ether and water; and ii) fractionating the resulting dialkyl ether from the water; operating the distillation column reactor system to obtain substantially complete conversion of the alkyl alcohol to form the corresponding dialkyl ether and water; recovering the dialkyl ether from the distillation column reactor as an overheads fraction; recovering the water from the distillation column reactor as a bottoms fraction.

摘要翻译： 一种制备二烷基醚的方法，该方法包括：将包含烷基醇的物流进料到蒸馏塔反应器系统; 在蒸馏塔反应器系统中同时进行：i）在蒸馏反应区中使烷基醇与催化蒸馏结构接触，从而使至少一部分烷基醇催化反应形成相应的二烷基醚和水; 和ii）从水中分馏得到的二烷基醚; 操作蒸馏塔反应器系统以获得烷基醇的基本上完全转化以形成相应的二烷基醚和水; 从塔顶反应器中回收二烷基醚作为塔顶馏分; 从蒸馏塔反应器中回收水作为塔底馏分。

公开(公告)号：US20100179362A1

公开(公告)日：2010-07-15

申请号：US12352198

申请日：2009-01-12

申请人： Lawrence A. Smith, JR. ,  William M. Cross, JR.

发明人： Lawrence A. Smith, JR. ,  William M. Cross, JR.

IPC分类号： C07C2/00

CPC分类号： C07C2/28 ,  B01J31/10 ,  B01J2231/20 ,  B01J2531/16 ,  C07C2527/173 ,  C07C2531/10 ,  C10G29/205 ,  Y02P20/127

摘要： A process for the dimerization of isoolefins, including: contacting an isoolefin with a solid catalyst composition passivated with at least one of an ether, an alcohol, and water; wherein the solid catalyst composition comprises at least one of a solid phosphoric acid catalyst and a resin of a macroporous matrix of polyvinyl aromatic compound crosslinked with a divinyl compound and having thereon from about 3 to 5 milli equivalents of sulfonic acid groups per gram of dry resin; and wherein at least 50% to less than 100% of acid groups in the solid catalyst composition are neutralized with a metal of Al, Fe, Zn, Cu, Ni, or mixtures thereof. The catalyst may be metalized prior to placement in a reactor or may be metalized in situ.

摘要翻译： 一种异烯烃二聚的方法，包括：使异烯烃与用醚，醇和水中的至少一种钝化的固体催化剂组合物接触; 其中所述固体催化剂组合物包含固体磷酸催化剂和与二乙烯基化合物交联的聚乙烯基芳族化合物的大孔基体的树脂中的至少一种，并且其上具有约3至5毫当量的磺酸基团/克干树脂 ; 并且其中固体催化剂组合物中的至少50％至小于100％的酸基团被Al，Fe，Zn，Cu，Ni或其混合物的金属中和。 催化剂可以在放置在反应器中之前被金属化，或者可以原位金属化。