公开(公告)号：US4481271A

公开(公告)日：1984-11-06

申请号：US330548

申请日：1981-12-14

申请人： Mitsuru Hashimoto ,  Kiyoshi Sakai ,  Toshio Fukagai ,  Tatsuya Katoh, deceased ,  by Mankichi Katoh, legal representative

发明人： Mitsuru Hashimoto ,  Kiyoshi Sakai ,  Toshio Fukagai ,  Tatsuya Katoh, deceased ,  by Mankichi Katoh, legal representative

IPC分类号： G03G5/06

CPC分类号： G03G5/0616 ,  G03G5/0679

摘要： A layered electrophotographic photoconductor whose charge generation layer comprises a bisazo pigment selected from the group consisting of the bisazo pigments represented by the following general formula (I) and whose charge transport layer contains a charge transport material selected from the group consisting of the hydrazone compounds represented by the following general formula (2): ##STR1## wherein A represents --C.sub.6 H.sub.4 --Cl(o), --C.sub.6 H.sub.4 --Cl(m), --C.sub.6 H.sub.4 --Br(o), --C.sub.6 H.sub.4 --Br(m), --C.sub.6 H.sub.4 --F(o), --C.sub.6 H.sub.4 --F(m), --C.sub.6 H.sub.4 --F(p), or --C.sub.6 H.sub.4 --I(m), ##STR2## wherein R.sup.1 represents a substituted or non-substituted naphthyl group, a substituted or non-substituted anthryl group, a substituted or non-substituted styryl group, or ##STR3## wherein B represents hydrogen, an alkyl group with one to three carbon atoms, an alkoxy group with one to three carbon atoms, a dialkylamino group, halogen, a nitro group, or a hydroxy group, and n represents an integer of 1 to 5, and when n is 2 or more, B can be different or identical to each other; R.sup.2 represents an alkyl group, a benzyl group; and R.sup.3 represents a phenyl group or a methoxyphenyl group.

摘要翻译： 一种层状电子照相感光体，其电荷产生层包含选自由以下通式（I）表示的双偶氮颜料组成的组的双偶氮颜料，其电荷输送层含有选自由以下的腙化合物组成的组中的电荷输送材料： （2）表示：其中A表示-C 6 H 4 -C（o），-C 6 H 4 -Cl（m），-C 6 H 4 -Br（o），-C 6 H 4 -Br（m） -C6H4-F（o），-C6H4-F（m），-C6H4-F（p）或-C6H4-I（m），其中R1表示取代或未取代的萘基， 或未取代的苯基，取代或未取代的苯乙烯基，或者其中B表示氢，具有1-3个碳原子的烷基，具有1-3个碳原子的烷氧基，二烷基氨基，卤素 ，硝基或羟基，n表示1〜5的整数，当n为2以上时，B可以不同或相同 对彼此; R2表示烷基，苄基， R 3表示苯基或甲氧基苯基。

公开(公告)号：US4332948A

公开(公告)日：1982-06-01

申请号：US149752

申请日：1980-05-14

申请人： Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Kyoji Tsutsui

发明人： Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Kyoji Tsutsui

IPC分类号： C07C67/00 ,  C07C241/00 ,  C07C251/86 ,  C07D213/53 ,  C07D307/36 ,  C07D307/52 ,  C07D333/20 ,  C07D333/22 ,  C07D333/36 ,  C09B26/02 ,  G03C1/72 ,  G03G5/06 ,  C07C109/12

CPC分类号： C07D213/53 ,  C07C251/72 ,  C07D307/52 ,  C07D333/22 ,  G03G5/0616 ,  G03G5/0629 ,  G03G5/0637

摘要： Hydrazone compounds having the general formula ##STR1## wherein Ar is selected from the group consisting of a naphthalene ring radical, substituted naphthalene ring radicals, an anthracene ring radical, substituted anthracene ring radicals, styryl, substituted styryls, a pyridine radical, a furan ring radical and a thiophene ring radical.The hydrazone compounds can be prepared by allowing 1-methyl-1-phenylhydrazine having the formula ##STR2## to react with an aldehyde represented by the general formula Ar-CHO, wherein Ar is the same as mentioned above at a substantially equal molar ratio in an organic solvent selected from the group consisting of lower alcohols, cyclic ethers, cellosolves, N,N-dimethylforamide and acetic acid, in the presence of an acid catalyst, by heating and refluxing the reaction mixture.The hydrazone compounds are extremely useful as charge transport materials for use in electrophotographic photoconductors of the type comprising an electroconductive support material and a photosensitive layer containing a charge generation material and a charge transport material.

摘要翻译： 具有通式的腙化合物，其中Ar选自萘环基，取代萘环基，蒽环基，取代的蒽环，苯乙烯基，取代的苯乙烯基，吡啶基，呋喃环 自由基和噻吩环基团。 腙化合物可以通过使具有式“IMAGE”的1-甲基-1-苯肼与通式Ar-CHO表示的醛反应来制备，其中Ar与上述相同，其摩尔比基本相等 在酸催化剂存在下，通过加热和回流反应混合物，选自低级醇，环醚，溶纤剂，N，N-二甲基甲酰胺和乙酸的有机溶剂。 腙化合物作为用于电子照相感光体的电荷传输材料是非常有用的，其中包括导电载体材料和含有电荷产生材料和电荷传输材料的感光层。

公开(公告)号：US4279981A

公开(公告)日：1981-07-21

申请号：US897508

申请日：1978-04-18

申请人： Masafumi Ohta ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Akio Kozima ,  Masaomi Sasaki

发明人： Masafumi Ohta ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Akio Kozima ,  Masaomi Sasaki

IPC分类号： C09B35/378 ,  G03G5/06

CPC分类号： G03G5/0687 ,  C09B35/378

摘要： The present invention provides trisazo compounds expressed by the general formula I ##STR1## [wherein A represents ##STR2## (wherein R represents hydrogen, alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, and n is an integer of 1, 2 or 3, R may be either identical or different when n is an integer of 2 or 3)]; a process for the preparation of said trisazo compounds; and electrophotographic sensitive materials having a high sensitivity as well as a high flexibility which comprise a conductive support and a photosensitive layer containing a trisazo compound, as an effective ingredient thereof, which is expressed by the general formula II ##STR3## [wherein A' represents ##STR4## (wherein Z represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as indole ring, carbazole ring, benzofuran ring, etc. or their substituents, Ar.sub.1 represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as dibenzofuran ring, etc. or their substituents, Ar.sub.2 and Ar.sub.3 represent aromatic rings such as benzene ring, naphthalene ring, etc. or their substituents, R.sub.1 and R.sub.3 represent hydrogen, lower alkyl radical, phenyl radical or their substituents, and R.sub.2 represents lower alkyl radical, carboxyl radical or their esters)].

摘要翻译： 本发明提供由通式I表示的三偶氮化合物，其中A代表氢，烷基，烷氧基，硝基，二烷基氨基 或卤素，n为1,2或3的整数，当n为2或3的整数时，R可以相同或不同）。 一种制备所述三偶氮化合物的方法; 和具有高灵敏度的电子照相感光材料以及包含导电性支持体和含有三偶氮化合物的感光层作为其有效成分的高柔性，其由通式II表示[其中A'表示 （其中Z表示芳环如苯环，萘环等，杂环如吲哚环，咔唑环，苯并呋喃环等）或其取代基，Ar1表示芳环如苯环，萘环 等等，杂环如二苯并呋喃环等或其取代基，Ar 2和Ar 3表示芳环如苯环，萘环等或其取代基，R 1和R 3表示氢，低级烷基，苯基或 它们的取代基，R 2代表低级烷基，羧基或它们的酯）]。

公开(公告)号：US4272598A

公开(公告)日：1981-06-09

申请号：US898130

申请日：1978-04-20

申请人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Akio Kozima

发明人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Akio Kozima

IPC分类号： C09B35/215 ,  C09B56/06 ,  G03G5/06 ,  G03G13/22

CPC分类号： G03G5/0683 ,  C09B35/215 ,  C09B56/06

摘要： The present invention provides disazo compounds expressed by the general formula I ##STR1## [wherein A represents ##STR2## (wherein R represents alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, n is 0 or an integer of 1, 2 or 3, and R may be either identical or different when n is an integer of 2 or 3)]; a process for the preparation of said compounds; and electrophotographic sensitive materials having a high sensitivity as well as a high flexibility which comprise a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing a disazo compound, as an effective ingredient, which is expressed by the general formula II ##STR3## [wherein A' represents ##STR4## (wherein X represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as indole ring, carbazole ring, benzofuran ring, etc. or their substituents, Ar.sub.1 represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as dibenzofuran, etc. or their substituents, Ar.sub.2 and Ar.sub.3 represent aromatic rings such as benzene ring, naphthalene ring, etc. or their substituents, R.sub.1 and R.sub.3 represent respectively hydrogen, lower alkyl radical, phenyl radical or their substituents, and R.sub.2 represents lower alkyl radical, carboxyl radical or their esters)].

摘要翻译： 本发明提供由通式I表示的双偶氮化合物[其中A表示（其中R表示烷基，烷氧基，硝基，二烷基氨基或卤素，n为0或 1或2或3的整数，当n为2或3的整数时，R可以相同或不同）。 一种制备所述化合物的方法; 和具有高灵敏度的电子照相感光材料以及包含导电性支持体和形成在其上的感光层的高柔性，所述感光层含有双偶氮化合物作为有效成分，其由通式II表示。 + TR 其中A'表示 + TR （其中X表示芳环如苯环，萘环等，杂环如吲哚环，咔唑环，苯并呋喃环等 或它们的取代基，Ar 1表示芳环如苯环，萘环等，杂环如二苯并呋喃等或其取代基，Ar2和Ar3表示芳环如苯环，萘环等或其取代基 ，R1和R3分别代表氢，低级烷基，苯基或它们的取代基，R2代表低级烷基，羧基或它们的酯）]。

公开(公告)号：US4251613A

公开(公告)日：1981-02-17

申请号：US908116

申请日：1978-05-22

申请人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Kyoji Tsutsui

发明人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Kyoji Tsutsui

IPC分类号： C09B35/02 ,  G03G5/06 ,  G03G13/22

CPC分类号： G03G5/0683 ,  C09B35/02

摘要： The present invention provides disazo compounds expressed by the general formula I ##STR1## a process for the preparation of said compounds; and electrophotographic sensitive material having a high sensitivity as well as a high flexibility which comprise a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing a disazo compound, as an effective ingredient, which is expressed by the general formula II A'--N.dbd.N--Z--N.dbd.N--A'.

摘要翻译： 本发明提供由通式I表示的双偶氮化合物，其中所述化合物的制备方法为： 和具有高灵敏度的电子照相感光材料以及包含导电性支持体和形成在其上的感光层的高柔性，所述感光层含有双偶氮化合物作为有效成分，其由通式IIA'- N = NZN = N-A'。

公开(公告)号：US4245021A

公开(公告)日：1981-01-13

申请号：US11063

申请日：1979-02-12

申请人： Takeo Kazami ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masaomi Sasaki ,  Kyoji Tsutsui ,  Masafumi Ohta

发明人： Takeo Kazami ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masaomi Sasaki ,  Kyoji Tsutsui ,  Masafumi Ohta

IPC分类号： G03G5/06 ,  G03G5/09

CPC分类号： G03G5/0605 ,  G03G5/0668 ,  Y10S430/10

摘要： An electrophotographic element according to the present invention exhibits an exceedingly high sensitivity and it comprises (1) an electroconductive support, a charge producing layer consisting essentially of a charge producing substance and a charge transport layer consisting essentially of a charge transport substance having the following general formula and a binder, the last-mentioned two layers being superposed in that order or vice versa on said support, or (2) an electroconductive support and a photosensitive layer, superposed thereon, and consisting essentially of a charge producing substance, a charge transport substance having said general formula and a binder: ##STR1## (wherein n is an integer of 1 or 2, R.sub.1 stands for hydrogen atom or an alkyl, nitro, dialkylamino, alkoxy, nitrile or carboxylic ester group, and R.sub.2 and R.sub.3 stand for hydrogen or halogen atom or nitro or dialkylamino group respectively).

摘要翻译： 根据本发明的电子照相元件显示出非常高的灵敏度，并且其包括（1）导电载体，基本上由电荷产生物质组成的电荷产生层和基本上由电荷输送物质组成的电荷输送层，其具有以下通用 配方和粘合剂，所述最后提到的两层在所述载体上以该顺序重叠，反之亦然;或（2）导电载体和感光层，叠加在其上，并基本上由电荷产生物质组成，电荷传输 具有所述通式的物质和粘合剂：其中n是1或2的整数，R1代表氢原子或烷基，硝基，二烷基氨基，烷氧基，腈或羧酸酯基，R2和R3代表 氢或卤素原子或硝基或二烷基氨基）。

公开(公告)号：US4242260A

公开(公告)日：1980-12-30

申请号：US961963

申请日：1978-11-20

申请人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Akio Kozima

发明人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Akio Kozima

IPC分类号： C09B35/215 ,  C09B56/06 ,  G03G5/06 ,  C07C107/04 ,  C09B35/24 ,  G03C1/76 ,  G03C5/54

CPC分类号： G03G5/0683 ,  C09B35/215 ,  C09B56/06

摘要： The present invention provides disazo compounds expressed by the general formula I ##STR1## wherein A represents ##STR2## in which R represents alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, n is 0 or an integer of 1, 2 or 3, and R may be either identical or different when n is an integer of 2 or 3. The disazo compounds are useful as photoconductive substances or charge-carrier generating substances in various kinds of electrophotographic elements.

摘要翻译： 本发明提供由通式I表示的双偶氮化合物，其中A表示其中R表示烷基，烷氧基，硝基，二烷基氨基或卤素，n为0或整数 为1,2或3，当n为2或3的整数时，R可以相同或不同。双偶氮化合物可用作各种电子照相元件中的光电导物质或电荷载体产生物质。

公开(公告)号：US4400455A

公开(公告)日：1983-08-23

申请号：US325900

申请日：1981-11-30

申请人： Mitsuru Hashimoto ,  Kiyoshi Sakai ,  Katsunari Ohta ,  Akio Kojima

发明人： Mitsuru Hashimoto ,  Kiyoshi Sakai ,  Katsunari Ohta ,  Akio Kojima

IPC分类号： C09B26/02 ,  C09B35/033 ,  G03G5/06

CPC分类号： G03G5/0629 ,  C09B26/02 ,  C09B35/033 ,  G03G5/0679 ,  Y10S430/10

摘要： A layered electrophotographic photoconductor whose charge generation layer comprises a bisazo pigment selected from the group consisting of the bisazo pigments represented by the following general formula (1) and whose charge transport layer contains a charge transport material selected from the group consisting of the hydrazone compounds represented by the following general formula (2): ##STR1## wherein A represents --C.sub.6 H.sub.4 --Cl(o), --C.sub.6 H.sub.4 --Cl(m), --C.sub.6 H.sub.4 --Br(o), --C.sub.6 H.sub.4 --Br(m), --C.sub.6 H.sub.4 --F(o), --C.sub.6 H.sub.4 --F(m), --C.sub.6 H.sub.4 --F(p), or --C.sub.6 H.sub.4 --I(m); ##STR2## wherein R.sup.1 represents a methyl group, an ethyl group, a 2-hydroxyethyl group or a 2-chloroethyl group; R.sup.2 represents a methyl group, an ethyl group, a benzyl group or a phenyl group; and R.sup.3 represents hydrogen, chloride, bromide, an alkyl group with one to four carbon atoms, an alkoxy group with one to four carbon atoms, a dialkylamino group, or a nitro group.

摘要翻译： 一种层状电子照相感光体，其电荷产生层包含选自由以下通式（1）表示的双偶氮颜料的双偶氮颜料，其电荷输送层含有选自由以下的腙化合物组成的组的电荷输送材料： （2）表示：其中A表示-C 6 H 4 -C（o），-C 6 H 4 -Cl（m），-C 6 H 4 -Br（o），-C 6 H 4 -Br（m） -C 6 H 4 -F（O），-C 6 H 4 -F（m），-C 6 H 4 -F（p）或-C 6 H 4 -I（m） （2）其中R1表示甲基，乙基，2-羟乙基或2-氯乙基; R2表示甲基，乙基，苄基或苯基; R 3表示氢，氯，溴，碳原子数为1〜4的烷基，碳原子数为1〜4的烷氧基，二烷基氨基或硝基。

公开(公告)号：US4293492A

公开(公告)日：1981-10-06

申请号：US152061

申请日：1980-05-20

申请人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Kyoji Tsutsui

发明人： Masaomi Sasaki ,  Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Kyoji Tsutsui

IPC分类号： C09B35/34 ,  G03G5/06 ,  C09B35/24

CPC分类号： C09B35/34 ,  G03G5/0683 ,  G03G5/0685

摘要： The present invention provides disazo compounds expressed by the general formula: ##STR1## [wherein A represents a member selected from the group consisting of ##STR2## (wherein X represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as indole ring, carbazole ring, benzofuran ring, etc. and their substituents, Ar.sub.1 represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as dibenzofuran ring, etc. and their substituents, Ar.sub.2 and Ar.sub.3 represent a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc. and their substituents, R.sub.1 and R.sub.3 represent a member selected from the group consisting of hydrogen, lower alkyl radical or phenyl radical and their substituents and R.sub.2 represents a member selected from the group consisting of lower alkyl radical, carboxyl radical and their esters)]; a process for the preparation of said compounds; and electrophotographic sensitive materials having a high sensitivity as well as a high flexibility which comprise a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing said disazo compound as an effective ingredient.

摘要翻译： 本发明提供由以下通式表示的双偶氮化合物：其中A表示选自下列的成员：其中X表示选自以下的成员：芳环如 苯环，萘环等杂环，吲哚环，咔唑环，苯并呋喃环等杂原子及其取代基，Ar 1表示选自苯环，萘环等芳香环的成员 ，诸如二苯并呋喃环等杂环及其取代基，Ar2和Ar3表示选自芳环如苯环，萘环等的基团及其取代基，R 1和R 3表示选自 由氢，低级烷基或苯基组成的组和它们的取代基，R 2表示选自低级烷基，羧基和 酯）]; 一种制备所述化合物的方法; 和具有高灵敏度的电子照相感光材料以及包含导电性支持体和形成在其上的感光层的高柔性，所述感光层含有所述双偶氮化合物作为有效成分。

公开(公告)号：US4365014A

公开(公告)日：1982-12-21

申请号：US79406

申请日：1979-09-27

申请人： Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Masaomi Sasaki

发明人： Kiyoshi Sakai ,  Mitsuru Hashimoto ,  Masafumi Ohta ,  Masaomi Sasaki

IPC分类号： G03G5/06 ,  G03G5/14

CPC分类号： G03G5/0629

摘要： An electrophotographic photoconductor is prepared by forming a photoconductive layer containing a hydrazone compound therein on an electroconductive support member. The hydrazone compounds represented by the following general formula, are useful as photoconductive materials and as charge transport materials for use in electrophotography: ##STR1## wherein R.sub.1 represents a methyl group, an ethyl group, a 2-hydroxyethyl group, or a 2-chloroethyl group, and R.sub.2 represents a methyl group, an ethyl group, a benzyl group or a phenyl group.

摘要翻译： 通过在导电性支持体上形成含有腙化合物的感光层来制备电子照相感光体。 由以下通式表示的腙化合物可用作光电导材料和用作电子照相术的电荷传输材料：其中R1表示甲基，乙基，2-羟基乙基或2-氯乙基 基团，R 2表示甲基，乙基，苄基或苯基。