公开(公告)号：US09457512B2

公开(公告)日：2016-10-04

申请号：US13932375

申请日：2013-07-01

申请人： NAMICS CORPORATION

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato

IPC分类号： B29C65/02 ,  H01M4/36 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0562 ,  H01M4/485 ,  H01M4/505

CPC分类号： B29C65/02 ,  H01M4/366 ,  H01M4/485 ,  H01M4/505 ,  H01M4/624 ,  H01M10/0525 ,  H01M10/0562 ,  Y02E60/122 ,  Y10T29/49112

摘要： Conventional ion rechargeable batteries having an electrode layer on an electrolyte layer suffer from an impurity layer formed at the interface, degrading performance. Conventional batteries with no such impurity layer have a problem of weak interface bonding. In the present invention, in a baking process step after an electrode layer is laminated on an electrolyte layer, materials for an electrode layer and an electrolyte layer are selected such that an intermediate layer formed of a reaction product contributing to charging and discharging reactions is formed at the interface of the electrode layer and the electrolyte layer. In addition, a paste that an active material is mixed with a conductive material at a predetermined mixing ratio is used to form a positive electrode layer and a negative electrode layer. Reductions in electrode resistance and interface resistance and improvement of charging and discharging cycle characteristics are made possible.

摘要翻译： 在电解质层上具有电极层的常规离子可再充电电池在界面处形成杂质层，降解性能。 没有这种杂质层的常规电池具有界面粘合弱的问题。 在本发明中，在将电极层层压在电解质层上之后的烘烤工序中，选择电极层和电解质层的材料，形成由有助于充放电反应的反应产物形成的中间层 在电极层和电解质层的界面处。 此外，使用活性物质以预定的混合比与导电材料混合的糊料形成正极层和负极层。 降低电极电阻和界面电阻以及充放电循环特性的改善成为可能。

公开(公告)号：US09263727B2

公开(公告)日：2016-02-16

申请号：US14447497

申请日：2014-07-30

申请人： Namics Corporation

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

IPC分类号： H01M10/0562 ,  H01M4/04 ,  H01M10/04 ,  H01M10/0525 ,  H01M10/0585 ,  H01M4/485 ,  H01M4/62 ,  H01M4/66

CPC分类号： H01M4/0404 ,  H01M4/0414 ,  H01M4/0471 ,  H01M4/485 ,  H01M4/622 ,  H01M4/661 ,  H01M4/666 ,  H01M10/044 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49108

摘要： This is to provide an all solid state secondary battery which can be produced by an industrially employable method capable of mass-production and has excellent secondary battery characteristics. This is an all solid state secondary battery containing a laminated material in which a positive-electrode unit and a negative-electrode unit are laminated alternately through an ion conductive inorganic-material layer, the positive-electrode unit has positive active material layers on both surfaces of a positive-electrode collector layer, the above-mentioned negative-electrode unit has negative active material layers on both surfaces of a negative-electrode collector layer, (A) at least one of the positive-electrode collector layer and the negative-electrode collector layer comprises a metal of either of Ag, Pd, Au and Pt, or an alloy containing either of Ag, Pd, Au and Pt, or a mixture containing two or more kinds selected from the metals and alloys, (B) each layer is in a sintered state, or (C) at least the starting material for the ion conductive inorganic material of the ion conductive inorganic-material layer is a calcined powder.

摘要翻译： 这是提供一种能够通过工业上可以大规模生产并且具有优异的二次电池特性的方法生产的全固态二次电池。 这是一种包含层叠材料的全固体二次电池，其中正极单元和负极单元交替地通过离子导电无机材料层层压，正极单元在两个表面上具有正的活性材料层 上述负极单元在负极集电体层的两面具有负极活性物质层，（A）正极集电体层和负极中的至少一个 集电体层包括Ag，Pd，Au和Pt中的任一种的金属，或包含Ag，Pd，Au和Pt中的任一种的合金，或包含选自金属和合金的两种或更多种的混合物，（B）每层 或（C）至少离子传导性无机材料层的离子传导性无机材料的原料为煅烧粉末。