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公开(公告)号：US11161103B2
公开(公告)日：2021-11-02
申请号：US16466436
申请日：2017-12-06
发明人： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC分类号： B01J31/22
摘要： An organometallic complex catalyst is disclosed for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the high frequency side compared to the TEP value of the ligand of formula (2-1).
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公开(公告)号：US20240359169A1
公开(公告)日：2024-10-31
申请号：US18686697
申请日：2022-09-16
发明人： Junchul Choi , Norihisa Fukaya , Kazuhiro Matsumoto , Tomoteru Mizusaki , Yukio Takagi , Yasuhiro Seki
IPC分类号： B01J31/18 , B01J31/16 , C07C67/475
CPC分类号： B01J31/1815 , B01J31/1608 , B01J31/1616 , C07C67/475 , B01J2231/543
摘要： The present invention provides an organic metal complex catalyst for an olefin metathesis reaction, which enables the achievement of a higher yield of a desired substance in an olefin metathesis reaction than the conventional catalysts. The organic metal complex catalyst according to the present invention has a structure represented by formula (1) and is used for an olefin metathesis reaction. In formula (1), M represents a coordination center and is an Ru atom or an ion thereof; R1, R2 and R3 may be the same as or different from each other and independently represent a substituent such as a hydrogen atom; R4, R5, R6 and R7 may be the same as or different from one another and independently represent a substituent such as a hydrogen atom; X represents a halogen atom; and R8 represents a substituent having 3 to 20 carbon atoms and having a π bond.
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公开(公告)号：US20220008905A1
公开(公告)日：2022-01-13
申请号：US17487333
申请日：2021-09-28
发明人： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC分类号： B01J31/22
摘要： An organometallic complex catalyst is disclosed for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a n bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the high frequency side compared to the TEP value of the ligand of formula (2-1).
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公开(公告)号：US12017208B2
公开(公告)日：2024-06-25
申请号：US17269093
申请日：2019-08-28
IPC分类号： B01J31/22 , C07C209/10
CPC分类号： B01J31/22 , C07C209/10 , B01J2531/824
摘要： It is an object of the present invention to provide a catalyst for a cross-coupling reaction in which an organometallic complex is sufficiently immobilized on a carrier and an object product can be easily obtained in a high yield and in a relatively short reaction time with a relatively small amount of use. The catalyst for a cross-coupling reaction of the present invention has a carrier part composed of a synthetic resin and an organometallic complex part immobilized on the carrier part by chemical bonding, and has a structure represented by formula (P1), wherein in (P1) R1, R2 may be the same or different, and is a substituent such as a hydrogen atom. R3, R4, R5, R6, R8, R9 may be the same or different and are substituents, such as a hydrogen. X represents a halogen atom, and R7 represents a substituent having 3 to 20 carbon atoms with a π bond. RS1 represents the main chain of the synthetic resin precursors having —CH2OH group at their end.
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公开(公告)号：US20190308182A1
公开(公告)日：2019-10-10
申请号：US16466436
申请日：2017-12-06
发明人： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC分类号： B01J31/22
摘要： An organometallic complex catalyst is disclosed for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the high frequency side compared to the TEP value of the ligand of formula (2-1).
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公开(公告)号：US20220032278A1
公开(公告)日：2022-02-03
申请号：US17490143
申请日：2021-09-30
发明人： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC分类号： B01J31/22
摘要： An organometallic complex catalyst that makes it possible to obtain a higher yield of a desired product than conventional catalysts in a cross-coupling reaction. The organometallic complex catalyst has a structure represented by formula (1) and is for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the low frequency side compared to the TEP value of the ligand of formula (2-1).
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公开(公告)号：US11167278B2
公开(公告)日：2021-11-09
申请号：US16466413
申请日：2017-12-06
发明人： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC分类号： B01J31/22
摘要： An organometallic complex catalyst that makes it possible to obtain a higher yield of a desired product than conventional catalysts in a cross-coupling reaction. The organometallic complex catalyst has a structure represented by formula (1) and is for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the low frequency side compared to the TEP value of the ligand of formula (2-1).
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公开(公告)号：US20210308660A1
公开(公告)日：2021-10-07
申请号：US17269093
申请日：2019-08-28
IPC分类号： B01J31/22 , C07C209/10
摘要： It is an object of the present invention to provide a catalyst for a cross-coupling reaction in which an organometallic complex is sufficiently immobilized on a carrier and an object product can be easily obtained. The catalyst for a cross-coupling reaction of the present invention has a carrier part composed of a synthetic resin and an organometallic complex part immobilized on the carrier part by chemical bonding, and has a structure represented by formula (P1), wherein in (P1) R1, R2 may be the same or different, and is a substituent such as a hydrogen atom. R3, R4, R5, R6, R8, R9 may be the same or different and are substituents, such as a hydrogen. X represents a halogen atom, and R7 represents a substituent having 3 to 20 carbon atoms with a π bond. RS1 represents the main chain of the synthetic resin precursors having —CH2OH group at their end.
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公开(公告)号：US20200299239A1
公开(公告)日：2020-09-24
申请号：US16084063
申请日：2017-02-15
IPC分类号： C07D213/73 , B01J23/89 , B01J21/18 , B01J35/10 , B01J35/02
摘要： An aromatic nitro compound has a structure in which a nitro group and a halogen atom, in a separated state, are directly bonded as substituents to the ring structure of the same ring; a reaction composition is provided which, in a hydrogenation reaction of the nitro group of said aromatic nitro compound, allows selectively hydrogenating the nitro group, and sufficiently reducing the separation of the halogen atom from the ring; also provided is a reaction system that uses this reaction composition. This reaction composition includes a catalyst which, with the aforementioned aromatic nitro compound as reactant, is used in a hydrogenation reaction of at least one of the one or more nitro groups of said reactant. Further, the reaction composition includes a base and an organic solvent. The catalyst includes a carrier, and Fe oxide particles and Pt particles supported by the carrier.
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公开(公告)号：US10177395B2
公开(公告)日：2019-01-08
申请号：US15316929
申请日：2016-03-30
IPC分类号： H01M4/92 , H01M8/1004 , B01J23/44 , B01J35/08 , B01J37/02 , H01M4/86 , H01M4/88 , H01M8/1018
摘要： To provide electrode catalyst (core-shell catalyst) having an excellent catalyst activity which contributes to lower the cost of the PEFC. The electrode catalyst has catalyst particles supported an a support. The catalyst particle has a core part containing simple Pd and a shell part containing simple Pt. A percentage RC (atom %) of the carbon of the support and a percentage RPd (atom %) of the simple Pd in an analytical region near a surface measured by X-ray photoelectron spectroscopy (XPS) satisfy the conditions of the following equation (1): 2.15≤[100×RPd/(RPd+RC)].
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