Abstract:
There is provided a cellulose derivative that has a high amount of a chelate adsorption group introduced, has high hydrophilicity, and is capable of efficiently recovering boron. The cellulose derivative of the present disclosure has a repeating unit represented by the following formula (1-1). In the following formula (I-1), Ra is the same as or different from each other, and is a hydroxyl group or a group represented by the following formula (a). In the following formula (a), R1 represents a hydrogen atom or a methyl group. R2 represents a hydrogen atom or a hydrocarbon group optionally having a hydroxyl group. R3 represents a hydrogen atom or a hydrocarbon group. Note that at least one of all R3 contained in the cellulose derivative is the group represented by the following formula (a).
Abstract:
An object is to provide a method for producing a polysaccharide derivative without using a catalyst, a cocatalyst, or an active compound by esterification, etherification, or the like, from a polysaccharide such as cellulose as a source material, while maintaining a high molecular weight. Another object is to provide a method for producing a cellulose derivative in a separated condition directly from biomass containing lignocellulose. A method for producing a polysaccharide derivative of the present invention is characterized in that a reaction is carried out in a mixture comprising: a source material comprising a polysaccharide; an ionic liquid for which the pKa of a conjugate acid of an anion in DMSO is 12 to 19 and which is capable of producing a carbene; and a chain or cyclic ester compound or an epoxy compound. Preferably as a source material containing a polysaccharide, a biomass source material containing lignocellulose is used.
Abstract:
The present invention provides an optically active poly(diphenylacetylene) compound represented by the following formula (I): [wherein each symbol is as described in the DESCRIPTION], and a production method thereof, an optical isomer separating agent containing the poly(diphenylacetylene) compound, and a packing material for a chiral column, containing the optical isomer separating agent coated on a carrier. According to the present invention, a practical optical isomer separation agent having a high optical resolution ability for a wide variety of racemic compounds and an optical isomer separation method can be provided.
Abstract:
Provided is a water-insoluble crosslinked structure with an excellent metal-adsorbing effect. The crosslinked structure is formed by crosslinking a first linear polymer and a second linear polymer. The first linear polymer has a plurality of pendant groups represented by Formula (a). The second linear polymer has a plurality of pendant groups represented by Formula (a). Some of the plurality of pendant groups in the first linear polymer and some of the plurality of pendant groups in the second linear polymer are bonded to each other via a crosslinker. In the formula, ring Z represents a heterocycle containing a nitrogen atom as a heteroatom, R1 represents a single bond or an alkylene group having from 1 to 10 carbons, and Q+ represents a counter cation.
Abstract:
The present disclosure provides an adsorbent which is produced using a low environmental load material as a raw material and adsorbs selenious acid selectively and efficiently. A selenious acid adsorbent according to the present disclosure includes a cellulose derivative (I) having a repeating unit represented by Formula (I). In Formula (I), each Ra represents a hydrogen atom, a group represented by Formula (a-1), or a group represented by Formula (a-2), and at least one of all the Ras included in the cellulose derivative is a group represented by Formula (a-1) or a group represented by Formula (a-2):
Abstract:
The present disclosure provides a cellulose derivative which has excellent storage stability and can selectively adsorb a valuable metal and a toxic metal. The cellulose derivative of the present disclosure has a repeating unit represented by Formula (I) below. In Formula (I) below. Ras are identical or different and are a hydrogen atom or a group represented by Formula (a) below. In Formula (a) below, ring Z represents a heterocycle containing a nitrogen atom as a heteroatom, and R1 represents a single bond or an alkylene group having from 1 to 10 carbons. Four R2s are identical or different, and each represent an alkyl group having from 1 to 10 carbons. At least one of all the Ras included in the cellulose derivative is a group represented by Formula (a) below.