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公开(公告)号：US20030089604A1
公开(公告)日：2003-05-15
申请号：US10290162
申请日：2002-11-08
IPC分类号： G01N027/407
CPC分类号： G01N27/4074 , G01N33/005
摘要： A gas sensor suitable for measuring hydrogen concentration, including a proton conductive layer (1); a first electrode (3) and a second electrode (5) provided on the proton conductive layer (1); a gas diffusion-limiting inlet (19) provided between the first electrode (3) and a measurement gas atmosphere (6) containing hydrogen gas; and a gas diffusion-limiting outlet (21) provided between the second electrode (5) and the atmosphere (6); wherein the ratio (a/b) between the diffusion resistance (a) of the diffusion limiting portion (19) and the diffusion resistance (b) of the gas outlet portion (21) is not greater than 2.
摘要翻译： 适用于测量氢浓度的气体传感器，包括质子传导层（1）; 设置在质子传导层（1）上的第一电极（3）和第二电极（5）。 设置在第一电极（3）和含有氢气的测量气体气氛（6）之间的气体扩散限制入口（19） 和设置在第二电极（5）和大气（6）之间的气体扩散限制出口（21）。 其中所述扩散限制部分（19）的扩散阻力（a）与所述气体出口部分（21）的扩散阻力（b）之比（a / b）不大于2。
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公开(公告)号：US20030042139A1
公开(公告)日：2003-03-06
申请号：US10231209
申请日：2002-08-30
IPC分类号： G01N027/407
CPC分类号： G01N27/4074
摘要： A hydrogen gas sensor is configured such that a first electrode (3) is provided on one surface of a proton conduction layer (1); a second electrode (5) and a reference electrode (7) are provided on the other surface of the proton conduction layer (1) in opposition to the first electrode (3); and these components are supported in a support element (10) consisting of a first support element (8) and a second support element (9). The first support element (8), which partially constitutes the support element (10), has a diffusion controlling portion (19) for establishing communication between an ambient atmosphere and a first recess (11a). The ratio (area ratio) S1/S2 between the first area S1 (the area of the meshed portion in FIG. 1) and the second area S2 (the area of the hatched portion in FIG. 1) is less than 0.35.
摘要翻译： 氢气传感器被配置为使得第一电极（3）设置在质子传导层（1）的一个表面上; 第二电极（5）和参考电极（7）相对于第一电极（3）设置在质子传导层（1）的另一个表面上。 并且这些部件被支撑在由第一支撑元件（8）和第二支撑元件（9）组成的支撑元件（10）中。 部分地构成支撑元件（10）的第一支撑元件（8）具有扩散控制部分（19），用于建立环境大气和第一凹部（11a）之间的连通。 第一区域S1（图1中的网格部分的面积）与第二区域S2（图1中的阴影部分的面积）之间的比率（面积比）S1 / S2小于0.35。
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公开(公告)号：US20030052005A1
公开(公告)日：2003-03-20
申请号：US10242403
申请日：2002-09-13
IPC分类号： G01N027/41
CPC分类号： G01N27/4074 , G01N33/005
摘要： A hydrogen gas sensor is configured such that an O-ring 21 is disposed within a measurement chamber 11a in order to seal against a first support element 9a and against a proton conduction layer 1. This O-ring 21 assumes the form of a rectangular frame that surrounds a first electrode 3, and a substantially circular cross section, and is elastic, heat resistant, and durable. A first metal plate 23a and a second metal plate 23b are disposed from the outside on opposite support elements 9a and 9b, respectively. The hydrogen gas sensor of the present embodiment has a pair of right-hand and left-hand through-holes 29 formed therein so as to extend along the thickness direction thereof. Bolts 31 are inserted into the corresponding through-holes 29. By fastening the metal plates 23a and 23b from the outside by means of the bolts 31 and nuts 33, the opposite support elements 9a and 9b are fastened, thereby clamping the entire hydrogen sensor in a unitary condition.
摘要翻译： 氢气传感器被配置为使得O形环21设置在测量室11a内以便密封第一支撑元件9a和抵靠质子传导层1.该O形环21呈矩形框架的形式 围绕第一电极3和大致圆形的横截面，并且是弹性的，耐热的和耐用的。 第一金属板23a和第二金属板23b分别从外部设置在相对的支撑元件9a和9b上。 本实施方式的氢气传感器具有沿其厚度方向延伸的一对形成在其中的右侧和左侧通孔29。 螺栓31插入对应的通孔29.通过螺栓31和螺母33从外部紧固金属板23a和23b，将相对的支撑元件9a和9b紧固，从而将整个氢传感器夹紧 一个单一的条件。
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公开(公告)号：US20020187075A1
公开(公告)日：2002-12-12
申请号：US10119901
申请日：2002-04-11
发明人： Norihiko Nadanami , Tomonori Kondo , Masaya Watanabe , Ryuji Inoue , Noboru Ishida , Takafumi Oshima
IPC分类号： G01N027/00
CPC分类号： G01N33/005 , G01N27/4074 , Y10T436/11 , Y10T436/203332 , Y10T436/22 , Y10T436/25875
摘要： A hydrogen sensor includes a first electrode 3 and a second electrode 4 provided in contact with a proton conduction layer 2; a gas diffusion controlling portion 6 provided between a measurement gas atmosphere and the first electrode 3; and a support element (1a, 1b) for supporting the proton conduction layer 6, the first electrode 3, the second electrode 4, and the gas diffusion controlling portion 6. Hydrogen contained in a measurement gas introduced via the gas diffusion controlling portion 6 is dissociated, decomposed, or reacted by applying a voltage between the first electrode 3 and the second electrode 4 to thereby generate protons. Hydrogen concentration is obtained on the basis of a limiting current generated as a result of the generated protons being pumped out via the proton conduction layer 2 from the first electrode 3 side of the proton conduction layer to the second electrode 4 side of the proton conduction layer. Hydrogen concentration on the first electrode 2 is controlled to a partial pressure of not less than 10null12 atm, or more preferably, of not less than 3null10null12 atm and of less than 10null2 atm.
摘要翻译： 氢传感器包括与质子传导层2接触而设置的第一电极3和第二电极4; 设置在测量气体气氛和第一电极3之间的气体扩散控制部分6; 以及用于支撑质子传导层6，第一电极3，第二电极4和气体扩散控制部分6的支撑元件（1a，1b）。经由气体扩散控制部分6引入的测量气体中包含的氢是 通过在第一电极3和第二电极4之间施加电压而解离，分解或反应，从而产生质子。 基于由生成的质子经由质子传导层2从质子传导层的第一电极3侧向质子传导层的第二电极4侧泵出的限制电流获得氢浓度 。 将第一电极2上的氢浓度控制在不小于10-12atm，或更优选不小于3×10-12 atm且小于10-2atm的分压。
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公开(公告)号：US20030066763A1
公开(公告)日：2003-04-10
申请号：US10144835
申请日：2002-05-15
发明人： Masaya Watanabe , Norihiko Nadanami , Tomonori Kondo , Ryuji Inoue , Takafumi Oshima , Noboru Ishida
IPC分类号： G01N027/26 , G01N027/407
CPC分类号： G01N33/005 , G01N27/4074 , G01N33/006
摘要： This invention provides a gas sensor including a proton-conductive polymer electrolyte layer and a method for measuring gas concentration, that are capable of measuring gas concentration at high accuracy nothwithstanding the presence of water vapor.
摘要翻译： 本发明提供了一种气体传感器，其包括质子传导性聚合物电解质层和测量气体浓度的方法，其能够即使存在水蒸气也能以高精度测量气体浓度。
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公开(公告)号：US20030042138A1
公开(公告)日：2003-03-06
申请号：US10231058
申请日：2002-08-30
IPC分类号： G01N027/407
CPC分类号： G01N27/4074 , G01N33/005
摘要： A hydrogen gas sensor including a first electrode 3 provided on one surface of a proton conduction layer 1; a second electrode 5 provided on the other surface of the proton conduction layer 1 in opposition to the first electrode 3; and these components are supported in a support element including a first support element 9a and a second support element 9b. A conductive, elastic element 23 is disposed between a first lead portion 10a and a first electrode 3 in contact with the first lead portion 10a and the first electrode 3. The conductive, elastic element 23 is an electrically conductive, elastic sheetlike element made of metal, and has a pair of right-hand and left-hand through-holes 25 formed therein at a central portion thereof. The conductive, elastic element 23 is held between the first lead portion 10a and the first electrode 3 while being pressed inward by a first support element 9a. Thus, the first electrode 3 comes in close contact with the proton conduction layer 1, whereby electrical connection is established therebetween.
摘要翻译： 一种氢气传感器，包括设置在质子传导层1的一个表面上的第一电极3; 设置在与第一电极3相对的质子传导层1的另一个表面上的第二电极5; 并且这些部件被支撑在包括第一支撑元件9a和第二支撑元件9b的支撑元件中。 导电弹性元件23设置在与第一引线部分10a和第一电极3接触的第一引线部分10a和第一电极3之间。导电弹性元件23是由金属制成的导电弹性片状元件 并且在其中心部分形成有一对右侧和左侧通孔25。 导电弹性元件23由第一支撑元件9a向内压的同时保持在第一引线部分10a和第一电极3之间。 因此，第一电极3与质子传导层1紧密接触，从而在它们之间建立电连接。
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