ALIPHATIC EPOXY-TERMINATED POLYSULFIDE POLYMER

    公开(公告)号:US20210363305A1

    公开(公告)日:2021-11-25

    申请号:US17303020

    申请日:2021-05-18

    IPC分类号: C08G75/14 C08L63/00

    摘要: An aliphatic epoxy-terminated polysulfide polymer has the formula R″—CHOH—CH2-S—R—(Sy-R)t-S—CH2-CHOH—R″ and is formed by a process, where each R is independently chosen from branched alkanediyl or branched arenediyl groups and groups with the structure —(CH2)a-O—(CH2)b-O—(CH2)c- and about 0 to about 20% of the number of R-groups are branched alkanediyl or branched arenediyl groups and about 80 to about 100% of the number of R-groups have the structure —(CH2)a-O—(CH2)b-O—(CH2)c-, where t is from about 1 to about 60, y is an average value of from about 1.0 to about 2.5, b is an integer value of from about 1 to about 8, and a and c are independently integers from about 1 to about 10, and where each R″ is independently a particular radical where, m, n, o, p, q and r independently have a value of from about 1 to about 10.

    PROCESS FOR THE PREPARATION OF A POLYTHIOETHERSULFIDE

    公开(公告)号:US20210363303A1

    公开(公告)日:2021-11-25

    申请号:US16886868

    申请日:2018-12-04

    IPC分类号: C08G75/04 C08K5/17 C08K5/1515

    摘要: Process for the production of a liquid mercapto-terminated polythioethersulfide comprising the step of reacting, at a temperature in the range 0-100° C. and in the presence of a catalyst: at least one compound selected from the group consisting of (i) dimercapto-dioxa-alkanes (DMDAs) and (ii) glycol di(mercapto carboxylic acid ester)s (GDMEs), at least one dimercapto-dialkyl sulfide (DMDS) at least one di-epoxide, and optionally at least one branching agent selected from compounds having at least three terminal groups selected from epoxy and mercapto groups, wherein the molar ratio (DMDA+GDME)/DMDS is in the range 1.1-4.0.