-
1.发明授权Dehydrogenation catalyst for formic acid, method for producing hydrogen, and method for producing heavy-hydrogen gas or heavy-hydrogenated hydrogen 有权用于甲酸的脱氢催化剂，氢气的制备方法以及重氢氢气或重氢氢气的制备方法公开(公告)号：US09315381B2
公开(公告)日：2016-04-19
申请号：US14374012
申请日：2013-01-25
Inventor： Yuichiro Himeda , Wan-Hui Wang
CPC classification number: C01B3/326 , B01J31/1815 , B01J31/2295 , B01J2231/763 , B01J2531/005 , B01J2531/0205 , B01J2531/0216 , B01J2531/821 , B01J2531/822 , B01J2531/827 , C01B3/22 , C01B4/00 , C01B2203/02 , C01B2203/0277 , C01B2203/1041 , C01B2203/1211 , C07F15/0033 , H01M8/065 , Y02P20/52
Abstract: To provide a catalyst for dehydrogenation of formic acid which allows hydrogen, heavy hydrogen gas or heavy-hydrogenated hydrogen containing no carbon monoxide to be produced through dehydrogenation of formic acid in a highly efficient manner.A catalyst for dehydrogenation of formic acid, including: a multinuclear metal complex represented by the following Formula (1), a tautomer or stereoisomer thereof, or a salt thereof, where M1 and M2 denote transition metals and may be the same as or different from each other; Q1 to Q6 each independently denote carbon or nitrogen; R1 to R6 each independently denote, for example, a hydrogen atom, an alkyl group, a phenyl group, a nitro group, a halogen group, a sulfonate group (sulfo group); L1 and L2 each independently denote an aromatic anionic ligand or an aromatic ligand, and may be substituted by one or more substituents; Y1 and Y2 each independently denote any ligand or are absent; and m denotes a positive integer, 0, or a negative integer.
Abstract translation: 提供甲酸脱氢催化剂，其允许通过以高效的方式使甲酸脱氢生产氢，重氢气或不含一氧化碳的重氢氢。 一种用于甲酸脱氢的催化剂，包括：由下式（1）表示的多核金属络合物，其互变异构体或立体异构体或其盐，其中M1和M2表示过渡金属，并且可以相同或不同 彼此; Q1至Q6各自独立地表示碳或氮; R 1〜R 6各自独立地表示例如氢原子，烷基，苯基，硝基，卤素基，磺酸酯基（磺基）等。 L1和L2各自独立地表示芳族阴离子配体或芳族配体，并且可以被一个或多个取代基取代; Y1和Y2各自独立地表示任何配体或不存在; m表示正整数，0表示负整数。
-
2.发明申请公开(公告)号：US20150166337A1
公开(公告)日：2015-06-18
申请号：US14374012
申请日：2013-01-25
Inventor： Yuichiro Himeda , Wan-Hui Wang
CPC classification number: C01B3/326 , B01J31/1815 , B01J31/2295 , B01J2231/763 , B01J2531/005 , B01J2531/0205 , B01J2531/0216 , B01J2531/821 , B01J2531/822 , B01J2531/827 , C01B3/22 , C01B4/00 , C01B2203/02 , C01B2203/0277 , C01B2203/1041 , C01B2203/1211 , C07F15/0033 , H01M8/065 , Y02P20/52
Abstract: To provide a catalyst for dehydrogenation of formic acid which allows hydrogen, heavy hydrogen gas or heavy-hydrogenated hydrogen containing no carbon monoxide to be produced through dehydrogenation of formic acid in a highly efficient manner.A catalyst for dehydrogenation of formic acid, including: a multinuclear metal complex represented by the following Formula (1), a tautomer or stereoisomer thereof, or a salt thereof, where M1 and M2 denote transition metals and may be the same as or different from each other; Q1 to Q6 each independently denote carbon or nitrogen; R1 to R6 each independently denote, for example, a hydrogen atom, an alkyl group, a phenyl group, a nitro group, a halogen group, a sulfonate group (sulfo group); L1 and L2 each independently denote an aromatic anionic ligand or an aromatic ligand, and may be substituted by one or more substituents; Y1 and Y2 each independently denote any ligand or are absent; and m denotes a positive integer, 0, or a negative integer.
Abstract translation: 提供甲酸脱氢催化剂，其允许通过以高效的方式使甲酸脱氢生产氢，重氢气或不含一氧化碳的重氢氢。 一种用于甲酸脱氢的催化剂，包括：由下式（1）表示的多核金属络合物，其互变异构体或立体异构体或其盐，其中M1和M2表示过渡金属，并且可以相同或不同 彼此; Q1至Q6各自独立地表示碳或氮; R 1〜R 6各自独立地表示例如氢原子，烷基，苯基，硝基，卤素基，磺酸酯基（磺基）等。 L1和L2各自独立地表示芳族阴离子配体或芳族配体，并且可以被一个或多个取代基取代; Y1和Y2各自独立地表示任何配体或不存在; m表示正整数，0表示负整数。
-
公开(公告)号：US10315190B2
公开(公告)日：2019-06-11
申请号：US15027943
申请日：2014-10-08
Inventor： Yuichiro Himeda , Wan-Hui Wang , Yuichi Manaka , Yuki Amamoto
Abstract: A catalyst including, as effective ingredient, complex represented by Formula (1) which contains bidentate ligand including aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms, or represented by Formula (2) which contains bidentate ligand including: aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms; and 6-membered ring having 1 or more nitrogen atoms, isomer or salt of the complex: where M1 and M2 denote transition metal such as iridium; X1 to X16 each independently denote nitrogen or carbon; R1 to R13 denote, for example, hydrogen atom, alkyl group, or hydroxy group, provided that when Xi (where i denotes 13 to 16) is nitrogen, Ri is absent at position corresponding to the nitrogen; L1 and L2 denote, for example, an aromatic anionic ligand; Z1 and Z2 denote any ligand or are absent; and m and n denote positive integer, 0, or negative integer.
-
-
Search Results
3
records
(took 0.016 seconds)
