Organolithium-Lewis base polymerization of 1,3-butadiene and novel
polybutadienes thus produced
    2.
    发明授权
    Organolithium-Lewis base polymerization of 1,3-butadiene and novel polybutadienes thus produced 失效
    由此制备1,3-丁二烯的有机锂 - 路易斯碱聚合和新型聚丁二烯

    公开(公告)号:US4022959A

    公开(公告)日:1977-05-10

    申请号:US583839

    申请日:1975-06-04

    IPC分类号: C08F136/06 C08F4/48

    CPC分类号: C08F136/06

    摘要: Homopolymers of butadiene having a vinyl content which varies substantially and decreasingly along the longitudinal axis of the macromolecule toward an end thereof are produced by conducting an organolithium-Lewis base catalyzed polymerization at a substantially constantly increasing polymerization temperature throughout the polymerization.

    摘要翻译: 通过在整个聚合过程中以基本上不断增加的聚合温度进行有机锂 - 路易斯碱催化聚合,制备具有乙烯基含量的均聚物,该乙烯基含量沿着大分子的纵向轴线朝向其末端变化。