摘要:
A polymerizable boric compound for electrochemical devices represented by the formula (1), wherein, B represents a boron atom, Z represents a polymerizable functional group, X represents a divalent C1-12 hydrocarbon group or in the absence of X, Z and B form a direct bond, AO represents a C2-4 oxyalkylene group, m and n are each the number of moles of the oxyalklylene group added and each independently stands for 2 or greater but less than 6, and R1 and R2 each represents a C1-12 hydrocarbon group.
摘要:
Provided is a lithium ion rechargeable battery less suffering from swelling even when stored at high temperatures. Disclosed are a cathode active material, a cathode for a lithium ion rechargeable battery using the cathode active material, and a lithium ion rechargeable battery using the cathode. The cathode active material includes particles, each of the particles including a cathode material capable of intercalating and deintercalating lithium ions, and a film formed on at least part of surfaces of the particles. The film includes a compound represented by Chemical Formula (1). Examples of the compound represented by Chemical Formula (1) include lithium squarate and dilithium squarate. Preferably, the lithium ion rechargeable battery is a prismatic battery.
摘要:
The gas generation and the decrease in battery capacity during high temperature storage of a lithium secondary battery are suppressed. The electrolyte contains a polymerizable compound or a polymer, the polymerizable compound contains a compound having an aromatic functional group and a polymerizable functional group and a compound having a complex-forming functional group forming a complex with a metal ion and a polymerizable functional group, and the polymer has the complex-forming functional group, the aromatic functional group and a residue of the polymerizable functional group.
摘要:
An electrolyte includes a mixture of polymerizable compounds, or a polymer, in which the mixture includes a polymerizable compound having an aromatic functional group and a polymerizable functional group, and a polymerizable compound having a phosphorus-containing functional group that contains phosphorus, and having a polymerizable functional group, and in which the polymer has residues of each of the phosphorus-containing functional group, the aromatic functional group and the polymerizable functional group.
摘要:
In a lithium secondary battery which contains an electrode group including a positive electrode, a negative electrode and a separator interposed between the positive electrode and the negative electrode, and an electrolytic solution, a current shut-off portion which is activated by an increase in an internal pressure is provided, a polymerizable compound having an aromatic functional group and a polymerizable functional group, or a polymer having an aromatic functional group and a residue of a polymerizable functional group is contained, and a carbon dioxide generating agent which produces carbon dioxide by a neutralization reaction is contained in at least one of the positive electrode and the separator. Thereby, the current shut-off valve is activated in an early stage of overcharge to increase the safety of the battery when overcharged.