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公开(公告)号:US20190300804A1
公开(公告)日:2019-10-03
申请号:US16364799
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Mazi Sardashti , Steven E. Lusk , Robert M. Walston
Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an alkylation catalyst to provide enhanced yields of mono-alkylated aromatics that are suitable for use as a blend component of liquid transportation fuels or other value-added chemical products.
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公开(公告)号:US20190300805A1
公开(公告)日:2019-10-03
申请号:US16364836
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Mazi Sardashti , Steven E. Lusk , Robert M. Walston
Abstract: The present disclosure relates generally to systems operable to produce liquid transportation fuels by converting a hydrocarbon feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. The system separates the hydrocarbon feed stream to form a first fraction comprising isopentane and smaller hydrocarbons, and a second fraction comprising n-pentane and larger components of the hydrocarbon feeds stream. Each fraction is then catalytically-activated in a separate activation reactor containing a separate activation catalyst, where the conditions maintained in each reactor are selected to maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first activation reactor is maintained at a lower temperature than the second activation reactor. Certain embodiments of the system mix at least a portion of the effluents from the first and second activation reactor and convert the resulting mixed effluent in either an oligomerization reactor containing an oligomerization catalyst or an oligomerization reactor containing an alkylation catalyst to provide enhanced yields of upgraded hydrocarbon products that are characterized as a liquid transportation fuel or a blend component thereof.
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公开(公告)号:US20190300455A1
公开(公告)日:2019-10-03
申请号:US16364764
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Mazi Sardashti , Steven E. Lusk , Robert M. Walston
Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an oligomerization catalyst to provide enhanced yields of aliphatic hydrocarbons that possess the characteristics of a blend component of a liquid transportation fuel or other value-added chemical products.
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公开(公告)号:US20190300454A1
公开(公告)日:2019-10-03
申请号:US16364737
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Mazi Sardashti , Steven E. Lusk , Robert M. Walton
Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. The process provides increased yields of upgraded hydrocarbon products that possess the characteristics of a liquid transportation fuel or a blend component thereof.
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