公开(公告)号：US20030060358A1

公开(公告)日：2003-03-27

申请号：US10281100

申请日：2002-10-28

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Erik Licht ,  Helmut G. Alt ,  M. Bruce Welch ,  Bryan E. Hauger

IPC: B01J031/00 ,  C07F017/00

CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/03

Abstract: A process for producing a new metallocene comprising reacting a first bridged metallocene which has an olefinically unsaturated with about two molar equivalents of an alkali metal alkyl, catalyst systems resulting from the combination of the resulting metallocenes and a cocatalyst, and polymerization processes using such catalyst systems are disclosed.

公开(公告)号：US20020065190A1

公开(公告)日：2002-05-30

申请号：US10040164

申请日：2001-10-22

Applicant: Phillips Petroleum Company

Inventor： Erik Licht ,  Helmut G. Alt ,  M. Bruce Welch

IPC: B01J031/00

CPC classification number: B01J31/14 ,  B01J31/122 ,  B01J31/2295 ,  B01J2531/48 ,  C07F17/00 ,  C08F4/65912 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/65927

Abstract: A process for producing a new metallocene comprising reacting a first metallocene which has a cyclodiene group having an olefinically unsaturated substituent with about two molar equivalents of an alkali metal alkyl, catalyst systems resulting from the combination of the resulting metallocene and an organoaluminum cocatalysts, and polymerization processes using such catalyst systems are disclosed.

Abstract translation: 一种新的茂金属的制备方法，包括使具有烯属不饱和取代基的环二烯基团的第一茂金属与约2摩尔当量碱金属烷基反应，由所得茂金属与有机铝助催化剂的组合得到的催化剂体系和聚合 公开了使用这种催化剂体系的方法。

公开(公告)号：US20030144438A1

公开(公告)日：2003-07-31

申请号：US10247325

申请日：2002-09-20

Applicant: Phillips Petroleum Company

Inventor： Roland Schmidt ,  Ulrich Hammon ,  M. Bruce Welch ,  Helmut G. Alt ,  Bryan E. Hauger ,  Ronald D. Knudsen

IPC: C08F004/16

CPC classification number: C08F10/00 ,  C07C2/32 ,  C07C2531/22 ,  C07F17/00 ,  C08F10/02 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/68 ,  C08F4/62 ,  C08F2500/04 ,  C08F210/14 ,  C08F4/68224 ,  C08F4/7042 ,  C08F4/64089 ,  C08F4/62089

Abstract: Pyridyldiimine ligands having one of the following structures: 1 and pyridyldiimine metal complexes having one of the following structures: 2 for example the Group 4b, 5b, 6b, 7b, and 8 transition metal (M) complexes such as vanadium complexes, are disclosed. The invention also relates to the use of these metal complexes as olefin polymerization or oligomerization catalysts, optionally in combination with metal alumoxane and similar catalyst activators. Certain of these catalysts have been found to possess robust activity as selective oligomerization catalysts, while others of these catalysts act selectively as polymerization catalysts. A method of synthesizing the above-noted ligands using p-toluenesulfonic acid as a catalyst is also disclosed.

Abstract translation: 具有以下结构之一的吡啶二亚胺配位体：具有以下结构之一的吡啶二亚胺金属络合物：例如第4b，5b，6b，7b和8族过渡金属（M）络合物如钒络合物。 本发明还涉及这些金属络合物作为烯烃聚合或低聚催化剂，任选地与金属铝氧烷和类似的催化剂活化剂组合的用途。 已经发现某些这些催化剂具有作为选择性低聚催化剂的强大活性，而这些催化剂中的其它催化剂选择性地作为聚合催化剂起作用。 还公开了使用对甲苯磺酸作为催化剂合成上述配体的方法。

公开(公告)号：US20020039960A1

公开(公告)日：2002-04-04

申请号：US09975223

申请日：2001-10-11

Applicant: Phillips Petroleum Company

Inventor： Helmut G. Alt ,  M. Bruce Welch

IPC: B01J031/00

CPC classification number: C08F10/00 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65925 ,  C08F110/02 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/20

Abstract: Metallocycle metallocenes are produced by reacting a first metallocene having an aralkyl group or an aryl dialkyl silyl group attached to a cyclodienyl group with about two molar equivalents of an alkali metal alkyl having at least 4 carbon atoms. The use of the metallocycle metallocenes as components of catalyst for the polymerization of olefins is also disclosed.

Abstract translation: 金属环金属茂是通过使具有芳环烷基的第一茂金属或与环二烯基连接的芳基二烷基甲硅烷基与约2摩尔当量的具有至少4个碳原子的碱金属烷基反应来制备的。 还公开了使用金属茂金属茂作为烯烃聚合的催化剂的组分。

公开(公告)号：US20010056033A1

公开(公告)日：2001-12-27

申请号：US09923648

申请日：2001-08-07

Applicant: Phillips Petroleum Company

Inventor： Alexander Koppl ,  Helmut G. Alt ,  M. Bruce Welch

IPC: B01J031/00

CPC classification number: B01J31/143 ,  B01J21/08 ,  B01J31/14 ,  B01J31/1616 ,  B01J31/2295 ,  B01J2531/48 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/65927

Abstract: Metallocenes having a 9-fluorenyl group and another cyclic dienyl group connected by a single carbon having a terminally unsaturated hydrocarbyl substituent wherein the 9-fluorenyl group has a hydrocarbyl substituent in the 4 position, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.