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1.发明授权Alpha-sulfo-fatty acid ester and/or amide salt(s) detergent laundry bars and processes for manufacture thereof 失效α-磺基脂肪酸酯和/或酰胺盐洗涤剂洗涤条及其制造方法
公开(公告)号：US4707289A
公开(公告)日：1987-11-17
申请号：US836910
申请日：1986-03-06
CPC分类号： C11D17/0069 , C11D1/28 , C11D3/126
摘要： Detergent laundry bars of acceptable mildness, detergency, foaming properties, processing characteristics and resistance to breakage are described which are based on built water soluble salts of alpha-sulfo-higher fatty acid-lower alcohol ester detergent and/or alpha-sulfo-higher fatty acid-amide, and which contain bentonite, which acts as a bodying agent for the laundry bars, facilitating production thereof, and contributing fabric softening properties to laundry washed with such laundry bars. When the bentonite is omitted or is replaced by water insoluble filler, such as calcium carbonate powder, and the alpha-sulfo-fatty acid derivative detergent is employed as an aqueous solution, bars made are not of acceptable hardness and such compositions are not satisfactorily processable in conventional soapmaking apparatuses.Also described are processes for converting aqueous solutions of alpha-sulfo-fatty acid derivative detergent to solid form by treatment with bentonite, and for making detergent laundry bars from such solidified detergent.
摘要翻译： 描述了基于建立的α-磺基 - 高级脂肪酸 - 低级醇酯洗涤剂和/或α-磺基 - 高级脂肪酸的水溶性盐的可接受的温和性，洗涤性，起泡性，加工特性和耐断裂性的洗涤剂洗涤条 酸 - 酰胺，并且其含有膨润土，其膨胀物作为洗衣条的固化剂，促进其生产，并且对用这种洗衣条洗涤的衣物提供织物柔软性。 使用碳酸钙粉末和α-磺基脂肪酸衍生物洗涤剂作为水溶液时，不使用膨润土或被水不溶性填料代替时，制成的棒不具有可接受的硬度，而且这些组成不能令人满意地加工 在传统的肥皂制造装置中。 还描述了通过用膨润土处理将α-磺基脂肪酸衍生物洗涤剂的水溶液转化成固体形式，并且从这种固化的洗涤剂制备洗涤剂洗涤条的方法。
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2.发明授权
公开(公告)号：US4806273A
公开(公告)日：1989-02-21
申请号：US74587
申请日：1987-07-17
CPC分类号： C11D3/2065 , C11D1/652 , C11D17/0069 , C11D1/14 , C11D1/523
摘要： Detergent laundry bars of improved physical characteristics, including improved resistance to breakage on handling, are described which include 10 to 35% of sodium higher fatty alcohol sulfate detergent, 10 to 60% of builder for the detergent mixture, a bodying proportion, in the range of 10 to 60% of water insoluble powder, 1 to 10% of higher fatty lower alkanolamide, 0.2 to 5% of glycerol, with the ratio of alkanolamide to glycerol being in the range of 1:5 to 25:1, and 5 to 20% of water (including that which is removable from any hydrate components when the bar is subjected to heating at 105.degree. C. for two hours). Preferably the invented bars will comprise 10 to 25% of sodium coco alcohol sulfate or equivalent sodium higher fatty alcohol sulfate, up to 5 or 10% of secondary detergents, 15 to 30% of sodium tripolyphosphate, 5 to 25% of sodium carbonate, 0 to 10% of sodium silicate, 10 to 50% of calcium carbonate powder, 3 to 7% of cocomonoethanolamide; 0.3 to 1% of glycerol, with the ratio of cocomonoethanolamide:glycerol being in the range of 2:1 to 25:1, and 5 to 12% of water. The described bars, which preferably are milled and plodded, exhibit better resistance to breakage on handling than do bars of similar formulas which do not contain the ethanolamide and glycerol, which is very surprising. They are also of acceptable hardness and do not slough or erode excessively on standing in contact with water, and in use. The bars process satisfactorily and foam well, too.
摘要翻译： 描述了具有改善的物理特性的洗涤剂洗涤条，包括改进的耐操作性破坏性，其包括10至35％的高级高级脂肪醇硫酸盐洗涤剂，10至60％的洗涤剂混合物助洗剂，占据比例 10〜60％的水不溶性粉末，1〜10％的高级脂肪低级烷醇酰胺，0.2〜5％的甘油，烷醇酰胺与甘油的比例在1:5〜25:1的范围内，5〜 20％的水（包括当条在105℃加热2小时时可从任何水合物成分中除去的水）。 优选地，本发明的棒将包含10-25％的椰子醇硫酸钠或当量的高级高级脂肪酸硫酸钠，至多5或10％的二次洗涤剂，15至30％的三聚磷酸钠，5至25％的碳酸钠，0 至10％的硅酸钠，10至50％的碳酸钙粉末，3至7％的共聚乙醇酰胺; 0.3至1％的甘油，其中共聚乙醇酰胺：甘油的比例在2:1至25:1的范围内，和5至12％的水。 所描述的棒，其优选地被研磨和分散，与不含乙醇酰胺和甘油的类似配方的条形物相比，在处理方面表现出更好的抗破裂性，这是非常令人惊讶的。 它们也具有可接受的硬度，并且在与水接触和使用时不会过度脱落或腐蚀。 酒吧过程也令人满意，泡沫也很好。
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3.发明授权Alkyl ethoxylate sulfate detergent laundry bars and processes for manufacture thereof 失效烷基乙氧基硫酸盐洗涤剂洗衣条及其制造方法
公开(公告)号：US4721581A
公开(公告)日：1988-01-26
申请号：US836908
申请日：1986-03-06
CPC分类号： C11D3/126 , C11D1/29 , C11D17/0069
摘要： Detergent laundry bars of acceptable mildness, foaming properties and processing characteristics are described which are based on built higher fatty alcohol ethoxylate sulfate detergent and which contain bentonite, which acts as a bodying agent for the laundry bars, facilitating production thereof, and contributes fabric softening properties to laundry washed with such laundry bar. When the bentonite is omitted or is replaced by water insoluble filler, such as calcium carbonate powder, bars made are not of acceptable hardness and such compositions are not satisfactorily processable in conventional soapmaking apparatuses.Also described are processes for converting aqueous solutions of higher fatty alcohol ethoxylate sulfate detergent to solid form by treatment with bentonite, and for making detergent laundry bars from such solidified detergent.
摘要翻译： 描述了基于建立的高级脂肪醇乙氧基硫酸盐洗涤剂的基本上具有可接受的温和性，发泡性能和加工特性的洗涤剂洗涤条，其含有作为洗衣条的保养剂的膨润土，促进其生产，并且有助于织物柔软性 用这种洗衣条洗衣服。 当膨润土被省略或被水不溶性填料如碳酸钙粉末代替时，制成的棒不具有可接受的硬度，并且这些组合物在传统的肥皂设备中不能令人满意地加工。 还描述了通过用膨润土处理将高级脂肪醇乙氧基化硫酸盐洗涤剂的水溶液转化为固体形式，以及从这种固化的洗涤剂制备洗涤剂洗涤条的方法。
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4.发明授权Alpha-sulfo-higher fatty acid-lower alcohol ester- and amide-based detergent laundry bars and process for manufacture thereof 失效α-磺基 - 高级脂肪酸 - 低级醇酯 - 和酰胺类洗涤剂洗衣条及其制造方法
公开(公告)号：US4705644A
公开(公告)日：1987-11-10
申请号：US836909
申请日：1986-03-06
CPC分类号： C11D3/0094 , C11D1/28 , C11D17/0069
摘要： Detergent laundry bars which are mild to the hands of a user, of good foaming properties during hand washing of laundry and of good processing characteristics, include 10 to 30% of water soluble salt of alpha-sulfo-higher fatty acid-lower alcohol ester, 10 to 50% of builder for such detergent, a bodying proportion, in the range of 20 to 70%, of water insoluble powder and/or sodium sulfate filler, and 5 to 20% of water. Preferably, this improved detergent laundry bar includes 18 to 22% of sodium alpha-sulfo-higher fatty acid methyl ester, 8 to 20% of sodium tripolyphosphate, 5 to 15% of sodium carbonate, 2 to 5% of sodium silicate, 20 to 35% of calcium carbonate, 5 to 15% of talc and 10 to 15% of water. Also within the invention is a process for manufacturing such detergent laundry bars wherein the components of the laundry bar composition which are in powder form are all pre-mixed, followed by admixing, with the pre-mix, of liquid components of the detergent composition, including sodium silicate, in aqueous solution, water and perfume, in that order, and the mixture is amalgamated, milled, plodded under vaccum, cut to desired lengths and pressed to desired form.
摘要翻译： 洗涤衣物洗涤条件良好，加工性好的清洗剂具有良好的泡沫特性，含有10-30％的α-磺基 - 高级脂肪酸 - 低级醇酯的水溶性盐， 10至50％的这种洗涤剂的助洗剂，占20％至70％水溶性粉末和/或硫酸钠填料的组成比例和5至20％的水。 优选地，该改进的洗涤剂洗衣条包括18-22％的α-磺基 - 高级脂肪酸钠甲酯，8-20％的三聚磷酸钠，5-15％的碳酸钠，2-5％的硅酸钠，20〜 35％的碳酸钙，5至15％的滑石和10至15％的水。 本发明还涉及一种制造这种洗涤剂洗衣条的方法，其中粉末形式的洗衣条组合物的组分都预先混合，然后与预混合物混合洗涤剂组合物的液体组分， 包括硅酸钠在水溶液中，水和香料，并将混合物合并，研磨，在真空下摇匀，切成所需长度并压制成所需的形式。
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公开(公告)号：US4787110A
公开(公告)日：1988-11-29
申请号：US72469
申请日：1987-07-13
CPC分类号： C11D17/0069 , D06F39/004
摘要： Detergent laundry bars of improved foaming properties during hand washing of laundry are described which include 15 to 45% of a mixture of 0.05 to 20 parts of sodium higher fatty alcohol sulfate and 1 part of sodium alpha-sulfo-higher fatty acid lower alkyl ester, 10 to 60% of a builder for the detergent mixture, a bodying proportion, in the range of 20 to 70%, of water insoluble powder and/or sodium sulfate filler, and 5 to 22% of water (including that which is removable from any hydrate components when the bar is subjected to heating at 105.degree. C. for two hours). Preferably the invented bars will comprise 5 to 20% of sodium coco alcohol sulfate, 10 to 20% of sodium alpha-sulfo-higher fatty acid methyl ester, 8 to 20% of sodium tripolyphosphate, 5 to 15% of sodium carbonate, 1 to 6% of sodium silicate, 20 to 35% of calcium carbonate powder, 0 to 15% of talc and 7 to 11% of water. The described bars, which are preferably milled and plodded, exhibit better foaming properties in use, with initial foaming, persistence of foaming and regeneration of foam when the wash water is re-used (especially regeneration foaming) being greater than those of comparable bars in which sodium higher fatty alcohol sulfate is employed alone. The invented laundry bars are also milder to the hands and human skin than comparable bars based on sodium higher fatty alcohol sulfate as the sole anionic detergent thereof. The invented bar formula is also more easily processable during production than bars of similar formulas, but which contain either higher alcohol sulfate or alpha-sulpho-higher fatty acid methyl ester, so that the manufacturing throughput rates may be increased, power consumption may be lowered, and a more homogeneous product may be produced.Also described are a process for manufacturing the present detergent laundry bars, a method of testing them for foaming characteristics, and a foam test apparatus.
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公开(公告)号：US5254284A
公开(公告)日：1993-10-19
申请号：US867379
申请日：1992-04-13
CPC分类号： C11D3/3738 , C03C17/30 , C09K3/18 , C11D3/222 , C11D3/43
摘要： Disclosed is a cleaning composition for hard surfaces which comprises an aqueous solution of an acidic or basic cleaner, a surfactant together with a silicone glycol and xanthan gum as anti-fogging agents.
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