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公开(公告)号:US20240413394A1
公开(公告)日:2024-12-12
申请号:US18813086
申请日:2024-08-23
Inventor: YOSHIAKI TANAKA , TAKASHI KUBO , KEITA MIZUNO
IPC: H01M10/0562 , C01G25/00 , C01G35/00 , H01M10/0585
Abstract: A solid electrolyte material includes a solid electrolyte and an oxide material. The solid electrolyte includes Li, M, O, and X. M is at least one selected from the group consisting of Nb, Ta, and Zr. X is at least one selected from the group consisting of F, Cl, Br, and I. The oxide material includes at least one selected from the group consisting of oxides of divalent metal elements and oxides of trivalent metal elements. The mass proportion of the oxide material to the solid electrolyte is 1% or more and 50% or less. A battery includes a positive electrode, a negative electrode, and a solid electrolyte layer disposed between the positive electrode and the negative electrode, and at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the above solid electrolyte material.
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公开(公告)号:US20250015286A1
公开(公告)日:2025-01-09
申请号:US18890830
申请日:2024-09-20
Inventor: KEITA MIZUNO , YOSHIAKI TANAKA , AKIHIRO SAKAI
Abstract: An oxyhalide material of the present disclosure contains Li, M, O, and X. M is at least two selected from Group 5 elements. X is at least one selected from the group consisting of F, Cl, Br, and I. The oxyhalide material of the present disclosure shows a reversible oxidation-reduction reaction. In an X-ray diffraction pattern obtained by X-ray diffraction measurement on the oxyhalide material using Cu-Kα radiation, at least one peak is present in a first range, and (A) or (B) below is satisfied: (A) No peak is present in a second range. (B) At least one peak is present in the second range, and a ratio of intensity Ip1 of a peak with the highest intensity present in the first range to intensity Ip2 of a peak with the highest intensity present in the second range Ip1/Ip2 is larger than 5.
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公开(公告)号:US20230018638A1
公开(公告)日:2023-01-19
申请号:US17933097
申请日:2022-09-17
Inventor: TAKASHI KUBO , KAZUFUMI MIYATAKE , KEITA MIZUNO , TETSUYA ASANO , AKIHIRO SAKAI
IPC: C01F17/36 , H01B1/06 , H01M10/0562
Abstract: The production method of the present disclosure includes heat-treating a material mixture containing a compound containing Y, a compound containing Sm, NH4α, Liβ, and Caγ2 in an inert gas atmosphere. The compound containing Y is at least one selected from the group consisting of Y2O3 and Yδ3, and the compound containing Sm is at least one selected from the group consisting of Sm2O3 and Smε3. The material mixture contains at least one selected from the group consisting of Y2O3 and Sm2O3, and α, β, γ, δ, and ε are each independently at least one selected from the group consisting of F, Cl, Br, and I.
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公开(公告)号:US20220209291A1
公开(公告)日:2022-06-30
申请号:US17698000
申请日:2022-03-18
Inventor: TAKASHI KUBO , KENTA NAGAMINE , KEITA MIZUNO , TETSUYA ASANO , AKIHIRO SAKAI
IPC: H01M10/0562 , H01M10/0525
Abstract: A solid electrolyte material includes Li, Ca, Y, Gd, and X wherein X is at least one element selected from the group consisting of F, Cl, Br, and I. A battery uses the solid electrolyte material.
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公开(公告)号:US20230387458A1
公开(公告)日:2023-11-30
申请号:US18362963
申请日:2023-08-01
Inventor: KEITA MIZUNO , YOSHIAKI TANAKA , TETSUYA ASANO , AKIHIRO SAKAI
IPC: H01M10/0562 , H01M10/0525 , H01M4/62 , C01F17/36
CPC classification number: H01M10/0562 , H01M10/0525 , H01M4/62 , C01F17/36 , H01M2300/008 , C01P2002/72 , C01P2006/40
Abstract: A solid electrolyte material of the present disclosure contains Li, Yb, and X. X is at least two selected from the group consisting of F, Cl, Br, and I. A battery of the present disclosure includes a positive electrode, a negative electrode, and an electrolyte layer disposed between the positive electrode and the negative electrode. At least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material of the present disclosure.
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公开(公告)号:US20230015865A1
公开(公告)日:2023-01-19
申请号:US17933098
申请日:2022-09-17
Inventor: TAKASHI KUBO , KAZUFUMI MIYATAKE , KEITA MIZUNO , TETSUYA ASANO , AKIHIRO SAKAI
IPC: C01F17/253
Abstract: A production method for producing a halide, the method includes a heat treatment step of heat-treating a mixed material containing (NH4)aYα3+a, (NH4)bSmβ3+b, Liγ, and Caδ2 in an inert gas atmosphere, wherein α, β, γ, and δ are each independently at least one selected from the group consisting of F, Cl, Br, and I, and the following three formulas: 0≤a≤3, 0≤b≤3, and 0
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公开(公告)号:US20250015291A1
公开(公告)日:2025-01-09
申请号:US18890833
申请日:2024-09-20
Inventor: KEITA MIZUNO , YOSHIAKI TANAKA , AKIHIRO SAKAI
IPC: H01M10/0562 , H01M10/052
Abstract: A positive electrode material of the present disclosure comprises a positive electrode active material, a first solid electrolyte, and a second solid electrolyte. The first solid electrolyte consists of Li, M1, and X1. The second solid electrolyte consists of Li, M2, O, and X2. M1 is at least one selected from the group consisting of Al, Ti, and Zr. M2 is at least one selected from Group 5 elements. X1 and X2 are each independently at least one selected from the group consisting of F, Cl, Br, and I and comprise F.
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公开(公告)号:US20240413393A1
公开(公告)日:2024-12-12
申请号:US18813081
申请日:2024-08-23
Inventor: YOSHIAKI TANAKA , YOHEI HAYASHI , KEITA MIZUNO
IPC: H01M10/0562 , H01M10/0525
Abstract: A solid electrolyte material of the present disclosure includes Li, M, A, and X. M is at least one selected from the group consisting of Nb, Ta, and Zr. A is at least one selected from the group consisting of O and S. X is at least one selected from the group consisting of F, Cl, Br, and I. The solid electrolyte material of the present disclosure has a Young's modulus of less than 23 GPa. A battery of the present disclosure includes a positive electrode, a negative electrode, and a solid electrolyte layer disposed between the positive electrode and the negative electrode, and at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material of the present disclosure.
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9.
公开(公告)号:US20240250299A1
公开(公告)日:2024-07-25
申请号:US18624258
申请日:2024-04-02
Inventor: KAZUFUMI MIYATAKE , KEITA MIZUNO , TAKASHI KUBO , AKINOBU MIYAZAKI
IPC: H01M10/0562
CPC classification number: H01M10/0562 , H01M2300/008
Abstract: The solid electrolyte material of the present disclosure is a solid electrolyte material including Li, Y, and I, wherein in an X-ray diffraction pattern of the solid electrolyte material obtained by X-ray diffraction measurement using Cu-Kα rays, the peak having the highest intensity among the peaks present in a diffraction angle 2θ range of greater than or equal to 25.0° and less than or equal to 29.1° has a half value width of less than 0.89°. The battery of the present disclosure includes a positive electrode, a negative electrode, and an electrolyte layer disposed between the positive electrode and the negative electrode. At least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material of the present disclosure.
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公开(公告)号:US20240021870A1
公开(公告)日:2024-01-18
申请号:US18362962
申请日:2023-08-01
Inventor: KEITA MIZUNO , TETSUYA ASANO , AKIHIRO SAKAI
IPC: H01M10/0562
CPC classification number: H01M10/0562 , H01M2300/008
Abstract: A solid electrolyte material of the present disclosure contains Li, Yb, M, and X. M is at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Y, Tb, Gd, Sm, In, Zr, and Hf. X is at least one selected from the group consisting of F, Cl, Br, and I. A battery of the present disclosure includes a positive electrode, a negative electrode, and an electrolyte layer disposed between the positive electrode and the negative electrode. At least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material of the present disclosure.
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