Abstract:
An electrode catalyst for a fuel battery includes a mesoporous material and catalyst metal particles supported at least in the mesoporous material. In the electrode catalyst for a fuel battery, before supporting the catalyst metal particles, the mesoporous material has mesopores having a mode radius of greater than or equal to 1 nm and less than or equal to 25 nm and has a value of greater than 0.90, the value being determined by dividing a specific surface area S1-25 (m2/g) of the mesopores obtained by analyzing a nitrogen adsorption-desorption isotherm according to a BJH method, the mesopores having a radius of greater than or equal to 1 nm and less than or equal to 25 nm, by a BET specific surface area (m2/g) evaluated according to a BET method.
Abstract:
An electrode catalyst according to the present disclosure includes a mesoporous material and catalyst metal particles which are supported in at least an inner portion of the mesoporous material and which contain platinum and a metal different from platinum. The mesoporous material has mesopores having a mode radius of greater than or equal to 1 nm and less than or equal to 25 nm and a pore volume of greater than or equal to 1.0 cm3/g and less than or equal to 3.0 cm3/g. The catalyst metal particles which are supported have an L10 structure. The proportion of the L10 structure is greater than 0.25.
Abstract:
A catalyst includes a mesoporous material and catalytic metal particles supported at least within the mesoporous material and containing platinum and a metal different from platinum. The mesoporous material has mesopores with a mode radius of 1 to 25 nm and a pore volume of 1.0 to 3.0 cm3/g before supporting of the catalytic metal particles, and has an average particle size of greater than or equal to 200 nm. A molar ratio of the metal different from platinum and contained in the catalytic metal particles relative to all metals contained in the catalytic metal particles is greater than or equal to 0.25, and among the catalytic metal particles, a volume ratio of catalytic metal particles having a particle size of greater than or equal to 20 nm is less than or equal to 10%.
Abstract:
The present invention provides a method for generating oxygen. The method comprises (a) preparing a water electrolysis device comprising a container storing an electrolyte aqueous solution; an anode which is in contact with the electrolyte aqueous solution and includes at least one silver delafossite compound selected from the group consisting of a silver cobalt delafossite compound represented by a chemical formula AgCoO2 and a silver rhodium delafossite compound represented by a chemical formula AgRhO2; a cathode which is in contact with the electrolyte aqueous solution; and a power supply, wherein the at least one silver delafossite compound is in contact with the electrolyte aqueous solution, and (b) applying an electric potential difference between the cathode and the anode using the power supply to generate oxygen on the anode due to electrolysis of water which occurs on the at least one silver delafossite compound.
Abstract:
The present invention provides a method for efficiently generating oxygen by electrolyzing water using a copper delafossite compound as an anode. First, in the present invention, a water electrolysis device is prepared. The water electrolysis device comprises a container, a power supply, an anode, a cathode; and an aqueous electrolytic solution. The anode and the cathode are in contact with the aqueous electrolytic solution. The anode has a copper cobalt delafossite compound represented by a chemical formula CuCoO2. The copper cobalt delafossite compound is in contact with the aqueous electrolytic solution. Then, an electric potential difference is applied between the cathode and the anode using the power supply to generate oxygen on the anode due to electrolysis of water which occurs on the copper cobalt delafossite compound.