公开(公告)号：US06322888B1

公开(公告)日：2001-11-27

申请号：US09147519

申请日：1999-09-03

申请人： Patrick Moireau ,  Bruno Gibello ,  Marc Roubin

发明人： Patrick Moireau ,  Bruno Gibello ,  Marc Roubin

IPC分类号： D02G300

CPC分类号： C03C25/36 ,  C03C25/12 ,  C03C25/26 ,  Y10T428/2938 ,  Y10T428/2964

摘要： A process for producing sized glass yarns, which entails: a) drawing streams of molten glass from orifices located at a bottom of one or more dies, in a form of one or more fans of continuous filaments, b) assembling the filaments into one or more moving supports, wherein a first stable composition having a viscosity of between 0.5 and 250 cP is deposited onto the surface of the continuous filaments, and a second stable composition, supplied separately from the first and having a viscosity of between 0.5 and 300 cP, is deposited onto the surface of the filaments of the yarns, at the earliest during deposition of the first composition and at the latest during collection of the years, the difference in viscosity between the two compositions deposited being less than 150 cP, the mixture of the deposited compositions functioning as a sizing composition and being polymerizable at room temperature.

摘要翻译： 一种用于生产尺寸规格的玻璃纱线的方法，其包括：a）以连续长丝的一个或多个风扇的形式从位于一个或多个模具的底部的孔抽出熔融玻璃流，b）将长丝组装成一个或多个 更移动的载体，其中粘度为0.5至250cP的第一稳定组合物沉积在连续长丝的表面上，和第二稳定组合物，与第一稳定组合物分开供应，粘度为0.5-300cP， 在第一组合物的沉积期间最早沉积在纱线的长丝的表面上，并且在最近几年的收集期间，沉积的两种组合物之间的粘度差小于150cP， 用作施胶组合物并在室温下可聚合的沉积组合物。

公开(公告)号：US06884469B1

公开(公告)日：2005-04-26

申请号：US10149633

申请日：2000-08-24

申请人： Patrick Moireau ,  Bruno Gibello

发明人： Patrick Moireau ,  Bruno Gibello

IPC分类号： C03C25/20 ,  C03C25/26 ,  D01G29/00 ,  B05D1/28 ,  C23C20/22

CPC分类号： C03C25/20 ,  C03C25/26 ,  D01D5/096 ,  D01G29/00

摘要： The invention relates to a process for manufacturing a continuous yarn, and the product obtained from such process. A multiplicity of continuous filaments are formed by the mechanical drawing of a multiplicity of streams of molten thermoplastic(s) flowing from the orifices of at least one fiberizing device. A mixture, in the liquid state, is deposited on the surface of at least some of the filaments before they are brought together into at least one yarn. An absorbent mat may be continuously impregnated, with at least some of said mixture being continuously taken up by means of a rotating roller in contact with said mat, and using a sizing roller, said mixture may be deposited on the filaments while they are being drawn.

摘要翻译： 本发明涉及一种用于制造连续纱线的方法，以及从该方法获得的产品。 通过从至少一个纤维化装置的孔流动的多个熔融热塑性物流的机械拉伸来形成多个连续长丝。 在将液体状态的混合物聚集成至少一根纱线之前，将液体状态的混合物沉积在至少一些长丝的表面上。 可以连续地浸渍吸收垫，其中至少一些所述混合物通过与所述垫接触的旋转辊连续吸收，并且使用施胶辊，所述混合物可以在被拉伸时沉积在长丝上 。

公开(公告)号：US06316058B1

公开(公告)日：2001-11-13

申请号：US09284463

申请日：1999-09-29

申请人： Patrick Moireau ,  Bruno Gibello

发明人： Patrick Moireau ,  Bruno Gibello

IPC分类号： C03C2502

CPC分类号： D06B1/14 ,  C03C25/20

摘要： A process for manufacturing a continuous yarn, which entails the steps of: a) continously impregnating a mat of mechanically held-together fibers with a mixture of anhydrous size in a liquid state; b) continuosly taking up at least some of the mixture of the anhydrous size by a sizing roller in contact with the mat such that a liquid film having an almost constant thickness of less than 8 &mgr;m is formed thereon; and c) depositing the mixture of the anhydrous size, using the sizing roller, on a surface of at least some of a multiplicity of continuous filaments which are formed by mechanical drawing of at least a multiplicity of streams containing molten glass flowing out of orifices of at least one device.

摘要翻译： 一种用于制造连续纱线的方法，其包括以下步骤：a）用液体状态的无水大小的混合物连续浸渍机械保持在一起的纤维垫; b）连续地吸收至少一些混合物， 通过与所述垫接触的施胶辊进行无水尺寸，使得在其上形成具有小于8μm的几乎恒定厚度的液膜; 以及c）使用所述施胶辊将所述无水大小的混合物沉积在多个连续细丝中的至少一些的表面上，所述多个连续长丝通过机械拉伸至少多个含有熔融玻璃的流动而形成， 至少一个设备。

公开(公告)号：US06514612B1

公开(公告)日：2003-02-04

申请号：US09581910

申请日：2000-09-12

申请人： Patrick Moireau ,  Marc Roubin

发明人： Patrick Moireau ,  Marc Roubin

IPC分类号： D02G300

CPC分类号： C03C25/26 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2962 ,  Y10T428/2964

摘要： The present invention relates to a sizing composition for a glass yarn, consisting of a solution whose solvent content is less than 5% by weight, this solution comprising at least 60% by weight of polymerizable components, at least 60% by weight of these polymerizable components being components with a molecular mass of less than 750 and these polymerizable components comprising at least one mixture capable of polymerizing: of component(s) containing at least one reactive acrylic function and/or at least one reactive methacrylic function, and of component(s) containing at least one reactive primary amine function and/or at least one reactive secondary amine function, at least 20% of the polymerizable components containing at least two reactive functions chosen from acrylic, methacrylic, primary amine and secondary amine functions.

摘要翻译： 本发明涉及一种用于玻璃纱线的上胶组合物，其由溶剂含量小于5重量％的溶液组成，该溶液包含至少60重量％的可聚合组分，至少60重量％的这些可聚合的 组分是分子量小于750的组分，并且这些可聚合组分包含至少一种能够聚合的混合物：包含至少一种反应性丙烯酸官能团和/或至少一种反应性甲基丙烯酸官能团的组分，和组分 ）包含至少一种反应性伯胺官能团和/或至少一种反应性仲胺官能团，至少20％的可聚合组分含有至少两种选自丙烯酸，甲基丙烯酸，伯胺和仲胺官能团的反应性官能团。

公开(公告)号：US20090305042A1

公开(公告)日：2009-12-10

申请号：US12158598

申请日：2006-12-18

申请人： Patrick Moireau ,  Jean-Baptiste Denis

发明人： Patrick Moireau ,  Jean-Baptiste Denis

IPC分类号： B32B5/16 ,  C09K3/00

CPC分类号： C09C1/0078 ,  B82Y30/00 ,  C01P2004/64 ,  C09C1/42 ,  C09C3/12 ,  Y10T428/2991

摘要： The present invention relates to a method for preparing lamellar nanoparticles, the method including: a) mixing a laminated material with a blowing agent chosen from polyols to obtain an expanded laminated material, b) reacting the expanded laminated material with a grafting agent in the presence of water and an acid, said agent corresponding to the general formula RaXY4-a  in which R represents a hydrogen atom or a hydrocarbon-based radical incorporating 1 to 40 carbon atoms, the R groups possibly being identical or different; X represents a silicon, zirconium or titanium atom; Y is an alkoxy group containing 1 to 12 carbon atoms, or a halogen; and a is equal to 1, 2 or 3; and c) recovering at least one lamellar nanoparticle.

摘要翻译： 本发明涉及一种制备层状纳米颗粒的方法，该方法包括：a）将层压材料与选自多元醇的发泡剂混合以获得膨胀的层压材料，b）在存在的情况下使膨胀的层压材料与接枝剂反应 的水和酸，所述试剂对应于通式RaXY4-a，其中R表示氢原子或含有1至40个碳原子的烃基基团，R基团可以相同或不同; X表示硅，锆或钛原子; Y是含有1至12个碳原子的烷氧基或卤素; a等于1,2或3; 和c）回收至少一个层状纳米颗粒。

公开(公告)号：US07276282B2

公开(公告)日：2007-10-02

申请号：US10506674

申请日：2003-03-26

申请人： Eric Dallies ,  Patrick Moireau

发明人： Eric Dallies ,  Patrick Moireau

IPC分类号： B32B9/00 ,  C08K9/06

CPC分类号： C03C25/40 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2962 ,  Y10T428/2964

摘要： The present invention relates to reinforcement yarns coated with a sizing composition comprising at least one silane satisfying the formula: Si(R1)(R2)(R3)(R4) in which: R1, R2 and R3 are chosen from the following atoms or groups: —H (except in the case of R3), —Cl, —O—R5, —O—R6—O—R5, —O—(C═O)—R5, —O—R6—(C═O)—R5, R5 and R6 being chosen from hydrocarbon radicals whose main chain has from 1 to 4 carbon atoms; R4═—R7—NHR8 R7 being chosen from branched hydrocarbon radicals whose main chain has from 2 to 6 carbon atoms, R8 being chosen from the following groups: —H, —R9—NH2, —R10—NH—R9—NH2, R9 being chosen from hydrocarbon radicals containing 1 to 12 carbon atoms or from carbonyls, and R10 being chosen from hydrocarbon radicals whose main chain has from 1 to 6 carbon atoms. The glass yarns according to the invention are particularly suitable for reinforcing organic materials, the yarns and composites obtained resisting in a corrosive medium.

摘要翻译： 本发明涉及涂覆有包含至少一种满足以下公式的硅烷的施胶组合物的增强纱线：<？in-line-formula description =“In-line Formulas”end =“lead”？> Si（R 1 （R 2）（R 3）（R 4）在线式描述=“In- 其中：R 1，R 2和R 3选自以下原子或基团，其中R 1，R 2，R 3，R 3， ：-H（除了R 3的情况除外），-Cl，-OR 5，-OR 6，-OR 5 -O-（CO）-R 5，-OR 6 - （CO）-R 5，R SUP > 5和R 6选自主链具有1至4个碳原子的烃基; R 4选自支链烃基，其主链具有以下基团：支链烃基，其主链具有 2至6个碳原子，R 8选自以下基团：-H，-R 9 -NH 2，-R SUP > 10个-NH-R 9 -NH 2，R 9选自含有1至12个碳原子的烃基或 来自羰基，R 10选自主链具有1至6个碳原子的烃基。 根据本发明的玻璃纱线特别适用于增强有机材料，在腐蚀性介质中获得的纱线和复合材料。

公开(公告)号：US5601882A

公开(公告)日：1997-02-11

申请号：US282476

申请日：1994-07-29

申请人： Eric Augier ,  Timothy Johnson ,  Patrick Moireau

发明人： Eric Augier ,  Timothy Johnson ,  Patrick Moireau

IPC分类号： C03B37/16 ,  C03C25/10 ,  C03C25/12 ,  D01G1/02 ,  B05D3/06

CPC分类号： C03C25/12 ,  C03B37/16 ,  Y02P40/57

摘要： A process and device for manufacturing cut threads according to which glass threads composed of continuous filaments are coated with a liquid non-aqueous size, which can react under the effect of actinic radiation. The threads are cut by a member which is also used to draw or entrain the threads mechanically before they are subjected to actinic radiation.

摘要翻译： 用于制造切割螺纹的方法和装置，根据该方法和装置，用连续长丝组成的玻璃丝涂覆有非水性液体，其可以在光化辐射的作用下反应。 螺纹由成员切割，该部件也用于在经受光化辐射之前机械地牵引或夹带螺纹。

公开(公告)号：US07241499B2

公开(公告)日：2007-07-10

申请号：US10496791

申请日：2002-12-05

申请人： Patrick Moireau

发明人： Patrick Moireau

IPC分类号： C03C17/02 ,  B32B9/00

CPC分类号： C03C25/26 ,  Y10T428/2907 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2962 ,  Y10T428/2964

摘要： The invention relates to a sizing composition composed of a solution comprising at least 5% by weight of solvent and comprising a thermally curable base system, said system comprising at least 60% by weight of components with a molecular mass of less than 750 and at least 60% by weight of components of a mixture exhibiting at least one epoxy reactive functional group, at least one amine, preferably primary or secondary amine, reactive functional group, and at least one hydroxyl reactive functional group. Another subject matter of the invention relates to the glass strands coated with the abovementioned sizing composition. The glass strands obtained are capable of being used to reinforce organic or inorganic materials.

摘要翻译： 本发明涉及由包含至少5重量％的溶剂并包含可热固化的基础体系的溶液组成的施胶组合物，所述体系包含至少60重量％的分子量小于750的组分和至少 60重量％的表现出至少一个环氧反应性官能团的混合物的组分，至少一种胺，优选伯胺或仲胺，反应性官能团和至少一个羟基反应性官能团。 本发明的另一主题涉及涂覆有上述施胶组合物的玻璃纤维。 获得的玻璃股能够用于增强有机或无机材料。

公开(公告)号：US06929211B1

公开(公告)日：2005-08-16

申请号：US10031574

申请日：2000-06-28

申请人： Guenther Mager ,  Patrick Moireau

发明人： Guenther Mager ,  Patrick Moireau

IPC分类号： B65H54/28 ,  B65H54/32 ,  B65H55/04

CPC分类号： B65H54/325 ,  B65H55/04 ,  B65H2701/3122

摘要： Method of manufacturing a frustoconical bobbin which is obtained by depositing superposed layers of a yarn onto a cylindrical support of longitudinal axis and comprises a base cone having a generatrix, an unwind cone having a generatrix and a main body having a generatrix which is inclined with respect to the axis and joins the two generatrices of the two cones. The method is characterized in that it comprises two rules governing the movement of the yarn guide, a first rule which is used to form part of the base cone, the last layer of yarn deposited according to this first rule going as far as the end of the unwind cone, and a second rule which is used to terminate the said base cone that has been started and, concomitantly, to form the main body and the unwind cone, the first layer of yarn deposited according to the second rule being parallel to the last layer deposited according to the first rule.

摘要翻译： 截头圆锥形筒管的制造方法是通过将一层纱线沉积在纵向轴线的圆柱形支撑件上而获得的，并且包括具有母线的底锥，具有母线的展开锥体和具有相对倾斜的母线的主体 并连接到两个锥体的两根母线上。 该方法的特征在于它包括两条规则，这些规则适用于导纱器的运动，该规则是用于形成底锥的一部分的第一规则，根据该第一规则沉积的最后一层纱线，直到最后 展开锥体和用于终止已经启动的所述基础锥体的第二规则，并且伴随地形成主体和展开锥体，根据第二规则沉积的第一层纱线平行于 最后一层按照第一条规则存放。

公开(公告)号：US06185963B1

公开(公告)日：2001-02-13

申请号：US08933038

申请日：1997-09-18

申请人： Patrick Moireau ,  Timothy Johnson

发明人： Patrick Moireau ,  Timothy Johnson

IPC分类号： C03B4002

CPC分类号： C03C25/26 ,  Y10T428/2936 ,  Y10T428/2938 ,  Y10T428/2962 ,  Y10T428/2964

摘要： The invention relates to a process for manufacturing continuous a glass fiber strand. The process consists in depositing on the glass filaments which are in the process of being drawn a sizing composition consisting of a solution of which the solvent content is less than 5 wt %, the solution comprising a mixture of constituents which can be polymerized and/or crosslinked by heat treatment, at least 60 wt % of the constituents being constituents of which the molecular weight (Mw) is less than 750, less than 10 weight % being film-forming agents and 0 to 25 weight % being coupling agents, lubricants, stabilizers and initiators and/or catalysts, it being possible if necessary for the agent to be polymerized and/or crosslinked by heat treatment, in winding the strand or strands, formed by collection of the filaments, on a rotating support so as to form a wound package consisting of turns of strand coated with a non-polymerized sizing composition. The strands are intended to reinforce thermoplastic or thermosetting organic substrates or substances of mineral origin.

摘要翻译： 本发明涉及连续玻璃纤维束的制造方法。 该方法包括沉积在正在拉伸的溶液含量小于5重量％的溶液组成的施胶组合物的过程中的玻璃纤维，该溶液包含可以聚合的成分的混合物和/或 通过热处理交联，至少60重量％的组分是其分子量（Mw）小于750，小于10重量％的成膜剂和0至25重量％的偶联剂，润滑剂， 稳定剂和引发剂和/或催化剂，如果需要，通过热处理可将聚合和/或交联的试剂在通过收集长丝形成的丝束或绞线卷绕在旋转的载体上以形成 缠绕包装，其由涂覆有非聚合施胶组合物的线股匝组成。 股线旨在加强热塑性或热固性有机基底或矿物来源的物质。