Linear polyalkylene ether glycols of high molecular weight
    4.
    发明授权
    Linear polyalkylene ether glycols of high molecular weight 失效
    高分子量的线性聚亚烷基醚二醇

    公开(公告)号:US4275244A

    公开(公告)日:1981-06-23

    申请号:US57229

    申请日:1979-07-13

    IPC分类号: C08G65/34 C08G65/42 C07C43/11

    摘要: Linear polypropylene ether glycols of high molecular weight are made by reacting a linear polypropylene ether glycol of lower molecular weight first with an alkaline agent such as sodium hydroxide or other suitable base to form an alcoholate, and then coupling the alcoholate with a suitable difunctional coupling agent, such as the benzene-sulfonic acid diester of ethylene glycol or with some other suitable arylsulfonic acid diester of a C.sub.2 to C.sub.6 alcohol, thereby obtaining a 100 percent linear polypropylene ether glycol of a desirably higher molecular weight. Materials so produced find use in an aqueous medium as defoaming agents, thickeners, or emulsifiers, and use as protective colloids to improve the low-temperature stability of polyurethane and other latices.

    摘要翻译: 通过使低分子量的线性聚丙烯醚二醇与碱性试剂如氢氧化钠或其它合适的碱反应形成醇化物,然后将醇化物与合适的双官能偶联剂 ,例如乙二醇的苯磺酸二酯或与C 2至C 6醇的一些其它合适的芳基磺酸二酯,从而获得理想的较高分子量的100%线性聚丙烯醚二醇。 如此制造的材料在水性介质中用作消泡剂,增稠剂或乳化剂,并且用作保护胶体以改善聚氨酯和其它胶乳的低温稳定性。

    Removal of oligomer deposits from textile materials
    7.
    发明授权
    Removal of oligomer deposits from textile materials 失效
    从纺织材料中去除低聚物沉积物

    公开(公告)号:US4294576A

    公开(公告)日:1981-10-13

    申请号:US152178

    申请日:1980-05-22

    CPC分类号: D06M13/46 D06P5/06

    摘要: A process for removing oligomer deposits from dyed and non-dyed textile materials which consist of polyester fibers or of blends of these fibers with other fibers, and from dyeing machinery, by a treatment with an aqueous, alkaline liquor which contains from 0.1 to 10 g/l of a quaternary ammonium compound carrying not less than two C.sub.6 -C.sub.22 -alkyl or -alkenyl groups on the quaternary nitrogen, at up to 100.degree. C. The oligomers are hydrolyzed and are removed together with the treatment liquor.

    摘要翻译: 从由染色和非染色的纺织材料中除去低聚物沉积物的方法,其由聚酯纤维或这些纤维与其它纤维的共混物和染色机械组成,通过用含有0.1至10g / l的季铵化合物,在高达100℃下在季氮上携带不少于两个C 6 -C 22 - 烷基或 - 烯基。低聚物被水解并与处理液一起除去。

    Polyether polyols and method of preparing same
    8.
    发明授权
    Polyether polyols and method of preparing same 失效
    聚醚多元醇及其制备方法

    公开(公告)号:US4113785A

    公开(公告)日:1978-09-12

    申请号:US736959

    申请日:1976-10-29

    摘要: New polyether polyols of predetermined structure are prepared by reacting polyether bis alcoholates with selected bis epoxides. Specifically, a polyoxyalkylene glycol is converted to the bis alcoholate, and then the bis alcoholate is reacted with an equivalent amount of a glycol bis glycidyl ether, with the reactants being mixed together all at once. The polyether polyalcoholate thus obtained is converted to a high molecular weight polyether polyol by acid neutralization or ion exchange.

    摘要翻译: 通过聚醚双醇酯与选择的双环氧化物反应制备具有预定结构的新型聚醚多元醇。 具体地说,将聚氧化亚烷基二醇转化成双醇化物,然后使双醇化物与等量的二醇双缩水甘油醚反应,同时将反应物全部混合在一起。 由此获得的聚醚多元醇酸通过酸中和或离子交换转化为高分子量聚醚多元醇。