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公开(公告)号：US4061684A
公开(公告)日：1977-12-06
申请号：US736939
申请日：1976-10-29
IPC分类号： C08G65/334 , C07C43/00 , C10M7/16
CPC分类号： C08G65/3344
摘要： Highly branched polyether polyols of high molecular weight (such as over 12,000) are made by coupling an alkoxylated polyglycerol, by reaction of the sodium alcoholate of the oxyalkylated polyglycerol with a dibenzenesulfo or ditoluenesulfo ester of a diol containing 2 to 6 carbon atoms. Products obtained are viscous resinous products which are particularly suitable for use as hydrophilic water-swellable gels and other purposes.
摘要翻译： 通过使烷氧基化聚甘油的醇钠与含有2至6个碳原子的二醇的二苯磺酸或二甲苯磺酸酯的反应，通过偶联烷氧基化聚甘油来制备高分子量的高支化聚醚多元醇（如12,000以上）。 获得的产品是特别适合用作亲水性水溶胀性凝胶和其它目的的粘性树脂产品。
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公开(公告)号：US4113785A
公开(公告)日：1978-09-12
申请号：US736959
申请日：1976-10-29
IPC分类号： C08G65/26 , C08G65/28 , C08G65/321 , C08G65/331 , C07C41/02 , C07C43/10
CPC分类号： C08G65/3312 , C08G65/26 , C08G65/321 , Y10S516/01
摘要： New polyether polyols of predetermined structure are prepared by reacting polyether bis alcoholates with selected bis epoxides. Specifically, a polyoxyalkylene glycol is converted to the bis alcoholate, and then the bis alcoholate is reacted with an equivalent amount of a glycol bis glycidyl ether, with the reactants being mixed together all at once. The polyether polyalcoholate thus obtained is converted to a high molecular weight polyether polyol by acid neutralization or ion exchange.
摘要翻译： 通过聚醚双醇酯与选择的双环氧化物反应制备具有预定结构的新型聚醚多元醇。 具体地说，将聚氧化亚烷基二醇转化成双醇化物，然后使双醇化物与等量的二醇双缩水甘油醚反应，同时将反应物全部混合在一起。 由此获得的聚醚多元醇酸通过酸中和或离子交换转化为高分子量聚醚多元醇。
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公开(公告)号：US4275244A
公开(公告)日：1981-06-23
申请号：US57229
申请日：1979-07-13
申请人： Herbert Helfert , Pauls Davis
发明人： Herbert Helfert , Pauls Davis
CPC分类号： C08G65/3344 , C08G65/3317 , C08G65/34 , Y10S516/02
摘要： Linear polypropylene ether glycols of high molecular weight are made by reacting a linear polypropylene ether glycol of lower molecular weight first with an alkaline agent such as sodium hydroxide or other suitable base to form an alcoholate, and then coupling the alcoholate with a suitable difunctional coupling agent, such as the benzene-sulfonic acid diester of ethylene glycol or with some other suitable arylsulfonic acid diester of a C.sub.2 to C.sub.6 alcohol, thereby obtaining a 100 percent linear polypropylene ether glycol of a desirably higher molecular weight. Materials so produced find use in an aqueous medium as defoaming agents, thickeners, or emulsifiers, and use as protective colloids to improve the low-temperature stability of polyurethane and other latices.
摘要翻译： 通过使低分子量的线性聚丙烯醚二醇与碱性试剂如氢氧化钠或其它合适的碱反应形成醇化物，然后将醇化物与合适的双官能偶联剂 ，例如乙二醇的苯磺酸二酯或与C 2至C 6醇的一些其它合适的芳基磺酸二酯，从而获得理想的较高分子量的100％线性聚丙烯醚二醇。 如此制造的材料在水性介质中用作消泡剂，增稠剂或乳化剂，并且用作保护胶体以改善聚氨酯和其它胶乳的低温稳定性。
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公开(公告)号：US3963714A
公开(公告)日：1976-06-15
申请号：US530305
申请日：1974-12-06
IPC分类号： C07D251/34 , C07D251/54 , C07D251/70 , D06P1/66 , D06P3/76 , C07D251/46 , C07D251/52
摘要： Special quaternary ammonium salts of 2,4,6-tris-(.omega.-dialkylamino-alkyleneamino)-triazines and 2,4,6-tris-(.omega.-dialkylaminoalkoxy)-triazines and their use in dyeing anionic polyacrylonitrile fibers with basic dyes; these special derivatives of triazine are particularly effective retarders.
摘要翻译： 2,4,6-三 - （ω-二烷基氨基 - 亚氨基氨基） - 三嗪和2,4,6-三 - （ω-二烷基氨基烷氧基） - 三嗪的特殊季铵盐及其用于染色阴离子聚丙烯腈纤维与碱性染料的用途; 这些三嗪的特殊衍生物是特别有效的缓凝剂。
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公开(公告)号：US5948945A
公开(公告)日：1999-09-07
申请号：US45911
申请日：1998-03-23
申请人： Rudolf Erich Lorenz , Herbert Helfert , Martin Schmidt-Radde , Hans-Peter Schildberg , Gunter Saladin
发明人： Rudolf Erich Lorenz , Herbert Helfert , Martin Schmidt-Radde , Hans-Peter Schildberg , Gunter Saladin
CPC分类号： C07C11/24
摘要： A process for vinylation of an organic acidic-hydrogen compound, which entails reacting an organic acidic-hydrogen compound with acetylene or an acetylene-containing gas under elevated pressure and at elevated temperature in the presence of a base, wherein reactor regions initiating decomposition of acetylene are treated with an effective amount of a chemically inert oil of medium viscosity.
摘要翻译： 一种使有机酸性氢化合物发生乙烯化的方法，其使得有机酸性氢化合物与乙炔或含乙炔的气体在升高的压力和升高的温度下在碱的存在下反应，其中反应器区域引发乙炔的分解 用有效量的中等粘度的化学惰性油处理。
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公开(公告)号：US5710284A
公开(公告)日：1998-01-20
申请号：US708820
申请日：1996-09-09
IPC分类号： C07B63/00 , C07D207/26 , C07D207/267 , C07D207/08
CPC分类号： C07D207/267
摘要： In a process for purifying N-vinylpyrrolidone by crystallization in a crystallizer, those surfaces of the crystallizer from which crystals grow during the crystallization are covered with an N-vinylpyrrolidone seed layer before the crystallization.
摘要翻译： 在结晶器中通过结晶纯化N-乙烯基吡咯烷酮的方法中，在结晶之前晶体生长的结晶器的那些表面在结晶之前用N-乙烯基吡咯烷酮种子层覆盖。
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公开(公告)号：US4294576A
公开(公告)日：1981-10-13
申请号：US152178
申请日：1980-05-22
摘要： A process for removing oligomer deposits from dyed and non-dyed textile materials which consist of polyester fibers or of blends of these fibers with other fibers, and from dyeing machinery, by a treatment with an aqueous, alkaline liquor which contains from 0.1 to 10 g/l of a quaternary ammonium compound carrying not less than two C.sub.6 -C.sub.22 -alkyl or -alkenyl groups on the quaternary nitrogen, at up to 100.degree. C. The oligomers are hydrolyzed and are removed together with the treatment liquor.
摘要翻译： 从由染色和非染色的纺织材料中除去低聚物沉积物的方法，其由聚酯纤维或这些纤维与其它纤维的共混物和染色机械组成，通过用含有0.1至10g / l的季铵化合物，在高达100℃下在季氮上携带不少于两个C 6 -C 22 - 烷基或 - 烯基。低聚物被水解并与处理液一起除去。
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9.发明授权Production of level dyeings on acrylonitrile polymer fibers with basic dyes 失效用碱性染料生产丙烯腈聚合物纤维上的水平染色
公开(公告)号：US3945794A
公开(公告)日：1976-03-23
申请号：US443824
申请日：1974-02-19
申请人： Rudolf Rokohl , Rolf Fikentscher , Herbert Helfert
发明人： Rudolf Rokohl , Rolf Fikentscher , Herbert Helfert
摘要： Acrylonitrile polymer fibers are dyed level shades with basic dyes using as leveling agent a quaternary ammonium salt containing two or three benzyl groups as nitrogen ligands.
摘要翻译： 丙烯腈聚合物纤维用碱性染料染色，使用作为流平剂的含有两个或三个苄基作为氮配体的季铵盐。
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10.发明授权公开(公告)号：US06888006B2
公开(公告)日：2005-05-03
申请号：US10275564
申请日：2001-05-10
申请人： Herbert Helfert , Martin Schmidt-Radde , Gerhard Laqua , Ulrich Eiden , Stephan Scholl , Christoph Übler
发明人： Herbert Helfert , Martin Schmidt-Radde , Gerhard Laqua , Ulrich Eiden , Stephan Scholl , Christoph Übler
IPC分类号： B01D3/14 , B01J3/00 , C07D201/16 , C07D207/26 , C07D207/267
CPC分类号： C07D207/267 , C07D201/16
摘要： A process for working up residues from the preparation of pyrrolidone and/or N-vinylpyrrolidone comprises subjecting the residues to a thermolysis.
摘要翻译： 从制备吡咯烷酮和/或N-乙烯基吡咯烷酮处理残留物的方法包括使残余物进行热分解。
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