公开(公告)号：US07501015B2

公开(公告)日：2009-03-10

申请号：US11289620

申请日：2005-11-30

申请人： Peter Gordon Odell ,  Paul F. Smith ,  Jennifer Lynne Belelie ,  Eniko Toma ,  Stephan Drappel ,  C. Geoffrey Allen ,  Rina Carlini ,  Christopher A. Wagner

发明人： Peter Gordon Odell ,  Paul F. Smith ,  Jennifer Lynne Belelie ,  Eniko Toma ,  Stephan Drappel ,  C. Geoffrey Allen ,  Rina Carlini ,  Christopher A. Wagner

IPC分类号： C09D11/00

CPC分类号： C09D11/101 ,  C09D11/34

摘要： The phase change ink a viscosity of from about 4 mPa-s to about 50 mPa-s at a first temperature and has a viscosity of from 104 mPa-s to about 109 mPa-s at a second lower temperature. The second temperature may be below the first temperature by at least 10° C. but by no more than 50° C. The first temperature may be from about 60° C. to about 110° C. and the second temperature may be from about 20° C. to about 70° C. A curve of log10 viscosity of the phase change ink plotted against temperature in degrees Celsius may have a slope having an absolute value less than 0.02 at the first temperature and have a slope having an absolute value greater than 0.08 for at least a region second temperatures.

摘要翻译： 相变墨在第一温度下的粘度为约4mPa·s至约50mPa·s，并且在第二较低温度下的粘度为104mPa·s至约109mPa·s。 第二温度可以低于第一温度至少10℃，但不超过50℃。第一温度可以为约60℃至约110℃，第二温度可以为约 20℃至约70℃。相变油墨的log 10粘度与温度相对于摄氏度的曲线可以具有在第一温度下具有小于0.02的绝对值的斜率，并且具有绝对值更大的斜率 至少一个区域第二温度高于0.08。

公开(公告)号：US07632546B2

公开(公告)日：2009-12-15

申请号：US11289609

申请日：2005-11-30

申请人： Peter G Odell ,  C Geoffrey Allen ,  Christopher A Wagner ,  Stephan V Drappel ,  Rina Carlini ,  Eniko Toma

发明人： Peter G Odell ,  C Geoffrey Allen ,  Christopher A Wagner ,  Stephan V Drappel ,  Rina Carlini ,  Eniko Toma

IPC分类号： B05D1/32 ,  C09D11/02

CPC分类号： C09D11/34 ,  C09D11/101

摘要： A radiation curable phase change ink preferably used in piezoelectric ink jet devices includes an ink vehicle that includes at least one gellant comprised of a curable polyamide-epoxy acrylate component and a polyamide component, and at least one colorant. The use of the gellant enables the ink to form a gel state having a viscosity of at least 103 mPa·s at very low temperatures of about 25° C. to about 100° C. The ink may thus be jetted at very low jetting temperatures of, for example, about 40° C. to about 110° C. The ink may be used to form an image by heating the ink to a first temperature at which the ink may be jetted, jetting onto a member or substrate maintained at a second temperature at which the ink forms a gel state, and exposing the ink to radiation energy to polymerize curable components of the ink.

摘要翻译： 优选用于压电喷墨装置中的可辐照固化相变油墨包括包含至少一种由可固化的聚酰胺 - 环氧丙烯酸酯组分和聚酰胺组分组成的胶凝剂和至少一种着色剂的油墨载体。 使用胶凝剂使得油墨能够在约25℃至约100℃的非常低的温度下形成粘度至少为103mPa.s的凝胶状态。因此可以在非常低的喷射温度下喷射油墨 例如约40℃至约110℃。油墨可以用于通过将油墨加热到可以喷射墨水的第一温度来形成图像，喷射到保持在油墨上的部件或基板上 油墨形成凝胶状态的第二温度，以及将油墨暴露于辐射能量以聚合油墨的可固化组分。

公开(公告)号：US20070120908A1

公开(公告)日：2007-05-31

申请号：US11289620

申请日：2005-11-30

申请人： Peter Odell ,  Paul Smith ,  Jennifer Belelie ,  Eniko Toma ,  Stephan Drappel ,  C. Allen ,  Rina Carlini ,  Christopher Wagner

发明人： Peter Odell ,  Paul Smith ,  Jennifer Belelie ,  Eniko Toma ,  Stephan Drappel ,  C. Allen ,  Rina Carlini ,  Christopher Wagner

IPC分类号： B41J2/175 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/101 ,  C09D11/34

摘要： The phase change ink a viscosity of from about 4 mPa-s to about 50 mPa-s at a first temperature and has a viscosity of from 104 mPa-s to about 109 mPa-s at a second lower temperature. The second temperature may be below the first temperature by at least 10° C. but by no more than 50° C. The first temperature may be from about 60° C. to about 110° C. and the second temperature may be from about 20° C. to about 70 ° C. A curve of log10 viscosity of the phase change ink plotted against temperature in degrees Celsius may have a slope having an absolute value less than 0.02 at the first temperature and have a slope having an absolute value greater than 0.08 for at least a region second temperatures.

摘要翻译： 相变墨在第一温度下的粘度为约4mPa·s至约50mPa·s，并且具有10-4mPa·s至约10°/ 在第二较低温度下，SUP> mPa-s。 第二温度可以低于第一温度至少10℃，但不超过50℃。第一温度可以为约60℃至约110℃，第二温度可以为约 20℃至约70℃。相变墨水的对数粘度曲线相对于摄氏温度的曲线可以具有在第一温度下具有小于0.02的绝对值的斜率，以及 在至少一个区域第二温度下具有绝对值大于0.08的斜率。

公开(公告)号：US20070120924A1

公开(公告)日：2007-05-31

申请号：US11289609

申请日：2005-11-30

申请人： Peter Odell ,  C. Allen ,  Christopher Wagner ,  Stephan Drappel ,  Rina Carlini ,  Eniko Toma

发明人： Peter Odell ,  C. Allen ,  Christopher Wagner ,  Stephan Drappel ,  Rina Carlini ,  Eniko Toma

IPC分类号： G01D11/00

CPC分类号： C09D11/34 ,  C09D11/101

摘要： A radiation curable phase change ink preferably used in piezoelectric ink jet devices includes an ink vehicle that includes at least one gellant comprised of a curable polyamide-epoxy acrylate component and a polyamide component, and at least one colorant. The use of the gellant enables the ink to form a gel state having a viscosity of at least 103 mPa·s at very low temperatures of about 25° C. to about 100° C. The ink may thus be jetted at very low jetting temperatures of, for example, about 40° C. to about 110° C. The ink may be used to form an image by heating the ink to a first temperature at which the ink may be jetted, jetting onto a member or substrate maintained at a second temperature at which the ink forms a gel state, and exposing the ink to radiation energy to polymerize curable components of the ink.

摘要翻译： 优选用于压电喷墨装置中的可辐照固化相变油墨包括包含至少一种由可固化的聚酰胺 - 环氧丙烯酸酯组分和聚酰胺组分组成的胶凝剂和至少一种着色剂的油墨载体。 使用胶凝剂使油墨能够在约25℃至约100℃的非常低的温度下形成粘度至少为10 -3 mPa.s的凝胶态。油墨可以 因此在例如约40℃至约110℃的非常低的喷射温度下喷射。油墨可以用于通过将油墨加热到可喷射油墨的第一温度来形成图像，喷射 在保持在油墨形成凝胶状态的第二温度下的构件或基底上，并将油墨暴露于辐射能量以聚合油墨的可固化组分。

公开(公告)号：US07691920B2

公开(公告)日：2010-04-06

申请号：US11034714

申请日：2005-01-14

申请人： Jennifer L. Belelie ,  Peter G. Odell ,  Eniko Toma ,  Paul F. Smith ,  Rina Carlini

发明人： Jennifer L. Belelie ,  Peter G. Odell ,  Eniko Toma ,  Paul F. Smith ,  Rina Carlini

IPC分类号： A61L24/00 ,  B01F3/04 ,  B05D1/32 ,  B41J2/01 ,  B41J2/16 ,  B41J2/17 ,  B41J29/38 ,  C07D209/48 ,  C07D303/40 ,  G01D11/00 ,  C08F2/00 ,  C08F2/46 ,  C08F14/06 ,  C08F20/22 ,  C08G59/14 ,  C08G65/18 ,  C08J3/28 ,  C09D5/00 ,  C09D11/00

CPC分类号： C09D11/101

摘要： An ink jet ink includes an ink vehicle, wherein the ink vehicle includes at least one wax monomer functionalized to include in the chain at least one reactive group curable upon exposure to radiation. The reactive group is preferably curable via cationic or free radical polymerization. In a preferred embodiment, the ink vehicle includes a wax monomer having a structure: wherein C represents a cationically curable group and R represents a radically curable group. The inks may be used to form an image by jetting the ink onto a transfuse member surface, increasing the viscosity of the ink upon the transfuse member surface, subsequently transferring the ink from the transfuse member surface to an image receiving substrate, and exposing the ink to radiation following the transfer to the image receiving substrate to effect reaction of the at least one reactive group.

摘要翻译： 喷墨油墨包括油墨载体，其中油墨载体包括至少一种蜡官能化的蜡单体，其在链中包含在暴露于辐射时可固化的至少一种反应性基团。 反应性基团优选通过阳离子或自由基聚合可固化。 在优选的实施方案中，油墨载体包括具有以下结构的蜡单体：其中C表示阳离子可固化基团，R表示可自由基固化的基团。 油墨可以用于通过将墨喷射到输入构件表面上来形成图像，增加在输入构件表面上的墨的粘度，随后将墨从输液构件表面转移到图像接收基底，并使墨 在转移到图像接收基板之后进行辐射以实现至少一个反应性基团的反应。

公开(公告)号：US07465348B1

公开(公告)日：2008-12-16

申请号：US11759913

申请日：2007-06-07

申请人： Rina Carlini ,  C. Geoffrey Allen ,  Sandra J. Gardner ,  Karl W. Dawson ,  Peter G. Odell ,  Paul F. Smith ,  Jennifer L. Belelie

发明人： Rina Carlini ,  C. Geoffrey Allen ,  Sandra J. Gardner ,  Karl W. Dawson ,  Peter G. Odell ,  Paul F. Smith ,  Jennifer L. Belelie

IPC分类号： C09B67/20 ,  C09B63/00 ,  C09B41/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09B63/005 ,  B82Y30/00 ,  C09B67/0005 ,  C09B67/0009 ,  C09D7/41 ,  C09D11/037 ,  C09D11/101 ,  C09D11/322 ,  C09D11/34

摘要： A nanoscale pigment particle composition includes an organic monoazo laked pigment including at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, wherein the functional moiety associates non-covalently with the functional group; and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized pigment particles.

摘要翻译： 纳米级颜料颗粒组合物包括包含至少一个官能部分的有机单偶氮染料和包含至少一个官能团的空间庞大稳定剂化合物，其中所述官能部分与所述官能团非共价键合; 并且相关稳定剂的存在限制了颗粒生长和聚集的程度，以提供纳米尺寸的颜料颗粒。

公开(公告)号：US07427323B1

公开(公告)日：2008-09-23

申请号：US11759906

申请日：2007-06-07

申请人： Maria M. Birau ,  Rina Carlini ,  C. Geoffrey Allen ,  Sandra J. Gardner ,  Karl W. Dawson ,  Peter G. Odell ,  Paul F. Smith ,  Caroline M. Turek ,  Roger E. Gaynor ,  Jeffrey H. Banning

发明人： Maria M. Birau ,  Rina Carlini ,  C. Geoffrey Allen ,  Sandra J. Gardner ,  Karl W. Dawson ,  Peter G. Odell ,  Paul F. Smith ,  Caroline M. Turek ,  Roger E. Gaynor ,  Jeffrey H. Banning

IPC分类号： C09B48/00 ,  C09B67/20 ,  C09B67/52 ,  C09D11/00

CPC分类号： C09D11/101 ,  B82Y30/00 ,  C09B67/0005 ,  C09B67/0017 ,  C09B67/0065 ,  C09B67/0096 ,  C09D11/34

摘要： A nanoscale pigment particle composition includes a quinacridone pigment including at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, wherein the functional moiety associates non-covalently with the functional group; and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized particles.

摘要翻译： 纳米级颜料颗粒组合物包括包含至少一个官能部分的喹吖啶酮颜料和包含至少一个官能团的空间庞大稳定剂化合物，其中所述官能部分与所述官能团非共价缔合; 并且相关稳定剂的存在限制了颗粒生长和聚集的程度，以提供纳米尺寸的颗粒。

公开(公告)号：US07449515B2

公开(公告)日：2008-11-11

申请号：US11289883

申请日：2005-11-30

申请人： Jennifer L. Belelie ,  Rina Carlini ,  Eniko Toma

发明人： Jennifer L. Belelie ,  Rina Carlini ,  Eniko Toma

IPC分类号： C08G18/08 ,  C09D11/00

CPC分类号： C08G18/755 ,  C08G18/2865 ,  C08G18/3206 ,  C08G18/6715 ,  C08G18/6735 ,  C09D175/16

摘要： Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising (A) a first isocyanate-derived compound which is the reaction product of a mixture comprising (1) an isocyanate; and (2) a component comprising (a) an alcohol having at least one ethylenic unsaturation; (b) an amine having at least one ethylenic unsaturation; (c) an acid having at least one ethylenic unsaturation; or (d) mixtures thereof, (B) a second isocyanate-derived compound which is the reaction product of (1) a diisocyanate; (2) a monoalcohol having exactly one hydroxyl group and having at least one ethylenic unsaturation; and (3) a polyol having two or more hydroxyl groups, (C) an optional phase change inducing component, said phase change inducing component containing at least one hydroxyl group, said phase change inducing component having a melting point of about 40° C. or higher, and (D) an optional curable viscosity modifying ester, said ink being curable upon exposure to ultraviolet radiation.

摘要翻译： 公开了一种相变油墨，其包含着色剂，引发剂和相变油墨载体，所述载体包含（A）第一异氰酸酯衍生化合物，其为包含（1）异氰酸酯的混合物的反应产物; 和（2）包含（a）具有至少一个烯属不饱和度的醇的组分; （b）具有至少一个烯属不饱和度的胺; （c）具有至少一个烯属不饱和度的酸; 或（d）其混合物，（B）第二异氰酸酯衍生化合物，其为（1）二异氰酸酯的反应产物; （2）具有正好一个羟基并具有至少一个烯属不饱和度的一元醇; 和（3）具有两个或多个羟基的多元醇，（C）任选的相变诱导组分，所述相变诱导组分含有至少一个羟基，所述相变诱导组分的熔点约为40℃。 或更高，和（D）任选的可固化粘度改性酯，所述油墨在暴露于紫外线辐射下是可固化的。

公开(公告)号：US07153349B2

公开(公告)日：2006-12-26

申请号：US11004451

申请日：2004-12-04

申请人： Rina Carlini ,  Eniko Toma ,  Peter G. Odell ,  Jeffrey H. Banning

发明人： Rina Carlini ,  Eniko Toma ,  Peter G. Odell ,  Jeffrey H. Banning

IPC分类号： C09D11/02 ,  G01D11/00

CPC分类号： C09D11/34 ,  C09D11/101

摘要： Phase change inks comprising a phase change ink carrier and one or more curable trans-1,2-cyclohexane bis[urea-urethane] compounds of the formulae wherein R1 and R′1 are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R′2 are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R′3 are hydrogen atoms or alkyl groups, R4 and R′4 are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R′1, R2, R′2, R3, R′3, R4, R′4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.

公开(公告)号：US20060122416A1

公开(公告)日：2006-06-08

申请号：US11004682

申请日：2004-12-04

申请人： Adela Goredema ,  Rina Carlini ,  Marcel Breton ,  Jeffrey Banning ,  Eniko Toma

发明人： Adela Goredema ,  Rina Carlini ,  Marcel Breton ,  Jeffrey Banning ,  Eniko Toma

IPC分类号： C07C275/26

CPC分类号： C09D11/34 ,  C07C275/26

摘要： Disclosed are trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R′1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R2 and R′2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R3 and R′3 each, independently of the other, is a hydrogen atom or an alkyl group, R4 and R′4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.

摘要翻译： 公开了下式的反式1,2-环己烷双（脲 - 氨基甲酸酯）化合物，其中R 1和R 2各自独立地是亚烷基 基团，亚芳基，芳基亚烷基或烷基亚芳基，R 2和R'2各自独立地是烷基，芳基 ，芳基烷基或烷基芳基，R 3和R'3各自独立地是氢原子或烷基，R 1， 4和R'4各自独立地是氢原子，氟原子，烷基或苯基，n是0,1或2的整数， 2,3或4，并且R 5是烷基，芳基，芳基烷基，烷基芳基或除烷基，芳基，芳基烷基或烷基芳基以外的取代基。