摘要:
Boron/nitrogen preceramic polymers are prepared by reacting (a) the product of mass thermolysis of a compound of Formula (1): ##STR1## in which A is a halogen atom and R is a hydrogen atom, a hydrocarbon radical, or an organosilyl or hydrogenoorganosilyl radical, with (b) an amino compound containing at least one --NH.sub.2 group; the resulting polymers are facilely pyrolyzed into boron nitride ceramic materials.
摘要:
Crosslinked random boron/nitrogen preceramic polymers are prepared by reacting (a) admixture of a trihalogenoborane A and a cyclic boron/nitrogen compound B containing recurring structural units of the following general formula (1): ##STR1## in which A is a halogen atom and R is a hydrogen atom, or a hydrocarbyl, organosilyl or hydrogenoorganosilyl radical, with (b) an amino compound C containing at least one --NH.sub.2 group; the resulting polymers are facilely pyrolyzed into boron nitride ceramic materials.
摘要:
Crosslinked boron/nitrogen preceramic polymers are prepared by reacting (a) admixture of a trihalogenoborane A and a compound B containing at least one dihalogenated boron atom, with (b) an amino compound C containing at least one --NH.sub.2 group; the resulting polymers are facilely pyrolyzed into boron nitride ceramic materials.
摘要:
Novel ceramic materials include a boron nitride matrix and an amount of silicon values, such ceramic materials comprising a core volume having an external sheath layer on an outer face surface thereof, with the majority of said silicon values being distributed throughout the external layer.
摘要:
Crosslinked boron/nitrogen preceramic polymers are prepared by reacting (a) admixture of a trihalogenoborane A and a compound B containing at least one dihalogenated boron atom, with (b) an amino compound C containing at least one --NH.sub.2 group; the resulting polymers are facilely pyrolyzed into boron nitride ceramic materials.
摘要:
Novel composite ceramic materials include a boron nitride matrix and an amount of silicon components compatible therewith; such ceramic materials comprise a core volume having an external sheath layer on an outer face surface thereof, with the majority of said silicon values being distributed throughout the external layer.
摘要:
Organometallic boron/nitrogen polymers, precursors of boron nitride, include recurring structural units of the formulae (I) and (II): ##STR1## wherein X is N-R.sup.3, Y is NR.sup.1 R.sup.2 and Z is N-R, in which R, R.sup.1, R.sup.2 and R.sup.3, which may be identical or different, are each a hydrogen atom, an optionally substituted hydrocarbon radical, or an organosilyl or hydrogenoorganosilyl radical and are prepared by reacting (a) at least one cyclic compound (compound A) containing recurring structural units of the formula (1): ##STR2## wherein A is a halogen atom and R is a hydrogen atom, an optionally substituted hydrocarbon radical, or an organosilyl or hydrogenoorganosilyl radical, with (b) at least one compound including at least one boron atom to which two halogen atoms are directly bonded (compound B), and (c) at least one compound containing at least one NH.sub.2 group compound C); the resulting organometallic polymers are facilely pyrolyzed into boron nitride ceramic materials.
摘要:
Organometallic boron/nitrogen polymers, precursors of boron nitride, are prepared by reacting at least one trihalogenoborane with at least one silazane compound containing at least one .tbd.Si--NH--Si.tbd. group, by gradually introducing the silazane compound into the trihalogenoborane, while maintaining the reaction medium at a temperature ranging from -100.degree. to 0.degree. C. and wherein the ratio of the gram equivalents of the .tbd.Si--NH--Si.tbd. groups of the silazane to the number of moles of trihalogenoborane is greater than 1; the resulting organometallic polymers are facilely pyrolyzed into boron nitride ceramic materials.
摘要:
Boron/nitrogen/silicon preceramic polymers are prepared by copolymerizing at least one trihaloborane with at least one disilazane and at least one B-trichloroborazine; the resulting polymers, advantageously in fibrous form, are then facilely crosslinked and pyrolyzed into boron nitride ceramic materials.
摘要:
Highly pure boron nitride ceramic material, devoid of silicon values and having low carbon content, is prepared by pyrolyzing, under an atmosphere of ammonia, the product of the reaction between (i) at least one B-trihalogeno-borazole having the formula: ##STR1## and (ii) at least one primary amine having the formula:H.sub.2 N--Rin which formulae X is a halogen atom and R is an optionally substituted hydrocarbon radical having from 1 to 6 carbon atoms.