公开(公告)号：US11072680B2

公开(公告)日：2021-07-27

申请号：US16105126

申请日：2018-08-20

申请人： Presidium USA, Inc

发明人： James Henry Blumsom ,  Andrew John Tennant ,  James A. Cella ,  David Goldwasser ,  Daniel J. Brunelle ,  Stephen Burks ,  Richard Heggs

IPC分类号： C08G59/62 ,  C08G18/40 ,  C08G18/48 ,  C08G18/46 ,  C08G18/50 ,  C08G18/44 ,  C08G18/42 ,  C08G18/76 ,  C08G64/42 ,  C08G18/32 ,  C08G18/02 ,  C08L75/04

摘要： There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

公开(公告)号：US12060452B2

公开(公告)日：2024-08-13

申请号：US17287156

申请日：2019-10-21

申请人： Presidium USA, Inc

发明人： Andrew John Tennant ,  James Henry Blumsom ,  Gary Jialanella ,  Jason Carter ,  James A. Cella ,  James M. Silva

IPC分类号： C08G59/62 ,  C08G18/02 ,  C08G18/32 ,  C08G18/40 ,  C08G18/42 ,  C08G18/44 ,  C08G18/46 ,  C08G18/48 ,  C08G18/50 ,  C08G18/76 ,  C08G64/42 ,  C08L75/04

CPC分类号： C08G59/62 ,  C08G18/02 ,  C08G18/3206 ,  C08G18/3215 ,  C08G18/3284 ,  C08G18/40 ,  C08G18/4222 ,  C08G18/4244 ,  C08G18/44 ,  C08G18/46 ,  C08G18/4615 ,  C08G18/48 ,  C08G18/4829 ,  C08G18/5021 ,  C08G18/7664 ,  C08G64/42 ,  C08L75/04 ,  C08G2310/00 ,  C08J2375/04

摘要： Disclosed are polyol compositions with a low viscosity that exhibit superior heat resistance, enhanced stability in the presence of water, improved strength, hardness, and molding characteristics relative to known polyurethane materials. Disclosed is a polyol composition comprising: (a) at least one monomeric polyol comprising three or more hydroxyl groups; (b) at least one higher polyol comprising three or more hydroxyl groups; and (c) at least one polyhydroxylated aromatic compound; wherein the at least one higher polyol comprises residues of either or both of the at least one monomeric polyol and the polyhydroxylated aromatic compound linked by one or more carbonate groups, oxygen ether groups, or a combination thereof. Disclosed are methods of preparing the disclosed compositions. Disclosed are articles prepared from the disclosed compositions that exhibit flexural strengths in excess of 10,000 psi and flexural moduli in excess of 400,000 psi, and exhibit outstanding green strength.

公开(公告)号：US11078325B2

公开(公告)日：2021-08-03

申请号：US16105161

申请日：2018-08-20

申请人： Presidium USA, Inc

发明人： James Henry Blumsom ,  Andrew John Tennant ,  James A. Cella ,  David Goldwasser ,  Daniel J. Brunelle ,  Stephen Burks ,  Richard Heggs

IPC分类号： C08G59/62 ,  C08G18/40 ,  C08G18/48 ,  C08G18/46 ,  C08G18/50 ,  C08G18/44 ,  C08G18/42 ,  C08G18/76 ,  C08G64/42 ,  C08G18/32 ,  C08G18/02 ,  C08L75/04

摘要： There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

公开(公告)号：US20240010786A9

公开(公告)日：2024-01-11

申请号：US17287156

申请日：2019-10-21

申请人： Presidium USA, Inc

发明人： Andrew John Tennant ,  James Henry Blumsom ,  Gary Jialanella ,  Jason Carter ,  James A. Cella ,  James M. Silva

IPC分类号： C08G59/62 ,  C08G18/40 ,  C08G18/48 ,  C08G18/46 ,  C08G18/50 ,  C08G18/44 ,  C08G18/42 ,  C08G18/76 ,  C08G64/42 ,  C08G18/32 ,  C08G18/02 ,  C08L75/04

CPC分类号： C08G59/62 ,  C08G18/40 ,  C08G18/4829 ,  C08G18/46 ,  C08G18/5021 ,  C08G18/48 ,  C08G18/44 ,  C08G18/4222 ,  C08G18/4244 ,  C08G18/4615 ,  C08G18/7664 ,  C08G64/42 ,  C08G18/3206 ,  C08G18/3215 ,  C08G18/3284 ,  C08G18/02 ,  C08L75/04 ,  C08J2375/04 ,  C08G2310/00

摘要： Disclosed is a polyol composition comprising: (a) at least one monomeric polyol comprising three or more hydroxyl groups; (b) at least one higher polyol comprising three or more hydroxyl groups; and (c) at least one polyhydroxylated aromatic compound; wherein the at least one higher polyol comprises residues of either or both of the at least one monomeric polyol and the polyhydroxylated aromatic compound linked by one or more carbonate groups, oxygen ether groups, or a combination thereof, and wherein the polyol composition has a viscosity of less than 5000 cps at 150 degrees Fahrenheit. The at least one monomeric polyol and at least one higher polyol may have any structures affording polyol compositions and polyurethane compositions having the requisite physical characteristics in terms of polyol composition viscosity and polyurethane heat resistance, strength and flexural modulus. The polyol compositions are adapted to provide structurally robust, temperature resistant polyurethanes, but are of sufficiently low viscosity to permit the use of currently available pumping and mixing equipment. The resultant polyurethane compositions may exhibit heat distortion temperatures in excess of 110 degrees centigrade, high strength and essentially no loss of material properties in prolonged humidity tests at 70 degrees centigrade, lower peak exotherms, typically less than 250 degrees Fahrenheit during in-mold curing/polymerization. Articles prepared from polyurethanes incorporating such polyol compositions as reactants exhibit flexural strengths in excess of 10,000 psi and flexural moduli in excess of 400,000 psi, and exhibit outstanding green strength.

公开(公告)号：US11066512B2

公开(公告)日：2021-07-20

申请号：US16105148

申请日：2018-08-20

申请人： Presidium USA, Inc

发明人： James Henry Blumsom ,  Andrew John Tennant ,  James A. Cella ,  David Goldwasser ,  Daniel J. Brunelle ,  Stephen Burks ,  Richard Heggs

IPC分类号： C08G59/62 ,  C08G18/40 ,  C08G18/48 ,  C08G18/46 ,  C08G18/50 ,  C08G18/44 ,  C08G18/42 ,  C08G18/76 ,  C08G64/42 ,  C08G18/32 ,  C08G18/02 ,  C08L75/04

摘要： There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

公开(公告)号：US20210363290A1

公开(公告)日：2021-11-25

申请号：US17287156

申请日：2019-10-21

申请人： Presidium USA, Inc

发明人： Andrew John Tennant ,  James Henry Blumsom ,  Gary Jialanella ,  Jason Carter ,  James A. Cella ,  James M. Silva

IPC分类号： C08G59/62 ,  C08G18/40 ,  C08G18/48 ,  C08G18/46 ,  C08G18/50 ,  C08G18/44 ,  C08G18/42 ,  C08G18/76 ,  C08G64/42 ,  C08G18/32 ,  C08G18/02 ,  C08L75/04

摘要： Disclosed is a polyol composition comprising: (a) at least one monomeric polyol comprising three or more hydroxyl groups; (b) at least one higher polyol comprising three or more hydroxyl groups; and (c) at least one polyhydroxylated aromatic compound; wherein the at least one higher polyol comprises residues of either or both of the at least one monomeric polyol and the polyhydroxylated aromatic compound linked by one or more carbonate groups, oxygen ether groups, or a combination thereof, and wherein the polyol composition has a viscosity of less than 5000 cps at 150 degrees Fahrenheit. The at least one monomeric polyol and at least one higher polyol may have any structures affording polyol compositions and polyurethane compositions having the requisite physical characteristics in terms of polyol composition viscosity and polyurethane heat resistance, strength and flexural modulus. The polyol compositions are adapted to provide structurally robust, temperature resistant polyurethanes, but are of sufficiently low viscosity to permit the use of currently available pumping and mixing equipment. The resultant polyurethane compositions may exhibit heat distortion temperatures in excess of 110 degrees centigrade, high strength and essentially no loss of material properties in prolonged humidity tests at 70 degrees centigrade, lower peak exotherms, typically less than 250 degrees Fahrenheit during in-mold curing/polymerization. Articles prepared from polyurethanes incorporating such polyol compositions as reactants exhibit flexural strengths in excess of 10,000 psi and flexural moduli in excess of 400,000 psi, and exhibit outstanding green strength.

公开(公告)号：US20190241699A1

公开(公告)日：2019-08-08

申请号：US16105161

申请日：2018-08-20

申请人： Presidium USA, Inc

发明人： James Henry Blumsom ,  Andrew John Tennant ,  James A. Cella ,  David Goldwasser ,  Daniel J. Brunelle ,  Stephen Burks ,  Richard Heggs

IPC分类号： C08G59/62 ,  C08G18/02 ,  C08G18/40 ,  C08G18/32 ,  C08G64/42 ,  C08G18/76 ,  C08L75/04 ,  C08G18/48 ,  C08G18/50 ,  C08G18/42 ,  C08G18/46 ,  C08G18/44

CPC分类号： C08G59/62 ,  C08G18/02 ,  C08G18/3206 ,  C08G18/3215 ,  C08G18/3284 ,  C08G18/40 ,  C08G18/4222 ,  C08G18/4244 ,  C08G18/44 ,  C08G18/46 ,  C08G18/4615 ,  C08G18/48 ,  C08G18/4829 ,  C08G18/5021 ,  C08G18/7664 ,  C08G64/42 ,  C08G2310/00 ,  C08J2375/04 ,  C08L75/04

摘要： There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

公开(公告)号：US20190055345A1

公开(公告)日：2019-02-21

申请号：US16105106

申请日：2018-08-20

申请人： Presidium USA, Inc

发明人： James Henry Blumsom ,  Andrew John Tennant ,  James A. Cella ,  David Goldwasser ,  Daniel J. Brunelle ,  Stephen Burks ,  Richard Heggs

IPC分类号： C08G59/62 ,  C08G18/44 ,  C08G18/02 ,  C08G18/32 ,  C08G64/42 ,  C08G18/76 ,  C08G18/50 ,  C08G18/42 ,  C08G18/46 ,  C08G18/40 ,  C08G18/48 ,  C08L75/04

摘要： There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

公开(公告)号：US10053533B1

公开(公告)日：2018-08-21

申请号：US15589182

申请日：2017-05-08

申请人： Presidium USA, Inc.

发明人： James Henry Blumsom ,  Andrew John Tennant ,  James A. Cella ,  David Goldwasser ,  Daniel J. Brunelle ,  Stephen Burks ,  Richard Heggs

IPC分类号： C08G59/62 ,  C08G18/42 ,  C08G18/40 ,  C08G18/46 ,  C08G18/48 ,  C08G18/50 ,  C08G18/44 ,  C08L75/04 ,  C08G18/02

CPC分类号： C08G59/62 ,  C08G18/02 ,  C08G18/3206 ,  C08G18/3215 ,  C08G18/3284 ,  C08G18/40 ,  C08G18/4222 ,  C08G18/4244 ,  C08G18/44 ,  C08G18/46 ,  C08G18/4615 ,  C08G18/48 ,  C08G18/4829 ,  C08G18/5021 ,  C08G18/7664 ,  C08G64/42 ,  C08G2310/00 ,  C08J2375/04 ,  C08L75/04

摘要： There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

公开(公告)号：US11072679B2

公开(公告)日：2021-07-27

申请号：US16105106

申请日：2018-08-20

申请人： Presidium USA, Inc

发明人： James Henry Blumsom ,  Andrew John Tennant ,  James A. Cella ,  David Goldwasser ,  Daniel J. Brunelle ,  Stephen Burks ,  Richard Heggs

IPC分类号： C08G59/62 ,  C08G18/40 ,  C08G18/48 ,  C08G18/46 ,  C08G18/50 ,  C08G18/44 ,  C08G18/42 ,  C08G18/76 ,  C08G64/42 ,  C08G18/32 ,  C08G18/02 ,  C08L75/04

摘要： There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.