公开(公告)号：US08679679B2

公开(公告)日：2014-03-25

申请号：US12350631

申请日：2009-01-08

申请人： Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Liya Wang ,  Jun Q. Chin

发明人： Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Liya Wang ,  Jun Q. Chin

IPC分类号： H01M4/134

CPC分类号： H01B1/18 ,  H01B1/16

摘要： A composite material having utility as an anode for lithium ion batteries comprises silicon, a transition metal, a ceramic and an electrically conductive diluent such as carbon. In particular instances, the ceramic is electrically conductive, and may comprise vanadium carbide or tungsten carbide. The transition metal may, in some instances, comprise iron. The material may be fabricated by grinding together a starting mixture of the components, and grinding may be accomplished in a high impact ball milling process, and the grinding step may cause partial alloying of the silicon with the metal and/or carbon. Further disclosed is a method for making the material as well as electrodes which incorporate the material.

摘要翻译： 作为用于锂离子电池的阳极的复合材料包括硅，过渡金属，陶瓷和诸如碳的导电稀释剂。 在特定情况下，陶瓷是导电的，并且可以包括碳化钒或碳化钨。 在一些情况下，过渡金属可以包含铁。 可以通过将组分的起始混合物一起研磨来制造材料，并且可以在高冲击球磨过程中实现研磨，并且研磨步骤可以引起硅与金属和/或碳的部分合金化。 进一步公开了制造该材料的方法以及结合该材料的电极。

公开(公告)号：US20090179181A1

公开(公告)日：2009-07-16

申请号：US12350631

申请日：2009-01-08

申请人： Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Liya Wang ,  Jun Q. Chin

发明人： Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Liya Wang ,  Jun Q. Chin

IPC分类号： H01B1/18 ,  B32B5/16

CPC分类号： H01B1/18 ,  H01B1/16

摘要： A composite material having utility as an anode for lithium ion batteries comprises silicon, a transition metal, a ceramic and an electrically conductive diluent such as carbon. In particular instances, the ceramic is electrically conductive, and may comprise vanadium carbide or tungsten carbide. The transition metal may, in some instances, comprise iron. The material may be fabricated by grinding together a starting mixture of the components, and grinding may be accomplished in a high impact ball milling process, and the grinding step may cause partial alloying of the silicon with the metal and/or carbon. Further disclosed is a method for making the material as well as electrodes which incorporate the material.

摘要翻译： 作为用于锂离子电池的阳极的复合材料包括硅，过渡金属，陶瓷和诸如碳的导电稀释剂。 在特定情况下，陶瓷是导电的，并且可以包括碳化钒或碳化钨。 在一些情况下，过渡金属可以包含铁。 可以通过将组分的起始混合物一起研磨来制造材料，并且可以在高冲击球磨过程中实现研磨，并且研磨步骤可以引起硅与金属和/或碳的部分合金化。 进一步公开了制造该材料的方法以及结合该材料的电极。

公开(公告)号：US08039152B2

公开(公告)日：2011-10-18

申请号：US11695975

申请日：2007-04-03

申请人： Monique Richard ,  Kimber L. Stamm ,  Liya Wang ,  Shih-Chieh Yin ,  Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Brian Glomski

发明人： Monique Richard ,  Kimber L. Stamm ,  Liya Wang ,  Shih-Chieh Yin ,  Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Brian Glomski

IPC分类号： H01M4/62 ,  H01M4/13

CPC分类号： H01M4/136 ,  H01M4/485 ,  H01M4/525 ,  H01M4/58 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/027

摘要： An anode material made from nanoparticles, said anode material including a homogeneous mixture of lithium-alloying nanoparticles with active support matrix nanoparticles, is provided. The active support matrix nanoparticle is a compound that participates in the conversion reaction of the lithium battery. The compound is preferably a transition metal compound, with said compound including a nitride, carbide, oxide or combination thereof. An electrode manufactured from the anode material preferably has a porosity of between 5 and 80% and more preferably has a porosity between 10 and 50%. The anode material nanoparticles preferably have a mean linear dimension of between 2 and 500 nanometers, and more preferably have a mean linear dimension of between 2 and 50 nanometers.

摘要翻译： 提供由纳米颗粒制成的阳极材料，所述阳极材料包括锂合金纳米颗粒与活性载体基质纳米颗粒的均匀混合物。 活性载体基质纳米颗粒是参与锂电池的转化反应的化合物。 化合物优选为过渡金属化合物，所述化合物包括氮化物，碳化物，氧化物或其组合。 由阳极材料制成的电极的孔隙率优选为5〜80％，更优选具有10〜50％的孔隙率。 阳极材料纳米颗粒优选具有2至500纳米的平均线性尺寸，更优选具有2至50纳米的平均线性尺寸。

公开(公告)号：US07722991B2

公开(公告)日：2010-05-25

申请号：US11463394

申请日：2006-08-09

申请人： Pu Zhang ,  Junqing Ma ,  Suresh Mani ,  Monique Richard ,  Shoji Yokoishi ,  Brian Glomski ,  Liya Wang ,  Shih-Chieh Yin ,  Kimber L. Stamm ,  Chris Silkowski ,  John Miller ,  Wen Li

发明人： Pu Zhang ,  Junqing Ma ,  Suresh Mani ,  Monique Richard ,  Shoji Yokoishi ,  Brian Glomski ,  Liya Wang ,  Shih-Chieh Yin ,  Kimber L. Stamm ,  Chris Silkowski ,  John Miller ,  Wen Li

IPC分类号： H01M4/58

CPC分类号： H01M10/052 ,  H01M4/134 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/62 ,  H01M4/621 ,  H01M4/624 ,  H01M2004/021

摘要： An anode material with lithium-alloying particles contained within a porous support matrix is provided. The porous support matrix preferably has a porosity of between 5 and 80% afforded by porosity channels and expansion accommodation pores, and is electrically conductive. More preferably the support matrix has a porosity of between 10 and 50%. The support matrix is made from an organic polymer, an inorganic ceramic or a hybrid mixture of organic polymer and inorganic ceramic. The organic polymer support matrix and can be made from a rod-coil polymer, a hyperbranched polymer, UV cross-linked polymer, heat cross-linked polymer or combination thereof. An inorganic ceramic support matrix can be made from at least one group IV-VI transition metal compound, with the compound being a nitride, carbide, oxide or combination thereof. The lithium-alloying particles are preferably nanoparticles with a mean linear dimension of between 5 and 500 nanometers, and more preferably have a mean linear dimension of between 5 and 50 nanometers.

摘要翻译： 提供了一种具有包含在多孔载体基质内的锂合金颗粒的阳极材料。 多孔载体基质优选具有孔隙率为5至80％，由孔隙率通道和膨胀调节孔提供，并且是导电的。 更优选地，载体基质具有10至50％的孔隙率。 支撑基体由有机聚合物，无机陶瓷或有机聚合物和无机陶瓷的混合混合物制成。 有机聚合物载体基质，可由棒状线圈聚合物，超支化聚合物，UV交联聚合物，热交联聚合物或其组合制成。 无机陶瓷载体基质可以由至少一种IV-VI族过渡金属化合物制成，化合物是氮化物，碳化物，氧化物或其组合。 锂合金化颗粒优选平均直线尺寸在5至500纳米之间的纳米颗粒，更优选具有5至50纳米的平均线性尺寸。

公开(公告)号：US20080248393A1

公开(公告)日：2008-10-09

申请号：US11695975

申请日：2007-04-03

申请人： Monique Richard ,  Kimber L. Stamm ,  Liya Wang ,  Shih-Chieh Yin ,  Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Brian Glomski

发明人： Monique Richard ,  Kimber L. Stamm ,  Liya Wang ,  Shih-Chieh Yin ,  Pu Zhang ,  Suresh Mani ,  Junqing Ma ,  Brian Glomski

IPC分类号： H01M4/40 ,  H01M4/62

CPC分类号： H01M4/136 ,  H01M4/485 ,  H01M4/525 ,  H01M4/58 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/027

摘要： An anode material made from nanoparticles, said anode material including a homogeneous mixture of lithium-alloying nanoparticles with active support matrix nanoparticles, is provided. The active support matrix nanoparticle is a compound that participates in the conversion reaction of the lithium battery. The compound is preferably a transition metal compound, with said compound including a nitride, carbide, oxide or combination thereof.An electrode manufactured from the anode material preferably has a porosity of between 5 and 80% and more preferably has a porosity between 10 and 50%. The anode material nanoparticles preferably have a mean linear dimension of between 2 and 500 nanometers, and more preferably have a mean linear dimension of between 2 and 50 nanometers.

摘要翻译： 提供由纳米颗粒制成的阳极材料，所述阳极材料包括锂合金纳米颗粒与活性载体基质纳米颗粒的均匀混合物。 活性载体基质纳米颗粒是参与锂电池的转化反应的化合物。 化合物优选为过渡金属化合物，所述化合物包括氮化物，碳化物，氧化物或其组合。 由阳极材料制成的电极的孔隙率优选为5〜80％，更优选具有10〜50％的孔隙率。 阳极材料纳米颗粒优选具有2至500纳米的平均线性尺寸，更优选具有2至50纳米的平均线性尺寸。

公开(公告)号：US20080038638A1

公开(公告)日：2008-02-14

申请号：US11463394

申请日：2006-08-09

申请人： Pu Zhang ,  Junqing Ma ,  Suresh Mani ,  Monique Richard ,  Shoji Yokoishi ,  Brian Glomski ,  Liya Wang ,  Shih-Chieh Yin ,  Kimber L. Stamm ,  Chris Silkowski ,  John Miller ,  Wen Li

发明人： Pu Zhang ,  Junqing Ma ,  Suresh Mani ,  Monique Richard ,  Shoji Yokoishi ,  Brian Glomski ,  Liya Wang ,  Shih-Chieh Yin ,  Kimber L. Stamm ,  Chris Silkowski ,  John Miller ,  Wen Li

IPC分类号： H01M4/58 ,  H01M4/62 ,  H01M4/40

CPC分类号： H01M10/052 ,  H01M4/134 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/62 ,  H01M4/621 ,  H01M4/624 ,  H01M2004/021

摘要： An anode material with lithium-alloying particles contained within a porous support matrix is provided. The porous support matrix preferably has a porosity of between 5 and 80% afforded by porosity channels and expansion accommodation pores, and is electrically conductive. More preferably the support matrix has a porosity of between 10 and 50%. The support matrix is made from an organic polymer, an inorganic ceramic or a hybrid mixture of organic polymer and inorganic ceramic The organic polymer support matrix and can be made from a rod-coil polymer, a hyperbranched polymer, UV cross-linked polymer, heat cross-linked polymer or combination thereof. An inorganic ceramic support matrix can be made from at least one group IV-VI transition metal compound, with the compound being a nitride, carbide, oxide or combination thereof. The lithium-alloying particles are preferably nanoparticles with a mean linear dimension of between 5 and 500 nanometers, and more preferably have a mean linear dimension of between 5 and 50 nanometers.

摘要翻译： 提供了一种具有包含在多孔载体基质内的锂合金颗粒的阳极材料。 多孔载体基质优选具有孔隙率为5至80％，由孔隙率通道和膨胀调节孔提供，并且是导电的。 更优选地，载体基质具有10至50％的孔隙率。 支撑基体由有机聚合物，无机陶瓷或有机聚合物和无机陶瓷的混合混合物制成有机聚合物载体基体，可由棒状聚合物，超支化聚合物，紫外线交联聚合物，热 交联聚合物或其组合。 无机陶瓷载体基质可以由至少一种IV-VI族过渡金属化合物制成，化合物是氮化物，碳化物，氧化物或其组合。 锂合金化颗粒优选平均直线尺寸在5至500纳米之间的纳米颗粒，更优选具有5至50纳米的平均线性尺寸。

公开(公告)号：US20060019115A1

公开(公告)日：2006-01-26

申请号：US11133054

申请日：2005-05-19

申请人： Liya Wang ,  Michael Heath ,  John Miller ,  Michael Wixom ,  Suresh Mani

发明人： Liya Wang ,  Michael Heath ,  John Miller ,  Michael Wixom ,  Suresh Mani

IPC分类号： H01M4/86

CPC分类号： B82Y30/00 ,  B22F2998/00 ,  C22C29/067 ,  H01M4/36 ,  H01M4/362 ,  H01M4/58 ,  H01M10/052 ,  Y10T428/12181 ,  C22C1/0491

摘要： A composite material which may be used as an electrode for a battery or other electrochemical device, or as a catalyst, has a matrix which is one or more metal carbide, metal nitride, metal boride, metal silicide or intermetallic compound. A metallic component is dispersed in the matrix. The metallic component comprises a metal and an agent which increases the melting point of the metal. The metallic component may be nanodispersed in the matrix. A specific material comprises a nanodispersion of tin, alloyed with an element which increases its melting point to at least 600° C., disposed in a matrix of a transition metal carbide or nitride. This material has very good utility as an anode material for lithium batteries. Also disclosed are other compositions as well as methods for manufacturing the compositions.

摘要翻译： 可以用作电池或其它电化学装置的电极或作为催化剂的复合材料具有作为一种或多种金属碳化物，金属氮化物，金属硼化物，金属硅化物或金属间化合物的基体。 金属成分分散在基质中。 金属组分包括金属和增加金属熔点的试剂。 金属组分可以纳米分散在基质中。 特定材料包括锡的纳米分散体，其与将其熔点增加至至少600℃的元素合金化，设置在过渡金属碳化物或氮化物的基体中。 该材料作为锂电池的负极材料具有非常好的用途。 还公开了其它组合物以及制备组合物的方法。

公开(公告)号：US20090170002A1

公开(公告)日：2009-07-02

申请号：US11954955

申请日：2007-12-12

申请人： Pu Zhang ,  Suresh Mani ,  Yet-Ming Chiang ,  Shih-Chieh Yin ,  Brian Glomski ,  Young-II Jang ,  Christopher Silkowski ,  Michael R. Wixom

发明人： Pu Zhang ,  Suresh Mani ,  Yet-Ming Chiang ,  Shih-Chieh Yin ,  Brian Glomski ,  Young-II Jang ,  Christopher Silkowski ,  Michael R. Wixom

IPC分类号： H01M4/58 ,  C01G23/00

CPC分类号： C01G23/005 ,  B82Y30/00 ,  C01G25/00 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/40 ,  H01M4/02 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M2004/021

摘要： Disclosed is a lithium titanate material, which may include an additive, and its use as an electrode in a battery. Specifically disclosed is a lithium titanate based material, with primary particle size larger than 100 nm, having very good high rate charge and discharge capabilities when incorporated into a lithium battery.

摘要翻译： 公开了一种钛酸锂材料，其可以包括添加剂，以及其作为电池中的电极的用途。 具体公开的是一次粒径大于100nm的钛酸锂基材料，当并入锂电池时具有非常好的高速充放电能力。

公开(公告)号：US08076030B2

公开(公告)日：2011-12-13

申请号：US11954955

申请日：2007-12-12

申请人： Pu Zhang ,  Suresh Mani ,  Yet-Ming Chiang ,  Shih-Chieh Yin ,  Brian Glomski ,  Young-Il Jang ,  Christopher Silkowski ,  Michael R. Wixom

发明人： Pu Zhang ,  Suresh Mani ,  Yet-Ming Chiang ,  Shih-Chieh Yin ,  Brian Glomski ,  Young-Il Jang ,  Christopher Silkowski ,  Michael R. Wixom

IPC分类号： H01M4/58 ,  C01G23/00

CPC分类号： C01G23/005 ,  B82Y30/00 ,  C01G25/00 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/40 ,  H01M4/02 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M2004/021

摘要： Disclosed is a lithium titanate material, which may include an additive, and its use as an electrode in a battery. Specifically disclosed is a lithium titanate based material, with primary particle size larger than 100 nm, having very good high rate charge and discharge capabilities when incorporated into a lithium battery.

摘要翻译： 公开了一种钛酸锂材料，其可以包括添加剂，以及其作为电池中的电极的用途。 具体公开的是一次粒径大于100nm的钛酸锂基材料，当并入锂电池时具有非常好的高速充放电能力。

公开(公告)号：US20070281211A1

公开(公告)日：2007-12-06

申请号：US11757658

申请日：2007-06-04

申请人： Pu Zhang ,  Suresh Mani ,  Michael R. Wixom

发明人： Pu Zhang ,  Suresh Mani ,  Michael R. Wixom

IPC分类号： H01M4/48 ,  C01G23/04

CPC分类号： C01G23/005 ,  C01G25/00 ,  C01P2002/52 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525

摘要： Disclosed is a doped lithium titanate and its use as an electrode in a battery. Further disclosed is a method for making an alkali metal titanate, which method includes mixing an alkali metal compound and a titanium compound, impact milling the mixture, and heating the milled mixture for a time, and at a temperature, sufficient to convert the mixture to the alkali metal titanate. The alkali metal compound can be in the form of Li2CO3 and the titanium compound can be in the form of TiO2. A dopant may be included in the mixture.

摘要翻译： 公开了掺杂的钛酸锂及其作为电池中的电极的用途。 进一步公开了制造碱金属钛酸盐的方法，该方法包括将碱金属化合物和钛化合物混合，将混合物进行冲击研磨，并将研磨的混合物加热一段时间，并在足以将混合物转化为 碱金属钛酸盐。 碱金属化合物可以是Li 2 CO 3 3的形式，钛化合物可以是TiO 2的形式。 可以在混合物中包含掺杂剂。