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公开(公告)号:US08512879B2
公开(公告)日:2013-08-20
申请号:US12615748
申请日:2009-11-10
申请人: Qing Ye , Jie Lu , Kelly Scott Chichak
发明人: Qing Ye , Jie Lu , Kelly Scott Chichak
CPC分类号: H01L51/0035 , C08G61/12 , C08G73/026 , C08G2261/1424 , C08G2261/148 , C08G2261/149 , C08G2261/1526 , C08G2261/3142 , C08G2261/3162 , C08G2261/411 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , C09K2211/1433 , C09K2211/1466 , C09K2211/185 , H01L51/5012 , H05B33/14
摘要: A polymer useful in an optoelectronic device comprises structural unit of formula I: wherein R1 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; Ar1 is aryl or heteroaryl; Ar2 is fluorene; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R3, R4 and R5 are independently hydrogen, alkyl, alkoxy, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2 phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3 methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.
摘要翻译: 可用于光电子器件的聚合物包括式I的结构单元:其中R 1在每次出现时独立地为C 1 -C 20脂族基团,C 3 -C 20芳族基团或C 3 -C 20脂环族基团; a在每次出现时独立地为0-4的整数; Ar 1是芳基或杂芳基; Ar2是芴; R2是亚烷基,取代的亚烷基,氧杂亚烷基,CO或CO 2; R3,R4和R5独立地是氢,烷基,烷氧基,烷基芳基,芳基,芳基烷基,杂芳基,取代的烷基; 取代的烷氧基,取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的杂芳基; 苯基吡啶,苯并异喹啉,二苯并喹啉,芴基吡啶,酮吡咯,2-(1-萘基)苯并恶唑,2-苯基苯并恶唑,苯基苯并噻唑,香豆素,噻吩并吡啶,苯基吡啶,苯并噻吩基吡啶,3-甲氧基-2-苯基吡啶, 噻吩基吡啶,苯基亚胺,乙烯基吡啶,吡啶基萘,吡啶基吡咯,吡啶基咪唑,苯基吲哚,其衍生物或其组合。
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公开(公告)号:US20110108807A1
公开(公告)日:2011-05-12
申请号:US12615748
申请日:2009-11-10
申请人: Qing Ye , Jie Lu , Kelly Scott Chichak
发明人: Qing Ye , Jie Lu , Kelly Scott Chichak
CPC分类号: H01L51/0035 , C08G61/12 , C08G73/026 , C08G2261/1424 , C08G2261/148 , C08G2261/149 , C08G2261/1526 , C08G2261/3142 , C08G2261/3162 , C08G2261/411 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , C09K2211/1433 , C09K2211/1466 , C09K2211/185 , H01L51/5012 , H05B33/14
摘要: A polymer useful in an optoelectronic device comprises structural unit of formula I: wherein R1 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; Ar1 is aryl or heteroaryl; Ar2 is fluorene; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R3, R4 and R5 are independently hydrogen, alkyl, alkoxy, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2 phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3 methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.
摘要翻译: 可用于光电子器件的聚合物包括式I的结构单元:其中R 1在每次出现时独立地为C 1 -C 20脂族基团,C 3 -C 20芳族基团或C 3 -C 20脂环族基团; a在每次出现时独立地为0-4的整数; Ar 1是芳基或杂芳基; Ar2是芴; R2是亚烷基,取代的亚烷基,氧杂亚烷基,CO或CO 2; R3,R4和R5独立地是氢,烷基,烷氧基,烷基芳基,芳基,芳基烷基,杂芳基,取代的烷基; 取代的烷氧基,取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的杂芳基; 苯基吡啶,苯并异喹啉,二苯并喹啉,芴基吡啶,酮吡咯,2-(1-萘基)苯并恶唑,2-苯基苯并恶唑,苯基苯并噻唑,香豆素,噻吩并吡啶,苯基吡啶,苯并噻吩基吡啶,3-甲氧基-2-苯基吡啶, 噻吩基吡啶,苯基亚胺,乙烯基吡啶,吡啶基萘,吡啶基吡咯,吡啶基咪唑,苯基吲哚,其衍生物或其组合。
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公开(公告)号:US20110155955A1
公开(公告)日:2011-06-30
申请号:US13060855
申请日:2009-08-19
申请人: Qing Ye , Jie Liu , Kelly Scott Chichak , Yanggang Liang
发明人: Qing Ye , Jie Liu , Kelly Scott Chichak , Yanggang Liang
IPC分类号: C07D401/10 , C09K11/06
CPC分类号: C09K11/06 , C07D213/53 , C09K2211/1007 , C09K2211/1029 , H01L51/0067 , H01L51/5048 , H05B33/14 , Y10S428/917
摘要: Compounds of formula I may be used in optoelectronic devices wherein R1, R2 and R4 are, independently at each occurrence, H, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R3 is H or a is, independently at each occurrence, 1 or 2; b is, independently at each occurrence, an integer ranging from 0-3; c is, independently at each occurrence, an integer ranging from 0-4; Ar is independently at each occurrence, H, or heteroaryl; and at least two of Ar are heteroaryl.
摘要翻译: 式I化合物可用于光电子器件,其中R 1,R 2和R 4在每次出现时独立地为H,C 1 -C 20脂族基,C 3 -C 20芳族基或C 3 -C 20环脂族基; R3是H或a是在每次出现时独立地为1或2; b在每次出现时独立地为0-3的整数; c在每次出现时独立地为0-4的整数; Ar在每次出现时独立地为H或杂芳基; 并且Ar中的至少两个是杂芳基。
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公开(公告)号:US07718087B2
公开(公告)日:2010-05-18
申请号:US11504552
申请日:2006-08-14
CPC分类号: C09K11/06 , C08L65/00 , C09K2211/1007 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0039 , H01L51/0043 , H01L51/0085 , H01L51/5012 , H01L51/5016 , H01L51/5048 , H01L51/5088 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要: The present invention provides compositions comprising at least one novel polymeric organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions of the present invention are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译: 本发明提供包含至少一种包含至少一种环金属配体和至少一种酮吡咯配体的新型聚合有机铱化合物的组合物。 本发明的聚合有机铱组合物称为(2)型有机铱组合物,其构成为使得新型有机铱化合物的至少一种配位体的数均分子量为2000克/摩尔或更高(如 通过凝胶渗透色谱法测定)。 类型(2)有机铱组合物在本文中被称为包含“聚合有机铱络合物”。 新型有机铱组合物可用于诸如OLED器件和光电器件的光电子器件。 一方面,本发明提供了用于制备具有增强的颜色特性和光输出效率的OLED器件的新型有机铱组合物。
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公开(公告)号:US20090289224A1
公开(公告)日:2009-11-26
申请号:US12125296
申请日:2008-05-22
申请人: Yangang Liang , Shengxia Liu , Kelly Scott Chichak , Qing Ye , Jie Liu
发明人: Yangang Liang , Shengxia Liu , Kelly Scott Chichak , Qing Ye , Jie Liu
IPC分类号: C09K11/06 , C07D401/10 , C07D401/14 , C07D405/14 , C07D213/02
CPC分类号: C07D405/10 , C07D213/06 , C07D213/127 , C07D213/30 , C07D213/643 , C07D401/10 , Y10S428/917
摘要: Organic compounds of formula I may be used in optoelectronic devices wherein R1 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R2 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; b is, independently at each occurrence, an integer ranging from 0-3; Ar1 is a direct bond or heteroaryl, aryl, or alkyl or cycloalkyl; Ar2 is heteroaryl, aryl, or alkyl or cycloalkyl; c is 0, 1 or 2; and n is an integer ranging from 2-4.
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公开(公告)号:US08691399B2
公开(公告)日:2014-04-08
申请号:US12350594
申请日:2009-01-08
申请人: Kelly Scott Chichak , Qing Ye
发明人: Kelly Scott Chichak , Qing Ye
IPC分类号: H01L51/54 , C09K11/06 , C07D213/06
CPC分类号: C07D401/14
摘要: Compounds of formula I may be used in optoelectronic devices wherein R1 and R2 are, independently at each occurrence, H, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a is an integer ranging from 0-2; b is 1 or 2; c is an integer ranging from 0-4; and Ar1 and Ar2 are independently heteroaryl.
摘要翻译: 式I化合物可以用于其中R 1和R 2在每次出现时独立地为H,C 1 -C 20脂族基团,C 3 -C 20芳族基团或C 3 -C 20脂环族基团的光电子器件; a是0-2的整数; b为1或2; c是0-4的整数; Ar 1和Ar 2独立地是杂芳基。
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公开(公告)号:US20100174086A1
公开(公告)日:2010-07-08
申请号:US12350629
申请日:2009-01-08
申请人: Kelly Scott Chichak , Qing Ye , Yangang Liang , Shengxia Liu , Rui Wang
发明人: Kelly Scott Chichak , Qing Ye , Yangang Liang , Shengxia Liu , Rui Wang
IPC分类号: C07D401/14
CPC分类号: C07D213/16 , C07D213/53
摘要: Compound of formula C is made by reacting a compound of formula A with an pyridyl boronic acid or pyridyl borate ester to form a compound of formula B; and combining the compound of formula B with a pyridyl dihalide to form the compound of C; wherein R3, R4, R5, R6 and R7 are, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; X is, independently at each occurrence, CH or N; Y is chloro or bromo; Z is bromo or iodo; and when Y is bromo, Z is iodo; d, e, and g are, independently at each occurrence, an integer ranging from 0-4; f is an integer ranging from 0-2; and h is an integer ranging from 0-3.
摘要翻译: 式C化合物通过使式A的化合物与吡啶基硼酸或吡啶基硼酸酯反应形成式B的化合物而制备; 并将式B化合物与吡啶基二卤化物结合形成C的化合物; 其中R 3,R 4,R 5,R 6和R 7在每次出现时独立地为C 1 -C 20脂族基团,C 3 -C 20芳族基团或C 3 -C 20脂环族基团; 每次出现时,X独立地为CH或N; Y是氯或溴; Z是溴或碘; 当Y为溴时,Z为碘; d,e和g各自独立地为0-4的整数; f是0-2的整数; h为0-3的整数。
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公开(公告)号:US20100090586A1
公开(公告)日:2010-04-15
申请号:US11504870
申请日:2006-08-16
IPC分类号: H01J1/62
CPC分类号: H01L51/0085 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/5016 , Y02E10/549 , Y10S428/917
摘要: The present invention provides electronic devices comprising novel polymeric organic iridium compositions which provide for enhanced device performance. The polymeric organic iridium compositions employed comprise a polymeric organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions employed are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the polymeric organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译: 本发明提供了包含新型聚合物有机铱组合物的电子器件,其提供增强的器件性能。 所用的聚合有机铱组合物包括含有至少一个环金属配体和至少一个酮基吡咯配体的聚合有机铱化合物。 所使用的聚合有机铱组合物称为类型(2)有机铱组合物,并且构成为使得聚合有机铱化合物的至少一种配体的数均分子量为每摩尔或更大2000克(通过凝胶测量) 渗透色谱)。 类型(2)有机铱组合物在本文中被称为包含“聚合有机铱络合物”。 在一个方面,本发明提供了诸如OLED器件和光伏器件之类的光电器件。 在另一方面,本发明提供具有增强的颜色特性和光输出效率的OLED器件。
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公开(公告)号:US07691494B2
公开(公告)日:2010-04-06
申请号:US11506002
申请日:2006-08-17
申请人: Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
发明人: Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
CPC分类号: H01L51/0085 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/1466 , C09K2211/1475 , C09K2211/185 , H01L51/0035 , H01L51/0039 , H01L51/0043 , H01L51/5016 , H01L51/5048 , H01L51/5088 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要: The present invention provides electronic devices comprising novel organic iridium compositions which provide for enhanced device performance. The novel iridium compositions employed comprise at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions employed are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译: 本发明提供了包含新型有机铱组合物的电子器件,其提供增强的器件性能。 所用的新型铱组合物包含至少一种包含至少一种环金属配体和至少一种酮基吡咯配体的新型有机铱化合物。 使用的有机铱组合物称为类型(1)有机铱组合物,并且构成为使得新型有机铱化合物的配体的数均分子量为每摩尔或更大2000克(通过凝胶渗透色谱法测量) 。 类型(1)有机铱组合物在本文中被称为包含“有机铱络合物”。 在一个方面,本发明提供了诸如OLED器件和光伏器件之类的光电器件。 在另一方面,本发明提供具有增强的颜色特性和光输出效率的OLED器件。
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10.
公开(公告)号:US07691292B2
公开(公告)日:2010-04-06
申请号:US11504871
申请日:2006-08-16
CPC分类号: C07F15/0033 , H01L51/0035 , H01L51/0043 , H01L51/0061 , H01L51/0085 , H01L51/5012 , Y02E10/549 , Y10S428/917
摘要: The present invention provides compositions comprising at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions of the present invention are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译: 本发明提供包含至少一种包含至少一种环金属配体和至少一种酮吡咯配体的新型有机铱化合物的组合物。 本发明的有机铱组合物被称为类型(1)有机铱组合物,并且构成为使得新的有机铱化合物的配体的数均分子量为每摩尔或更大2000克(通过凝胶测量) 渗透色谱)。 类型(1)有机铱组合物在本文中被称为包含“有机铱络合物”。 新型有机铱组合物可用于诸如OLED器件和光电器件的光电子器件。 一方面,本发明提供了用于制备具有增强的颜色特性和光输出效率的OLED器件的新型有机铱组合物。
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