公开(公告)号：US07785461B2

公开(公告)日：2010-08-31

申请号：US11099476

申请日：2005-04-06

申请人： Rafael Menegassi De Almeida ,  Jefferson Roberto Gomes ,  Marcelo Edral Pacheco ,  Marcus Vinicius Eiffle Duarte ,  Rogerio Oddone ,  Giane Ribeiro Stuart

发明人： Rafael Menegassi De Almeida ,  Jefferson Roberto Gomes ,  Marcelo Edral Pacheco ,  Marcus Vinicius Eiffle Duarte ,  Rogerio Oddone ,  Giane Ribeiro Stuart

IPC分类号： C10G65/04

CPC分类号： C10G45/02 ,  C10G2400/02

摘要： A process for the selective hydrodesulfurization of a naphtha containing olefins and organosulfur compounds is disclosed, which minimizes the hydrogenation of the olefins and results in a product with a low sulfur content. The process involves a two-stage hydrodesulfurization with H2S removed from the first stage effluent. A flow of hydrogen and at least one added non-reactive compound is fed into the first stage, wherein the H2 molar fraction ranges from 0.2 to 1.0, and with H2S at the reactor intake limited to a maximum of 0.1% by volume. The second stage involves a feedstream of hydrogen and at least one added non-reactive compound, wherein the H2 molar fraction ranges from 0.2 to 0.7 and with H2S at the reactor intake limited to a maximum of 0.05% by volume.

摘要翻译： 公开了含有烯烃和有机硫化合物的石脑油的选择性加氢脱硫的方法，其使烯烃的氢化最小化并导致具有低硫含量的产物。 该方法涉及从第一阶段流出物中除去H 2 S的两步加氢脱硫。 将氢气流和至少一种添加的非反应性化合物流进入第一阶段，其中H 2摩尔分数为0.2-1.0，反应器进料中的H 2 S限制为最大0.1体积％。 第二阶段涉及氢气和至少一种添加的非反应性化合物的进料流，其中H 2摩尔分数为0.2-0.7，反应器进料中的H 2 S为最大0.05体积％。

公开(公告)号：US08366910B2

公开(公告)日：2013-02-05

申请号：US12298071

申请日：2007-04-26

申请人： Jefferson Roberto Gomes ,  Raissa Maria Cotta Ferreira da Silva ,  Rogerio Oddone ,  Adriana de Souza Ferreira ,  Nelmo Furtado Fernandes

发明人： Jefferson Roberto Gomes ,  Raissa Maria Cotta Ferreira da Silva ,  Rogerio Oddone ,  Adriana de Souza Ferreira ,  Nelmo Furtado Fernandes

IPC分类号： C10G65/12 ,  C10G45/58

CPC分类号： C10G3/46 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1037 ,  C10G2300/307 ,  C10G2300/308 ,  C10G2300/4018 ,  C10G2400/04 ,  Y02P30/20

摘要： A process is described for hydroconversion of a mixture of organic oils of different origins in a conventional hydrotreatment unit, constituted by at least two catalyst beds, under moderately severe process conditions to obtain diesel fuel oil. The process includes injection of a stream of oil of animal or plant origin, with independently adjusted flow rates, from the second catalyst bed of the hydrotreatment unit onwards, in accordance with the variations in temperature observed in each of the catalyst beds after the first bed. The process is applicable to conventional hydrotreatment units, and makes it possible to overcome the effects of the highly exothermic nature of hydroconversion reactions in oils of animal and/or plant origin in hydrotreatment process for obtaining specified diesel fuel oil.

摘要翻译： 描述了用于在中等严苛工艺条件下由至少两个催化剂床构成的常规加氢处理单元中将不同来源的有机油混合物加氢转化以获得柴油燃料油的方法。 该方法包括根据在第一床之后的每个催化剂床中观察到的温度变化向前注入来自加氢处理单元的第二催化剂床的具有独立调节的流速的动物或植物来源的油流 。 该方法适用于常规加氢处理装置，并且可以克服在加氢处理过程中用于获得特定柴油的动物和/或植物来源的加氢转化反应的高度放热性质的影响。

公开(公告)号：US20090301932A1

公开(公告)日：2009-12-10

申请号：US12298071

申请日：2007-04-26

申请人： Jefferson Roberto Gomes ,  Raissa Maria Cotta Ferreira da Silva ,  Rogerio Oddone ,  Adriana De Souza Ferreira ,  Nelmo Furtado Fernandes

发明人： Jefferson Roberto Gomes ,  Raissa Maria Cotta Ferreira da Silva ,  Rogerio Oddone ,  Adriana De Souza Ferreira ,  Nelmo Furtado Fernandes

IPC分类号： C10G69/02

CPC分类号： C10G3/46 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1037 ,  C10G2300/307 ,  C10G2300/308 ,  C10G2300/4018 ,  C10G2400/04 ,  Y02P30/20

摘要： A process is described for hydroconversion of a mixture of organic oils of different origins in a conventional hydrotreatment unit, constituted by at least two catalyst beds, under moderately severe process conditions to obtain diesel fuel oil. The process includes injection of a stream of oil of animal or plant origin, with independently adjusted flow rates, from the second catalyst bed of the hydrotreatment unit onwards, in accordance with the variations in temperature observed in each of the catalyst beds after the first bed. The process is applicable to conventional hydrotreatment units, and makes it possible to overcome the effects of the highly exothermic nature of hydroconversion reactions in oils of animal and/or plant origin in hydrotreatment process for obtaining specified diesel fuel oil.

摘要翻译： 描述了用于在中等严苛工艺条件下由至少两个催化剂床构成的常规加氢处理单元中将不同来源的有机油混合物加氢转化以获得柴油燃料油的方法。 该方法包括根据在第一床之后的每个催化剂床中观察到的温度变化向前注入来自加氢处理单元的第二催化剂床的具有独立调节的流速的动物或植物来源的油流 。 该方法适用于常规加氢处理装置，并且可以克服在加氢处理过程中用于获得特定柴油的动物和/或植物来源的加氢转化反应的高度放热性质的影响。

公开(公告)号：US20060096893A1

公开(公告)日：2006-05-11

申请号：US11099476

申请日：2005-04-06

申请人： Rafael De Almeida ,  Jefferson Gomes ,  Marcelo Pacheco ,  Marcus Duarte ,  Rogerio Oddone ,  Giane Stuart

发明人： Rafael De Almeida ,  Jefferson Gomes ,  Marcelo Pacheco ,  Marcus Duarte ,  Rogerio Oddone ,  Giane Stuart

IPC分类号： C10G65/04

CPC分类号： C10G45/02 ,  C10G2400/02

摘要： A process for the selective hydrodesulfurization of a naphtha containing olefins and organosulfur compounds is disclosed, which minimizes the hydrogenation of the olefins and results in a product with a low sulfur content. The process involves a two-stage hydrodesulfurization with H2S removed from the first stage effluent. A flow of hydrogen and at least one added non-reactive compound is fed into the first stage, wherein the H2 molar fraction ranges from 0.2 to 1.0, and with H2S at the reactor intake limited to a maximum of 0.1% by volume. The second stage involves a feedstream of hydrogen and at least one added non-reactive compound, wherein the H2 molar fraction ranges from 0.2 to 0.7 and with H2S at the reactor intake limited to a maximum of 0.05% by volume.

摘要翻译： 公开了含有烯烃和有机硫化合物的石脑油的选择性加氢脱硫的方法，其使烯烃的氢化最小化并导致具有低硫含量的产物。 该方法涉及从第一级流出物中除去H 2 S 2 S的两级加氢脱硫。 将氢气流和至少一种添加的非反应性化合物进料到第一阶段，其中H 2 H 2摩尔分数为0.2至1.0，H 2 反应器进料的S限制在最大为0.1％（体积）。 第二阶段包括氢气和至少一种添加的非反应性化合物的进料流，其中H 2 N 2摩尔分数在0.2至0.7和H 2 S 2的范围内 反应器进料量最多限制在0.05％（体积）。