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公开(公告)号:US6068823A
公开(公告)日:2000-05-30
申请号:US231751
申请日:1999-01-15
申请人: Ramiro Sanchez , Graciela Lubertino
发明人: Ramiro Sanchez , Graciela Lubertino
IPC分类号: B01D53/04 , C07C243/00 , C07C243/02 , C07F3/00 , B01D53/56 , C07C243/04
CPC分类号: B01D53/02 , C07C243/00 , C07C243/02 , C07F3/003 , B01D2253/102 , B01D2253/106 , B01D2257/404
摘要: A direct fixation of NO.sub.2 and N.sub.2 O.sub.4 at room temperature and atmospheric pressure is described using bis(diorganoamino)magnesium compounds formed from reactions between donor-solvent free diorganomagnesium compounds and primary or secondary amines, yielding new compositions of matter having the general formulas [(R.sub.2 N).sub.i (R.sub.2 NN.sub.x O.sub.y)jMg].sub.m and [(R.sub.2 N).sub.i (R.sub.2 NN.sub.x O.sub.y).sub.j (N.sub.x O.sub.y).sub.k Mg].sub.m. Methods are also described to convert these new compositions of matter into useful organic compounds and nitrogen gas.
摘要翻译: 使用由供体无溶剂二有机镁化合物与伯胺或仲胺之间的反应形成的双(二有机基氨基)镁化合物来描述在室温和大气压下直接固定NO 2和N 2 O 4,产生具有通式[(R 2 N )i(R2NNxOy)jMg] m和[(R2N)i(R2NNxOy)j(NxOy)kMg] m。 还描述了将这些新的物质组合物转化为有用的有机化合物和氮气的方法。