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    Energetic azidomethyl-substituted 1,3-dioxolanes
    1.
    发明授权
    Energetic azidomethyl-substituted 1,3-dioxolanes 失效
    能量叠氮甲基取代的1,3-二氧戊环

    公开(公告)号：US5243057A

    公开(公告)日：1993-09-07

    申请号：US320144

    申请日：1989-03-07

    申请人： Edward E. Hamel ,  Renato R. Rindone ,  Der-Shing Huang

    发明人： Edward E. Hamel ,  Renato R. Rindone ,  Der-Shing Huang

    IPC分类号： C07D317/28

    CPC分类号： C07D317/28 ,  Y02P20/582

    摘要： Methylazide-substituted 1,3-dioxolanes of the generic formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently selected from H, C.sub.1 -C.sub.6 alkyl and CH.sub.2 N.sub.3 are disclosed as energetic plasticizers for rocket and gun propellants and explosives formulations. Methods of preparation of these compounds are also disclosed, in which halogen-substituted vicinal diols are reacted with aldehydes or ketones to form the halo-analog of the product, which is then converted to the product by reaction with a metal azide.

    摘要翻译： 其中R1，R2，R3，R4，R5和R6独立地选自H，C1-C6烷基和CH2N3的通式为“IMAGE”的甲基偶氮取代的1,3-二氧戊环被公开为用于火箭和枪推进剂的能量增塑剂 和爆炸物配方。 还公开了这些化合物的制备方法，其中将卤素取代的连位二醇与醛或酮反应以形成产物的卤代 - 类似物，然后通过与金属叠氮化物反应将其转化成产物。

    Energetic azidomethyl-substituted 1,3-dioxolanes
    2.
    发明授权
    Energetic azidomethyl-substituted 1,3-dioxolanes 失效
    能量叠氮甲基取代的1,3-二氧戊环

    公开(公告)号：US5698718A

    公开(公告)日：1997-12-16

    申请号：US460444

    申请日：1990-01-03

    申请人： Edward E. Hamel ,  Renato R. Rindone ,  Der-shing Huang

    发明人： Edward E. Hamel ,  Renato R. Rindone ,  Der-shing Huang

    IPC分类号： C07D317/28

    CPC分类号： C07D317/28 ,  Y02P20/582

    摘要： Methylazide-substituted 1,3-dioxolanes of the generic formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently selected from H, C.sub.1 -C.sub.6 alkyl and CH.sub.2 N.sub.3 are disclosed as energetic plasticizers for rocket and gun propellants and explosives formulations. Methods of preparation of these compounds are also disclosed, in which halogen-substituted vicinal diols are reacted with aldehydes or ketones to form the halo-analog of the product, which is then converted to the product by reaction with a metal azide.

    摘要翻译： 其中R1，R2，R3，R4，R5和R6独立地选自H，C1-C6烷基和CH2N3的通式为“IMAGE”的甲基偶氮取代的1,3-二氧戊环被公开为用于火箭和枪推进剂的能量增塑剂 和爆炸物配方。 还公开了这些化合物的制备方法，其中将卤素取代的连位二醇与醛或酮反应以形成产物的卤代 - 类似物，然后通过与金属叠氮化物反应将其转化成产物。