公开(公告)号：US20060040068A1

公开(公告)日：2006-02-23

申请号：US10533059

申请日：2003-10-07

申请人： Rene Wegh ,  Johan Lub

发明人： Rene Wegh ,  Johan Lub

IPC分类号： C09K19/00

CPC分类号： C09K19/3857 ,  G02B5/3016 ,  G02F1/133536 ,  G02F2001/133543 ,  Y10T428/1005

摘要： The invention pertains to a method of manufacturing a layer of a cholesterically ordered polymer material, in which the material is oriented in such a way that the axis of the molecular helix of the cholesterically ordered material extends transversely to the layer, wherein the method comprises the steps: a) providing a layer comprising a cholesterically ordered mixture of a low-molecular weight polymerizable material and a high-molecular weight material, which high-molecular weight material comprises a quantity of a convertible group, which in its non-converted and in its converted state determines the pitch or the material to a different extent, the conversion of said high-molecular weight material being inducible by radiation, and the layer absorbs said radiation; b) irradiating the layer to convert at least a part of the convertible groups it the irradiated parts of the layer; c) letting at least the low-molecular weight material reorient to form the required helical structure; d) at least partially polymerizing and/or cross-linking the low-molecular weight material with itself and/or with the high-molecular weight material to freeze in the formed structure.

摘要翻译： 本发明涉及一种制造胆甾醇有序聚合物材料层的方法，其中材料以这样一种方式取向，使得胆甾醇排序材料的分子螺旋轴线横向于该层延伸，其中该方法包括 步骤：a）提供包含低分子量可聚合材料和高分子量材料的胆甾醇排序混合物的层，该高分子量材料包含一定量的可转化基团，其在其未转化和 其转化状态决定了沥青或材料的不同程度，所述高分子量材料的转化可通过辐射诱导，并且该层吸收所述辐射; b）照射该层以将其所辐照的部分的至少一部分可转换基团转化; c）使至少低分子量材料重新取向以形成所需的螺旋结构; d）至少部分地将低分子量材料与其自身和/或与高分子量材料聚合和/或交联以在形成的结构中冷冻。

公开(公告)号：US20060022167A1

公开(公告)日：2006-02-02

申请号：US10519604

申请日：2003-06-13

申请人： Johan Lub ,  Rene Wegh

发明人： Johan Lub ,  Rene Wegh

IPC分类号： C09K19/36 ,  C09K19/52 ,  C09K19/20 ,  C07C69/76

CPC分类号： C07D493/04 ,  C07C69/92 ,  C09K19/586 ,  Y10T428/10 ,  Y10T428/1036

摘要： The invention pertains to a phenylethanediol derivative having at least one polymerizable group, characterized in that the phenylethanediol derivative further comprises at least one photo-convertible group for adjusting the helical twisting power of the phenylethanediol derivative. According to a preferred embodiment the phenylethanediol has the formula wherein A stands for a bond or a p-phenylene group; B and B′ are independently (O)p—CoH2o—O—CO—CR′═CH2, o being 2-12, p being 0 or 1, and R′ being H or CH3; P stands for a CH2 or a C═O group; Q and Q′ are independently selected from H, C1-C3 alkyl, C1-C3 alkoxy, halogen, and CN; n is an integer from 1 to 3; and m is an integer from 0 to 2; and: wherein A stands for a bond or a p-phenylene group; B is (O)p—CoH2o—O—CO—CR′═CH2, o being 2-12, p is 1, and R′ being H or CH3; P stands for a CH2 or a C═O group; Q is selected from H, C1-C3 alkyl, C1-C3 alkoxy, halogen, and CN; and m is an integer from 0 to 2.

摘要翻译： 本发明涉及具有至少一个可聚合基团的苯乙二醇衍生物，其特征在于所述苯乙二醇衍生物还包含至少一个用于调节苯乙二醇衍生物的螺旋扭转能力的光转化基团。 根据优选的实施方案，苯乙二醇具有下式：其中A代表键或对亚苯基; B和B'独立地是（O）-O-CO-CR'-CH 2，-O-CO-CR'-CH 2， / SUB，o为2-12，p为0或1，R'为H或CH 3。 P代表CH 2或C-O基团; Q和Q'独立地选自H，C 1 -C 3烷基，C 1 -C 3烷氧基，卤素和CN; n为1〜3的整数， m为0〜2的整数。 和：其中A代表键或对亚苯基; B是（O）-O-CO-CR'-CH 2，-O-CO-CR'-CH 2， o为2-12，p为1，R'为H或CH 3。 P代表CH 2或C-O基团; Q选自H，C 1 -C 3烷基，C 1 -C 3烷氧基，卤素和CN; m为0〜2的整数。