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公开(公告)号：US20110251357A1
公开(公告)日：2011-10-13
申请号：US13046957
申请日：2011-03-14
IPC分类号： C08G77/38
CPC分类号： C09D183/04 , C08G77/045 , C08G77/06 , C08G77/14 , H01L23/296 , H01L27/14623 , H01L27/14625 , H01L31/0216 , H01L31/02164 , H01L2924/0002 , H01L2924/00
摘要： Inorganic/organic hybrid polymers containing silsesquioxane cages are robust and exhibit desirable physical properties such as strength, hardness, and optical transparency at infrared and ultraviolet wavelengths. The polymers are prepared by polymerizing functionalized polyhedral silsesquioxane monomers such as polyhedral silsesquioxanes bearing two complementarily reactive functional groups bonded to cage silicon atoms by means of spacer moieties. The spacer moieties allow for steric mobility and more complete cure than polyhedral silsesquioxanes bearing reactive functional groups bound directly to cage silicon atoms.
摘要翻译： 含有倍半硅氧烷笼的无机/有机杂化聚合物是牢固的并且表现出期望的物理性质，例如红外和紫外线波长下的强度，硬度和光学透明度。 聚合物是通过聚合功能化的多面体倍半硅氧烷单体制备的，例如通过间隔基部分带有两个与笼状硅原子键合的互补反应性官能团的多面体倍半硅氧烷。 间隔基部分允许空间移动和更完全的固化比承载反应性官能团直接结合到笼状硅原子的多面体倍半硅氧烷。
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公开(公告)号：US07915369B2
公开(公告)日：2011-03-29
申请号：US11075042
申请日：2005-03-08
IPC分类号： C08G77/08
CPC分类号： C09D183/04 , C08G77/045 , C08G77/06 , C08G77/14 , H01L23/296 , H01L27/14623 , H01L27/14625 , H01L31/0216 , H01L31/02164 , H01L2924/0002 , H01L2924/00
摘要： Inorganic/organic hybrid polymers containing silsesquioxane cages are robust and exhibit desirable physical properties such as strength, hardness, and optical transparency at infrared and ultraviolet wavelengths. The polymers are prepared by polymerizing functionalized polyhedral silsesquioxane monomers such as polyhedral silsesquioxanes bearing two complementarily reactive functional groups bonded to cage silicon atoms by means of spacer moieties. The spacer moieties allow for steric mobility and more complete cure than polyhedral silsesquioxanes bearing reactive functional groups bound directly to cage silicon atoms.
摘要翻译： 含有倍半硅氧烷笼的无机/有机杂化聚合物是牢固的并且表现出期望的物理性质，例如红外和紫外线波长下的强度，硬度和光学透明度。 聚合物是通过聚合功能化的多面体倍半硅氧烷单体制备的，例如通过间隔基部分带有两个与笼状硅原子键合的互补反应性官能团的多面体倍半硅氧烷。 间隔基部分允许空间移动和更完全的固化比承载反应性官能团直接结合到笼状硅原子的多面体倍半硅氧烷。
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公开(公告)号：US20060122351A1
公开(公告)日：2006-06-08
申请号：US11075042
申请日：2005-03-08
CPC分类号： C09D183/04 , C08G77/045 , C08G77/06 , C08G77/14 , H01L23/296 , H01L27/14623 , H01L27/14625 , H01L31/0216 , H01L31/02164 , H01L2924/0002 , H01L2924/00
摘要： Inorganic/organic hybrid polymers containing silsesquioxane cages are robust and exhibit desirable physical properties such as strength, hardness, and optical transparency at infrared and ultraviolet wavelengths. The polymers are prepared by polymerizing functionalized polyhedral silsesquioxane monomers such as polyhedral silsesquioxanes bearing two complementarily reactive functional groups bonded to cage silicon atoms by means of spacer moieties. The spacer moieties allow for steric mobility and more complete cure than polyhedral silsesquioxanes bearing reactive functional groups bound directly to cage silicon atoms.
摘要翻译： 含有倍半硅氧烷笼的无机/有机杂化聚合物是牢固的并且表现出期望的物理性质，例如红外和紫外线波长下的强度，硬度和光学透明度。 聚合物是通过聚合功能化的多面体倍半硅氧烷单体制备的，例如通过间隔基部分带有两个与笼状硅原子键合的互补反应性官能团的多面体倍半硅氧烷。 间隔基部分允许空间移动和更完全的固化比承载反应性官能团直接结合到笼状硅原子的多面体倍半硅氧烷。
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4.发明授权公开(公告)号：US07576169B2
公开(公告)日：2009-08-18
申请号：US10971809
申请日：2004-10-22
IPC分类号： C08G77/04 , C08G77/06 , C01B33/113
CPC分类号： C08G77/04 , B27K3/153 , C07F7/21 , C08G77/02 , C08G77/045 , C08G77/08 , C08L83/04 , C08L97/02
摘要： Polyhedral silsesquioxane anions are economically prepared by reaction of a silica source derived from combusted organic material with a quaternary ammonium hydroxide compound. Reaction of the resulting anions with chlorosilanes may be effected in near stoichiometric fashion in organic solvent containing reactive quantities of organic acids such as formic acid. The functional groups on the resulting functionalized silsesquioxanes may be substituted for other functional groups by reaction with di- or polysiloxanes in the presence of a synthetic ion exchange resin.
摘要翻译： 通过衍生自燃烧的有机材料的二氧化硅源与季铵氢氧化物化合物的反应经济地制备多面体倍半硅氧烷阴离子。 所得阴离子与氯硅烷的反应可以在含有反应性有机酸如甲酸的有机溶剂中以近化学计量的方式进行。 所得官能化倍半硅氧烷上的官能团可以通过在合成离子交换树脂的存在下与二硅氧烷或聚硅氧烷反应来代替其它官能团。
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5.发明授权Process for making particulate-free poly(phenylene ether) compositions and photovoltaic backsheet materials derived therefrom 有权制造无颗粒聚（亚苯基醚）组合物和由其衍生的光电底片材料的方法公开(公告)号：US08912261B2
公开(公告)日：2014-12-16
申请号：US13530750
申请日：2012-06-22
申请人： Norihiro Takamura
发明人： Norihiro Takamura
IPC分类号： C08K5/523
摘要： The present invention is directed to a process for preparing halogen-free melt-filtered polymer compositions, compositions prepared by the process, as well as articles derived therefrom. The process comprises filtering the melted composition through a filter to remove particulate impurities that are 0.5 mm2 in size or larger. The composition comprises: (a) 60 to 90 percent by weight of a poly(phenylene ether); (b) 3 to 23 percent by weight of a styrenic polymer; (c) 5-11 percent by weight of a halogen-free flame retardant comprising at least one organic phosphate flame retardant, wherein the composition has: (i) a melt viscosity of 620 Pa·s or less as measured according at 280° C. and 1500 s−1; and (ii) a heat deflection temperature that is 135° C. or more as measured according to ASTM D648 on 6.4 mm thick bars at 1.82 MPa.
摘要翻译： 本发明涉及一种制备无卤素熔融过滤聚合物组合物，通过该方法制备的组合物以及由其衍生的制品的方法。 该方法包括通过过滤器过滤熔融的组合物以除去尺寸为0.5mm2或更大的颗粒杂质。 该组合物包含：（a）60至90重量％的聚（苯醚）; （b）3〜23重量％的苯乙烯类聚合物; （c）5-11重量％的含有至少一种有机磷酸酯阻燃剂的无卤阻燃剂，其中该组合物具有：（i）根据280℃测量的熔融粘度为620Pa·s或更低 和1500 s-1; 和（ii）根据ASTM D648在1.82MPa的6.4mm厚的条上测量的135℃或更高的热变形温度。
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公开(公告)号：US08653167B2
公开(公告)日：2014-02-18
申请号：US13116363
申请日：2011-05-26
IPC分类号： C08K5/521
CPC分类号： C08K5/521 , C08G2650/58 , C08K5/0066 , C08K5/34928 , C08L53/025 , C08L71/12 , C08L2201/02 , C08L27/18 , C08L53/005
摘要： A molding composition is disclosed which contains specific amounts of poly(arylene ether), styrenic polymer, hydrogenated block copolymer, flame retardant, and polytetrafluoroethylene. The molding composition performs well on a battery of tests, including heat resistance, impact strength, melt flow, and flame retardancy, and is particularly useful for producing photovoltaic junction boxes and connectors.
摘要翻译： 公开了含有特定量的聚（亚芳基醚），苯乙烯类聚合物，氢化嵌段共聚物，阻燃剂和聚四氟乙烯的成型组合物。 该模塑组合物对包括耐热性，冲击强度，熔体流动性和阻燃性在内的一组测试性能良好，并且对于生产光伏接线盒和连接器特别有用。
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公开(公告)号：US20120302679A1
公开(公告)日：2012-11-29
申请号：US13116363
申请日：2011-05-26
CPC分类号： C08K5/521 , C08G2650/58 , C08K5/0066 , C08K5/34928 , C08L53/025 , C08L71/12 , C08L2201/02 , C08L27/18 , C08L53/005
摘要： A molding composition is disclosed which contains specific amounts of poly(arylene ether), styrenic polymer, hydrogenated block copolymer, flame retardant, and polytetrafluoroethylene. The molding composition performs well on a battery of tests, including heat resistance, impact strength, melt flow, and flame retardancy, and is particularly useful for producing photovoltaic junction boxes and connectors.
摘要翻译： 公开了含有特定量的聚（亚芳基醚），苯乙烯类聚合物，氢化嵌段共聚物，阻燃剂和聚四氟乙烯的成型组合物。 该模塑组合物对包括耐热性，冲击强度，熔体流动性和阻燃性在内的一组测试性能良好，并且对于生产光伏接线盒和连接器特别有用。
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8.发明申请公开(公告)号：US20130345345A1
公开(公告)日：2013-12-26
申请号：US13530750
申请日：2012-06-22
申请人： Norihiro Takamura
发明人： Norihiro Takamura
摘要： The present invention is directed to a process for preparing halogen-free melt-filtered polymer compositions, compositions prepared by the process, as well as articles derived therefrom. The process comprises filtering the melted composition through a filter to remove particulate impurities that are 0.5 mm2 in size or larger. The composition comprises: (a) 60 to 90 percent by weight of a poly(phenylene ether); (b) 3 to 23 percent by weight of a styrenic polymer; (c) 5-11 percent by weight of a halogen-free flame retardant comprising at least one organic phosphate flame retardant, wherein the composition has: (i) a melt viscosity of 620 Pa·s or less as measured according at 280° C. and 1500 s−1; and (ii) a heat deflection temperature that is 135° C. or more as measured according to ASTM D648 on 6.4 mm thick bars at 1.82 MPa.
摘要翻译： 本发明涉及一种制备无卤素熔融过滤聚合物组合物，通过该方法制备的组合物以及由其衍生的制品的方法。 该方法包括通过过滤器过滤熔融的组合物以除去尺寸为0.5mm2或更大的颗粒杂质。 该组合物包含：（a）60至90重量％的聚（苯醚）; （b）3〜23重量％的苯乙烯类聚合物; （c）5-11重量％的含有至少一种有机磷酸酯阻燃剂的无卤阻燃剂，其中该组合物具有：（i）根据280℃测量的熔融粘度为620Pa·s或更低 和1500 s-1; 和（ii）根据ASTM D648在1.82MPa的6.4mm厚的条上测量的135℃或更高的热变形温度。
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公开(公告)号：US08530552B1
公开(公告)日：2013-09-10
申请号：US13457616
申请日：2012-04-27
IPC分类号： C08K5/523
CPC分类号： C08L71/12 , C08K5/523 , C08L25/06 , C08L25/12 , C08L2205/035 , C08L2666/40 , C08L2666/84 , C08L25/08 , C08L33/20
摘要： A composition includes specific amounts of poly(phenylene ether), polymerized styrene residue, and polymerized acrylonitrile residue. The composition can be prepared using a recycled homopolystyrene that includes an acrylonitrile copolymer as an impurity. The composition largely preserves the desirable properties of a corresponding composition prepared from virgin resins without requiring chemical compatibilization of the poly(phenylene ether) and the acrylonitrile copolymer.
摘要翻译： 组合物包括特定量的聚（苯醚），聚合苯乙烯残基和聚合的丙烯腈残基。 组合物可以使用包含丙烯腈共聚物作为杂质的再循环均聚苯乙烯来制备。 该组合物在很大程度上保持了由原始树脂制备的相应组合物所需的性能，而不需要聚（苯醚）和丙烯腈共聚物的化学相容性。
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10.发明申请公开(公告)号：US20050142054A1
公开(公告)日：2005-06-30
申请号：US10971809
申请日：2004-10-22
IPC分类号： B01F20060101 , B05D1/18 , B27K3/20 , C01B33/113 , C07F7/21 , C08G77/04
CPC分类号： C08G77/04 , B27K3/153 , C07F7/21 , C08G77/02 , C08G77/045 , C08G77/08 , C08L83/04 , C08L97/02
摘要： Polyhedral silsesquioxane anions are economically prepared by reaction of a silica source derived from combusted organic material with a quaternary ammonium hydroxide compound. Reaction of the resulting anions with chlorosilanes may be effected in near stoichiometric fashion in organic solvent containing reactive quantities of organic acids such as formic acid. The functional groups on the resulting functionalized silsesquioxanes may be substituted for other functional groups by reaction with di- or polysiloxanes in the presence of a synthetic ion exchange resin.
摘要翻译： 通过衍生自燃烧的有机材料的二氧化硅源与季铵氢氧化物化合物的反应经济地制备多面体倍半硅氧烷阴离子。 所得阴离子与氯硅烷的反应可以在含有反应性有机酸如甲酸的有机溶剂中以近化学计量的方式进行。 所得官能化倍半硅氧烷上的官能团可以通过在合成离子交换树脂的存在下与二硅氧烷或聚硅氧烷反应来代替其它官能团。
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