公开(公告)号：US5392594A

公开(公告)日：1995-02-28

申请号：US12092

申请日：1993-02-01

申请人： Robert B. Moore ,  William P. Hegarty ,  David W. Studer ,  Edward J. Tirados

发明人： Robert B. Moore ,  William P. Hegarty ,  David W. Studer ,  Edward J. Tirados

IPC分类号： C07C27/06 ,  C07C29/151 ,  C07C41/01 ,  C01B17/05

CPC分类号： C07C29/1516 ,  C07C27/06 ,  C07C41/01

摘要： An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

摘要翻译： 在一体化进料处理和催化反应系统中，由包含氢气，一氧化碳，二氧化碳和含硫化合物的合成气的一部分产生氧化有机液体产物和燃料气体。 为了防止催化剂中毒，反应器进料中的含硫化合物被吸收在包含反应器产物的液体中，所得到的含硫液体通过用反应器中未处理的合成气汽提而被再生。 汽提废气与剩余的合成气组合以提供燃料气体产物。 再生液体的一部分用作吸收剂的组成，其余部分作为液体产物取出。 该方法对于与利用燃气轮机进行发电的联合循环煤气化系统的集成特别有用。