Process for making calciummonohydrogen phosphate dihydrate
    2.
    发明授权
    Process for making calciummonohydrogen phosphate dihydrate 失效
    磷酸二氢钙二水合物的制备方法

    公开(公告)号:US4483837A

    公开(公告)日:1984-11-20

    申请号:US507784

    申请日:1983-06-24

    IPC分类号: C01B25/32 C01B15/16 C01B25/26

    CPC分类号: C01B25/322

    摘要: The disclosure relates to a process for making calciummonohydrogen phosphate dihydrate with a high degree of whiteness from pure phosphoric acid and naturally occurring calcium carbonates. More particularly, a fine-particulate calcium carbonate is suspended in water and the suspension is mixed at temperatures between 0.degree. and 60.degree. C. with phosphoric acid so as to establish a Ca/P-ratio of 0.20 up to 0.57. The phosphoric acid is added in quantities per unit time preventing the resulting mixture from foaming over. Next, solid matter constituents are separated from the mixture, after CO.sub.2 has ceased to evolve, with the resultant formation of a clear colorless acid solution. This solution and an aqueous suspension or solution of pure alkali metal and/or alkaline earth metal carbonates and/or hydroxides, are jointly introduced into a reaction zone at a reaction temperature of 20.degree. to 45.degree. C. so as to establish a pH-value initially of 2.0 to 5.0 and then, towards the end of the reaction of 6.0 to 8.0. Finally, the reaction product is filtered off, washed out, and dried in known fashion.

    摘要翻译: 本公开涉及一种从纯磷酸和天然存在的碳酸钙制备具有高白度的磷酸氢钙二水合物的方法。 更具体地,将细颗粒碳酸钙悬浮在水中,并将悬浮液在0℃至60℃的温度下与磷酸混合,以便确定0.20至0.57的Ca / P比。 每单位时间内加入磷酸,防止所得混合物发泡。 接下来,在CO 2停止放出之后,固体成分与混合物分离,形成澄清的无色酸溶液。 将该溶液和纯碱金属和/或碱土金属碳酸盐和/或氢氧化物的水性悬浮液或溶液在20〜45℃的反应温度下共同引入反应区,以建立pH- 值最初为2.0〜5.0,然后在6.0〜8.0的反应结束。 最后,将反应产物滤出,洗涤并以已知方式干燥。