公开(公告)号：US4765796A

公开(公告)日：1988-08-23

申请号：US75169

申请日：1987-07-20

Applicant: Robert J. Harper, Jr. ,  John V. Beninate

Inventor： Robert J. Harper, Jr. ,  John V. Beninate

IPC: D06M13/285 ,  D06M15/431 ,  D06M9/00 ,  D06P5/00

CPC classification number: D06M15/431 ,  D06M13/285 ,  D06P3/6008 ,  D06P3/62 ,  D06P3/66

Abstract: Cellulosic fabric is dyed by affixing a hydroxymethyl phosphonium-nitrogen based polymer to the fabric and thereafter dyeing it with a cotton dye having anionic groups, in an acidic or neutral environment. In addition, a new method of affixing the polymer to the fabric is provided comprising contacting the fabric with a solution of urea and a precondensate of urea and tetrakis hydroxymethyl phosphonium salt.

Abstract translation: 纤维素织物通过将羟甲基鏻 - 氮基聚合物固定在织物上，然后在酸性或中性环境中用具有阴离子基团的棉花染料染色。 此外，提供了将聚合物固定在织物上的新方法，包括使织物与脲和脲和四羟甲基鏻盐的预缩合物的溶液接触。

公开(公告)号：US3954400A

公开(公告)日：1976-05-04

申请号：US499810

申请日：1974-08-22

Applicant: Wilson A. Reeves ,  Darrell J. Donaldson ,  Donald J. Daigle ,  George L. Drake, Jr. ,  John V. Beninate

Inventor： Wilson A. Reeves ,  Darrell J. Donaldson ,  Donald J. Daigle ,  George L. Drake, Jr. ,  John V. Beninate

IPC: D06M15/431 ,  C08G51/24 ,  D06M13/32 ,  D06M13/38

CPC classification number: D06M15/431 ,  Y10S428/921

Abstract: Textile treating compositions containing the elements phosphorus, nitrogen, and bromine and the processes for imparting flame resistance to organic fibrous materials have been prepared. This is accomplished by impregnating the textile treating compositions consisting of (1) tris(hydroxymethyl)phosphine mixed with nitrogenous compounds containing at least two members of the group hydrogen and methylol radicals (--CH.sub.2 OH) attached to trivalent nitrogen atoms, or (2) soluble methylol phosphine adducts which contain one or more methylol phosphine radicals (P--CH.sub.2 OH) prepared by reacting tris(hydroxymethyl)phosphine with an amide or amine which contains one or more hydrogens attached to a trivalent nitrogen with an organic bromine containing material with at least 10% bromine in the form of bromine atoms attached to carbon atoms, in proportions selected so that generally the phosphorus contained in structures of the group (--CH.sub.2).sub.3 P amounts to a small portion of the total weight of the mixture, and heating to cause insolubilization in or on the fibrous structure.

Abstract translation: 已经制备了含有磷，氮和溴元素的纺织品处理组合物和赋予有机纤维材料阻燃性的方法。 这是通过浸渍由（1）三（羟甲基）膦混合的纺织品处理组合物实现的，所述组合物与含有至少两个连接到三价氮原子的氢和羟甲基（-CH 2 OH）的成员的含氮化合物混合，或（2）可溶的 含有一个或多个羟甲基膦加成物的羟甲基膦加合物（P-CH 2 OH），其通过使三（羟甲基）膦与含有一个或多个与三价氮连接的氢的酰胺或胺与含有有机溴的材料与至少10 以溴原子连接碳原子的形式的溴，以选定的比例，使得通常基团（-CH 2）3 P的结构中所含的磷相当于混合物总重量的一小部分，并加热以引起不溶解 在纤维结构中或之上。

公开(公告)号：US4067687A

公开(公告)日：1978-01-10

申请号：US652277

申请日：1976-01-23

Applicant: Darrell J. Donaldson ,  George L. Drake, Jr. ,  John V. Beninate ,  Wilson A. Reeves ,  Donald J. Daigle

Inventor： Darrell J. Donaldson ,  George L. Drake, Jr. ,  John V. Beninate ,  Wilson A. Reeves ,  Donald J. Daigle

IPC: D06M15/431 ,  D06M15/673 ,  D06M1/00

CPC classification number: D06M15/673 ,  D06M15/431 ,  Y10S428/921

Abstract: Textile treating compositions containing the elements phosphorus, nitrogen, and bromine and the processes for imparting flame resistance to organic fibrous materials have been prepared. This is accomplished by impregnating the textile treating compositions consisting of (1) tris(hydroxymethyl)phosphine mixed with nitrogenous compounds containing at least two members of the group hydrogen and methylol radicals (--CH.sub.2 OH) attached to trivalent nitrogen atoms, or (2) soluble methylol phosphine adducts which contain one or more methylol phosphine radicals (P--CH.sub.2 OH) prepared by reacting tris(hydroxymethyl)phosphine with an amide or amine which contains one or more hydrogens attached to a trivalent nitrogen with an organic bromine containing material with at least 10% bromine in the form of bromine atoms attached to carbon atoms, in proportions selected so that generally the phosphorus contained in structures of the group (--CH.sub.2).sub.3 P amount to a small portion of the total weight of the mixture, and heating to cause insolubilization in or on the fibrous structure.

Abstract translation: 已经制备了含有磷，氮和溴元素的纺织品处理组合物和赋予有机纤维材料阻燃性的方法。 这是通过浸渍由（1）三（羟甲基）膦混合的纺织品处理组合物实现的，所述组合物与含有至少两个连接到三价氮原子的氢和羟甲基（-CH 2 OH）的成员的含氮化合物混合，或（2）可溶的 含有一个或多个羟甲基膦加成物的羟甲基膦加合物（P-CH 2 OH），其通过使三（羟甲基）膦与含有一个或多个与三价氮连接的氢的酰胺或胺与含有有机溴的材料与至少10 以溴原子连接碳原子形式的溴的比例按所选择的比例，使得通常基团（-CH 2）3 P的结构中所含的磷相当于混合物总重量的一小部分，并加热以引起不溶解 在纤维结构中或之上。

公开(公告)号：US3987013A

公开(公告)日：1976-10-19

申请号：US543704

申请日：1975-01-23

Applicant: John V. Beninate ,  Donald J. Daigle ,  George L. Drake ,  Wilson A. Reeves ,  Darrell J. Donaldson

Inventor： John V. Beninate ,  Donald J. Daigle ,  George L. Drake ,  Wilson A. Reeves ,  Darrell J. Donaldson

IPC: C08G18/38 ,  D06M15/579 ,  D06M15/667 ,  D06M15/673 ,  C08G18/00

CPC classification number: C08G18/3889 ,  C08G18/388 ,  D06M15/579 ,  D06M15/667 ,  D06M15/673

Abstract: Methylol phosphines, methylol phosphines in combination with amine or amido compounds or water soluble adducts of these methylol phosphines and amides or amines when mixed and reacted with mono, di or polyisocyanates wherein the isocyanate groups are attached to carbon atoms are particularly valuable for the preparation of thermosetting flame resistant polymers. The polymers which are produced are crosslinked phosphorus and nitrogen containing polymers in which the reoccurring structure units each contain a phosphorus atom, that is a component of a radical of the group tris(methylene)-phosphine (--CH.sub.2).sub.3 P and is linkd to at least one isocyanate radical by connecting urethane structure.The polymer forming solutions are also valuable for the preparation of flame-, glow-, wrinkle- and shrink-resistant textiles by impregnating fabrics with these solutions and causing reaction and polymer formation by application of heat.