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公开(公告)号:US07141701B1
公开(公告)日:2006-11-28
申请号:US11207951
申请日:2005-08-19
申请人: Robert J. Schmidt , Russell C. Schulz , Patrick J. Bullen , Constante P. Tagamolila , Steven P. Lankton , Gary A. Peterson , Michael E. Fettis
发明人: Robert J. Schmidt , Russell C. Schulz , Patrick J. Bullen , Constante P. Tagamolila , Steven P. Lankton , Gary A. Peterson , Michael E. Fettis
摘要: A process for decomposing a cumene oxidation product mixture containing cumene hydroperoxide (CHP) and dimethylphenolcarbinol (DMPC) to produce phenol and acetone.
摘要翻译: 一种用于分解含有氢过氧化枯烯(CHP)和二甲基苯酚甲醇(DMPC)的枯烯氧化产物混合物以产生苯酚和丙酮的方法。
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公开(公告)号:US07141700B1
公开(公告)日:2006-11-28
申请号:US11207842
申请日:2005-08-19
申请人: Robert J. Schmidt , Russell C. Schulz , Patrick J. Bullen , Constante P. Tagamolila , Steven P. Lankton , Gary A. Peterson , Michael E. Fettis
发明人: Robert J. Schmidt , Russell C. Schulz , Patrick J. Bullen , Constante P. Tagamolila , Steven P. Lankton , Gary A. Peterson , Michael E. Fettis
摘要: A process for the decomposition of a cumene oxidation product mixture to produce phenol and acetone with reduced by-product formation by introducing the cumene oxidation mixture into an inlet of a decomposing vessel containing indirect heat exchange surfaces wherein the cumene oxidation product mixture and a circulating stream are admixed, reacted and cooled by passage around the indirect heat exchange surfaces.
摘要翻译: 一种通过将异丙基苯氧化混合物引入含有间接热交换表面的分解容器的入口中来分解枯烯氧化产物混合物以产生苯酚和丙酮以减少副产物形成的方法,其中异丙基苯氧化产物混合物和循环流 通过绕间接热交换表面通过混合,反应和冷却。
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公开(公告)号:US20100292519A1
公开(公告)日:2010-11-18
申请号:US12467622
申请日:2009-05-18
IPC分类号: C07C2/00
CPC分类号: C07C6/126 , C07C7/1485 , C07C2521/04 , C07C2521/08 , C07C2529/08 , C07C2529/70 , C07C15/073 , C07C15/085 , C07C15/02
摘要: Byproduct formation in aromatic alkylation processes is reduced when different polyalkylated aromatic compounds are first fractionated into separate streams enriched in these respective polyalkylated aromatic compounds, and the separate streams are sent to different transalkylation reaction zones, which may or may not be in the same reactor. The different transalkylation reaction zones allow for greater control of the transalkylation of the respective polyalkylated aromatic compounds, such as diisopropylbenzene (DIPB) and triisopropylbenzene (TIPB) that accompany the alkylation of benzene with propylene in a process for cumene production.
摘要翻译: 当将不同的多烷基化芳族化合物首先分馏成富含这些各自的多烷基化芳族化合物的分离的流中时,芳族烷基化方法中的副产物形成降低,并且将分离的物流送入不同的烷基转移反应区,其可以是或不在同一个反应器中。 不同的烷基转移反应区可以更好地控制各种多烷基化芳族化合物如二异丙基苯(DIPB)和三异丙基苯(TIPB)在烷基化反应过程中伴随苯与丙烯烷基化反应的烷基转移。
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公开(公告)号:US09150469B2
公开(公告)日:2015-10-06
申请号:US12467622
申请日:2009-05-18
CPC分类号: C07C6/126 , C07C7/1485 , C07C2521/04 , C07C2521/08 , C07C2529/08 , C07C2529/70 , C07C15/073 , C07C15/085 , C07C15/02
摘要: Byproduct formation in aromatic alkylation processes is reduced when different polyalkylated aromatic compounds are first fractionated into separate streams enriched in these respective polyalkylated aromatic compounds, and the separate streams are sent to different transalkylation reaction zones, which may or may not be in the same reactor. The different transalkylation reaction zones allow for greater control of the transalkylation of the respective polyalkylated aromatic compounds, such as diisopropylbenzene (DIPB) and triisopropylbenzene (TIPB) that accompany the alkylation of benzene with propylene in a process for cumene production.
摘要翻译: 当将不同的多烷基化芳族化合物首先分馏成富含这些各自的多烷基化芳族化合物的分离的流中时,芳族烷基化方法中的副产物形成降低,并且将分离的物流送入不同的烷基转移反应区,其可以是或不在同一个反应器中。 不同的烷基转移反应区可以更好地控制各种多烷基化芳族化合物如二异丙基苯(DIPB)和三异丙基苯(TIPB)在烷基化反应过程中伴随苯与丙烯烷基化反应的烷基转移。
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公开(公告)号:US07525003B2
公开(公告)日:2009-04-28
申请号:US11752508
申请日:2007-05-23
IPC分类号: C07C15/073 , C07C2/64
CPC分类号: C07C15/073 , C07C2/66 , C07C6/126
摘要: This ethylbenzene process involves contacting, in an alkylation zone, a first benzene recycle stream and an ethylene feed stream with an alkylation catalyst to form ethylbenzene. In a transalkylation zone, a polyethylbenzene recycle stream and a second benzene recycle stream are contacted with a transalkylation catalyst to form additional ethylbenzene. The effluents are passed into a dividing wall distillation column where a benzene overhead and a benzene side draw are removed and recycled. An ethylbenzene stream product stream is also removed. The remainder, largely polyethylbenzene and tar, is passed to a polyethylbenzene column for separation. The separated polyethylbenzene is recycled to the transalkylation reactor.
摘要翻译: 该乙苯方法包括在烷基化区中与烷基化催化剂接触第一苯再循环流和乙烯进料流以形成乙苯。 在烷基转移区中,将聚乙苯再循环流和第二苯再循环流与烷基转移催化剂接触以形成另外的乙苯。 流出物被送入分离塔蒸馏塔,其中苯塔顶馏出物和苯侧馏分被除去并再循环。 还除去乙苯料流产物流。 其余的,主要是聚乙苯和焦油,被送到聚乙苯塔进行分离。 将分离的聚乙苯再循环至烷基转移反应器。
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公开(公告)号:US20080289946A1
公开(公告)日:2008-11-27
申请号:US11752532
申请日:2007-05-23
IPC分类号: B01D3/14
摘要: The apparatus includes an alkylation unit connected to a first benzene recycle conduit, a feed conduit and an alkylation effluent conduit; a transalkylation unit connected to an polyalkylbenzene recycle conduit, a second benzene recycle conduit, and a transalkylation effluent conduit. A dividing wall distillation column is in fluid communication with the transalkylation effluent conduit, the alkylation effluent conduit, a product stream, a bottoms stream conduit and first and second benzene recycle conduits. A polyalkylbenzene fractionation column is connected to the bottoms stream conduit, the polyalkylbenzene recycle conduit and a heavy component conduit.
摘要翻译: 该装置包括连接到第一苯循环导管,进料管和烷基化流出物导管的烷基化单元; 连接到多烷基苯再循环导管,第二苯循环导管和烷基转移流出物导管的烷基转移单元。 分隔壁蒸馏塔与烷基转移流出物导管,烷基化流出物导管,产物流,塔底流导管和第一和第二苯循环导管流体连通。 多烷基苯分馏塔连接到底部料流管道,聚烷基苯再循环管道和重组分管道。
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公开(公告)号:US07525006B2
公开(公告)日:2009-04-28
申请号:US11752528
申请日:2007-05-23
IPC分类号: C07C15/073 , C07C2/64
摘要: This cumene process involves contacting, in an alkylation zone, a first benzene recycle stream and a propylene feed stream with an alkylation catalyst to form cumene. In a transalkylation zone, a polyisopropyl benzene recycle stream and a second benzene recycle stream are contacted with a transalkylation catalyst to form additional cumene. The effluents are passed into a dividing wall distillation column. A cumene stream is removed from an intermediate point of the dividing wall fractionation column; a first benzene recycle stream is removed from a first end and a heavy aromatics stream is removed from a second end. A second benzene recycle stream is removed from an intermediate point located between the first end and the cumene stream. A polyisopropyl benzene stream is removed from an intermediate point of located between the second end and the cumene stream.
摘要翻译: 该枯烯方法包括在烷基化区中与烷基化催化剂接触第一苯再循环流和丙烯进料流以形成枯烯。 在烷基转移区中,将聚异丙基苯再循环物流和第二苯循环物流与烷基转移催化剂接触以形成额外的枯烯。 将废水排入分隔壁蒸馏塔。 从分隔壁分馏塔的中间点除去枯烯物流; 从第一端除去第一苯回收物流,并从第二端除去重质芳烃物流。 从位于第一端和异丙苯流之间的中间点除去第二苯循环物流。 从位于第二端和异丙苯流之间的中间点除去聚异丙基苯物流。
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公开(公告)号:US07525005B2
公开(公告)日:2009-04-28
申请号:US11752520
申请日:2007-05-23
IPC分类号: C07C15/073 , C07C2/64
CPC分类号: C07C15/085 , C07C2/66 , C07C6/126
摘要: This cumene process involves contacting, in an alkylation zone, a first benzene recycle stream and a propylene feed stream with an alkylation catalyst to form cumene. In a transalkylation zone, a polyisopropylbenzene recycle stream and a second benzene recycle stream are contacted with a transalkylation catalyst to form additional cumene. The effluents are passed into a benzene distillation column. From the benzene distillation column, a first benzene recycle stream is removed as overhead; a second benzene recycle stream is removed as a side draw; and a bottoms stream comprising polyisopropylbenzene, cumene, and heavy aromatics is removed from an end. The bottoms stream is passed to a dividing wall distillation column where the polyisopropylbenzene recycle stream is removed from an intermediate point; a cumene product stream is removed from a first end, and a heavy aromatic stream is removed from a second end.
摘要翻译: 该枯烯方法包括在烷基化区中与烷基化催化剂接触第一苯再循环流和丙烯进料流以形成枯烯。 在烷基转移区中,将聚异丙基苯循环物流和第二苯再循环物流与烷基转移催化剂接触以形成额外的枯烯。 将废水送入苯蒸馏塔。 从苯蒸馏塔中取出第一个苯循环物流作为塔顶馏出物; 第二个苯循环流作为侧面吸附除去; 并且从末端去除包含聚异丙基苯,枯烯和重芳烃的底部料流。 将底部物流送入分隔壁蒸馏塔,从中间点除去聚异丙苯再循环物流; 从第一端除去枯烯产物流,并从第二端除去重芳族物流。
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公开(公告)号:US07713386B2
公开(公告)日:2010-05-11
申请号:US11752532
申请日:2007-05-23
摘要: The apparatus includes an alkylation unit connected to a first benzene recycle conduit, a feed conduit and an alkylation effluent conduit; a transalkylation unit connected to an polyalkylbenzene recycle conduit, a second benzene recycle conduit, and a transalkylation effluent conduit. A dividing wall distillation column is in fluid communication with the transalkylation effluent conduit, the alkylation effluent conduit, a product stream, a bottoms stream conduit and first and second benzene recycle conduits. A polyalkylbenzene fractionation column is connected to the bottoms stream conduit, the polyalkylbenzene recycle conduit and a heavy component conduit.
摘要翻译: 该装置包括连接到第一苯循环导管,进料管和烷基化流出物导管的烷基化单元; 连接到多烷基苯再循环导管,第二苯循环导管和烷基转移流出物导管的烷基转移单元。 分隔壁蒸馏塔与烷基转移流出物导管,烷基化流出物导管,产物流,塔底流导管和第一和第二苯循环导管流体连通。 多烷基苯分馏塔连接到底部料流管道,聚烷基苯再循环管道和重组分管道。
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公开(公告)号:US07525004B2
公开(公告)日:2009-04-28
申请号:US11752516
申请日:2007-05-23
IPC分类号: C07C15/073 , C07C2/64
CPC分类号: C07C2/66 , C07C6/126 , C07C15/073
摘要: This ethylbenzene process involves contacting, in an alkylation zone, a first benzene recycle stream and an ethylene feed stream with an alkylation catalyst to form ethylbenzene. In a transalkylation zone, a polyethylbenzene recycle stream and a second benzene recycle stream are contacted with a transalkylation catalyst to form additional ethylbenzene. The effluents are passed into a benzene distillation column. From the benzene distillation column, a first benzene recycle stream is removed as overhead; a second benzene recycle stream is removed as a side draw; and a bottoms stream comprising polyethylbenzene, ethylbenzene, and flux oil is removed from an end. The bottoms stream is passed to a dividing wall distillation column where the polyethylbenzene recycle stream is removed from an intermediate point; an ethylbenzene product stream is removed from a first end, and a heavy oil stream is removed from a second end.
摘要翻译: 该乙苯方法包括在烷基化区中与烷基化催化剂接触第一苯再循环流和乙烯进料流以形成乙苯。 在烷基转移区中,将聚乙苯再循环流和第二苯再循环流与烷基转移催化剂接触以形成另外的乙苯。 将废水送入苯蒸馏塔。 从苯蒸馏塔中取出第一个苯循环物流作为塔顶馏出物; 第二个苯循环流作为侧面吸附除去; 从末端除去包含聚乙基苯,乙苯和助熔剂油的底部料流。 将塔底物流送入分隔壁蒸馏塔,其中从中间点除去多乙基苯循环物流; 从第一端去除乙苯产物流,并从第二端除去重油流。
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