公开(公告)号：US4861787A

公开(公告)日：1989-08-29

申请号：US263961

申请日：1988-10-25

申请人： Ernst Beriger ,  Wolfgang Eckhardt ,  Robert Nyfeler

发明人： Ernst Beriger ,  Wolfgang Eckhardt ,  Robert Nyfeler

IPC分类号： A01N43/82 ,  A01N43/824 ,  C07D413/04 ,  C07D417/04

CPC分类号： C07D413/04 ,  A01N43/82 ,  C07D417/04

摘要： Novel compounds of the formula ##STR1## in which R' represents C.sub.1 -C.sub.5 -alkyl, halogen, trifluoromethyl or C.sub.1 -C.sub.3 -alkoxy;R" represents C.sub.1 -C.sub.5 -alkyl or halogen; andR"' represents C.sub.1 -C.sub.5 -alkyl that is unsubstituted or is substituted by from 1 to 6 halogen atoms, C.sub.1 -C.sub.5 -alkenyl that is unsubstituted or is substituted by from 1 to 6 halogen atoms, or C.sub.1 -C.sub.5 - alkynyl that is unsubstituted or is substituted by from 1 to 6 halogen atoms;m represents 0, 1, 2 or 3 andn represents 0 or 1; andX.sub.1 and X.sub.2 each represents, independently of the other, oxygen or sulphur,as active ingredients for controlling plant parasite nematodes and for preventing damage to cultivated plants caused by nematode attack.

摘要翻译： 式中，R'表示C 1 -C 5 - 烷基，卤素，三氟甲基或C 1 -C 3 - 烷氧基的新化合物＆lt; IMAGE＆gt; R“表示C 1 -C 5烷基或卤素; 和R“'表示未被取代或被1至6个卤素原子取代的C1-C5-烷基，未被取代或被1至6个卤素原子取代的C1-C5-烯基或C1-C5-炔基 未被取代或被1至6个卤素原子取代; m表示0,1,2或3，n表示0或1; X1和X2各自独立地表示作为控制植物寄生线虫的活性成分的氧或硫，并且用于防止由线虫攻击引起的对栽培植物的损害。

公开(公告)号：US4894380A

公开(公告)日：1990-01-16

申请号：US176483

申请日：1988-03-25

申请人： Robert Nyfeler ,  Wolfgang Eckhardt ,  Ernst Beriger ,  Odd Kristiansen

发明人： Robert Nyfeler ,  Wolfgang Eckhardt ,  Ernst Beriger ,  Odd Kristiansen

IPC分类号： A01N43/82 ,  A01N43/824 ,  C07D413/04 ,  C07D417/04

CPC分类号： C07D413/04 ,  A01N43/82 ,  C07D417/04

摘要： The invention relates to 2-mercapto-5-pyridyl-1,3,4-oxadiazoles and 2-mercapto-5-pyridyl-1,3,4-thiadiazoles of the formula I ##STR1## wherein X is oxygen or sulfur,R' is C.sub.1 -C.sub.3 alkyl which is substituted by bromine, fluorine, C.sub.1 -C.sub.3 alkoxy or cyano; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkenyl; unsubstituted or halogen-substituted C.sub.4 -C.sub.7 alkynyl,R is C.sub.1 -C.sub.3 alkyl, unsubstituted C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkoxy which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkenyl; C.sub.3 -C.sub.7 alkynyl, C.sub.1 -C.sub.3 alkylthio, halogen, cyano, hydroxy, amino or amino which is substituted by one or two C.sub.1 -C.sub.3 alkyl groups; or is aminocarbonyl; andn is 0, 1, 2, 3 or 4,to the preparation of the compounds of formula I and to novel intermediates for the synthesis of these compounds. The compounds of formula I have nematicidal properties. The invention further relates to nematicidal compositions which contain at least one compound of formula I as active component, and to methods of using said compounds and of the compositions containing them for controlling nematodes.

摘要翻译： 本发明涉及式I的2-巯基-5-吡啶基-1,3,4-恶二唑和2-巯基-5-吡啶基-1,3,4-噻二唑，其中X是氧或 硫，R'是被溴，氟，C 1 -C 3烷氧基或氰基取代的C 1 -C 3烷基; 未取代或卤素取代的C 3 -C 7链烯基; 未取代的或卤素取代的C4-C7炔基，R是C1-C3烷基，未取代的C1-C3烷氧基或被卤素或C1-C3烷氧基取代的C1-C3烷氧基; 未取代或卤素取代的C 3 -C 7链烯基; 被一个或两个C 1 -C 3烷基取代的C 3 -C 7炔基，C 1 -C 3烷硫基，卤素，氰基，羟基，氨基或氨基; 或是氨基羰基; 和n为0,1,2,3或4，用于制备式I化合物和用于合成这些化合物的新中间体。 式I的化合物具有杀线虫性质。 本发明还涉及含有至少一种式I化合物作为活性组分的杀线虫组合物，以及使用所述化合物和含有它们的组合物控制线虫的方法。

公开(公告)号：US4861367A

公开(公告)日：1989-08-29

申请号：US172884

申请日：1988-03-25

申请人： Robert Nyfeler ,  Wolfgang Eckhardt ,  Ernst Beriger

发明人： Robert Nyfeler ,  Wolfgang Eckhardt ,  Ernst Beriger

IPC分类号： A01N43/82 ,  A01N43/824 ,  C07D413/04 ,  C07D417/04

CPC分类号： C07D413/04 ,  A01N43/82 ,  C07D417/04

摘要： 2-Mercapto-5-pyrazinyl-1,3,4-oxadiazoles and 2-mercapto-5-pyrazinyl-1,3,4-thiadiazoles of formula I ##STR1## wherein X is oxygen or sulfur,R' is C.sub.1 -C.sub.5 alkyl, unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or cyano; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkenyl; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkynyl,R is C.sub.1 -C.sub.3 alkyl, unsubstituted C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkoxy which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy; halogen, cyano, hydroxy, amino or amino which is substituted by one or two C.sub.1 -C.sub.3 alkyl groups; or is aminocarbonyl; andn is 0, 1, 2 or 3, the preparation thereof and novel intermediates for their synthesis are disclosed.The compounds of formula I have nematicidal properties. Nematicidal compositions which contain at least one compound of formula I as active ingredient, methods of using said compounds and of the compositions containing them for controlling nematodes are also disclosed.

摘要翻译： 2-巯基-5-吡嗪基-1,3,4-恶二唑和式I的2-巯基-5-吡嗪基-1,3,4-噻二唑其中X是氧或硫，R'是 C1-C5烷基，未取代或被卤素，C1-C3烷氧基或氰基取代; 未取代或卤素取代的C 3 -C 7链烯基; 未取代的或卤素取代的C3-C7炔基，R是C1-C3烷基，未取代的C1-C3烷氧基或被卤素或C1-C3烷氧基取代的C1-C3烷氧基; 卤素，氰基，羟基，氨基或被一个或两个C 1 -C 3烷基取代的氨基; 或是氨基羰基; 并且n为0,1,2或3，其制备及其合成的新中间体被公开。 式I的化合物具有杀线虫性质。 还公开了含有至少一种式I化合物作为活性成分的杀线虫剂组合物，使用所述化合物和含有它们的组合物用于控制线虫的方法。

公开(公告)号：US5162349A

公开(公告)日：1992-11-10

申请号：US408837

申请日：1989-09-18

申请人： Ernst Beriger ,  Wolfgang Eckhardt

发明人： Ernst Beriger ,  Wolfgang Eckhardt

IPC分类号： A01N43/82 ,  A01N43/824 ,  C07D271/10 ,  C07D271/113 ,  C07D285/12 ,  C07D285/125 ,  C07D417/04

CPC分类号： C07D271/113 ,  A01N43/82 ,  C07D285/125 ,  C07D417/04

摘要： Mercapto-bis-[1,3,4-oxa- and -thiadiazoles] ##STR1## in which X.sub.1 and X.sub.2 independently of one another are oxygen or sulfur, R.sub.1 is hydrogen or C.sub.1 -C.sub.5 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or cyano; C.sub.3 -C.sub.7 alkenyl which is unsubstituted or substituted by halogen; or C.sub.3 -C.sub.7 alkynyl which is unsubstituted or substituted by halogen,R.sup.2 is hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.3 alkoxy which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkylthio which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.7 alkenylthio which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.7 alkylnylthio which is unsubstituted or substituted by halogen, --SH, phenyl which is unsubstituted or substituted by halogen or ##STR2## in which R.sub.3 and R.sub.4 are C.sub.1 -C.sub.3 alkyl, and processes for the preparation of the compounds of the formula I are described.The compounds of the formula I have nematocidal and microbicidal properties. Nematocidal compositions which contain at least one active substance of the formula I as the active substance and furthermore processes for the use of the active substances and the compositions in combating nematodes and fungi which are harmful to plants are described.

摘要翻译： 其中X 1和X 2彼此独立地是氧或硫，R 1是氢或C 1 -C 5烷基的巯基 - 双 - [1,3,4-氧杂 - 噻二唑]（I） 卤素，C 1 -C 3烷氧基或氰基; 未被取代或被卤素取代的C3-C7链烯基; 或未取代或被卤素取代的C 3 -C 7炔基，R 2是氢，C 1 -C 5烷基，未被取代或被卤素取代的C 1 -C 3烷氧基，未被取代或被卤素取代的C 1 -C 3烷硫基，未取代或取代的C 3 -C 7链烯基 未取代或被卤素取代的C 3 -C 7烷基硫基，-SH，未被取代或被卤素取代的苯基或其中R 3和R 4为C 1 -C 3烷基的化合物，以及制备式 我被描述 式I的化合物具有杀线虫和杀微生物的性质。 描述了含有至少一种式I活性物质作为活性物质的杀伤组合物，并且还描述了使用活性物质和组合物来防治对植物有害的线虫和真菌的方法。

公开(公告)号：US5013745A

公开(公告)日：1991-05-07

申请号：US408838

申请日：1989-09-18

申请人： Ernst Beriger ,  Wolfgang Eckhardt

发明人： Ernst Beriger ,  Wolfgang Eckhardt

IPC分类号： A01N43/82 ,  C07D271/10 ,  C07D271/113 ,  C07D285/12 ,  C07D285/125 ,  C07D413/04 ,  C07D417/04 ,  G04B37/10

CPC分类号： A01N43/82 ,  C07D271/113 ,  C07D285/125 ,  C07D413/04 ,  C07D417/04 ,  G04B37/10

摘要： 2-Mercapto-1,3,4-oxadiazoles and 2-mercapto-1,3,4-thiadiazoles of the formula I ##STR1## in which X.sub.1 and X.sub.2 independently of one another are oxygen or sulfur, R.sub.1 is difluoromethyl or 3,4,4-trifluoro-3-butenyl, R.sub.2 is hydrogen or C.sub.1 -C.sub.3 alkyl and R.sub.3 is hydrogen, C.sub.1 -C.sub.5 alkyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy, C.sub.3 -C.sub.7 alkenyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy, C.sub.3 -C.sub.7 alkynyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy, or phenyl which is unsubstituted or substituted by halogen, NO.sub.2, CF.sub.3, C.sub.1 -C.sub.3 -alkyl or C.sub.1 -C.sub.3 alkoxy, or wherein, furthermore, R.sub.2 and R.sub.3 together can form the methylene chain (--CH.sub.2 --)n as a constituent of a 5- or 6-membered ring with the heteroatom X.sub.1, in which n is 3 or 4, and processes for the preparation of the compounds of the formula I are described.The compounds of the formula I have nematicidal properties. Nematicidal compositions which contain at least one active substance of the formula I as the active substance and furthermore methods of using the active substances and the compositions for controlling nematodes are described.

摘要翻译： 式I的2-巯基-1,3,4-恶二唑和2-巯基-1,3,4-噻二唑其中X1和X2彼此独立地是氧或硫，R1是二氟甲基 或3,4,4-三氟-3-丁烯基，R 2是氢或C 1 -C 3烷基，R 3是氢，未被取代或被卤素或C 1 -C 3烷氧基取代的C 1 -C 5烷基，未被取代或被卤素取代的C 3 -C 7链烯基 或C1-C3烷氧基，未被取代或被卤素或C1-C3烷氧基取代的C3-C7炔基，或未被取代或被卤素，NO2，CF3，C1-C3-烷基或C1-C3烷氧基取代的苯基，或者其中R2 和R3一起可以形成作为与杂原子X1（其中n为3或4）的5或6元环的组成的亚甲基链（-CH 2 - ）n，以及制备式 我被描述 式I的化合物具有杀线虫性质。 描述了含有至少一种式I活性物质作为活性物质的杀线虫剂组合物，以及使用活性物质和组合物控制线虫的方法。

公开(公告)号：US4910210A

公开(公告)日：1990-03-20

申请号：US285846

申请日：1988-12-16

申请人： Ernst Beriger ,  Wolfgang Eckhardt

发明人： Ernst Beriger ,  Wolfgang Eckhardt

IPC分类号： A01N43/82 ,  A01N43/824 ,  C07D285/12 ,  C07D285/125 ,  C07D417/12

CPC分类号： C07D285/125 ,  A01N43/82 ,  C07D417/12

摘要： Novel compounds of the formula ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.12 alkyl that is unsubstituted or substituted by halogen, phenyl, C.sub.1 -C.sub.3 alkoxy or by hydroxy, C.sub.1 -C.sub.3 alkyl that is substituted by carbonyl, O-alkylcarboxy, amino or by a heterocycle, unsubstituted or halo-substituted C.sub.3 -C.sub.7 cycloalkyl or unsubstituted cyclopropylmethyl, unsubstituted or halo-substituted C.sub.3 -C.sub.7 alkenyl, unsubstituted or halo-substituted C.sub.3 -C.sub.7 alkynyl, benzyl that is unsubstituted or mono-, di-or tri-substituted in the nucleus by C.sub.1 -C.sub.4 alkyl, halogen, nitro, cyano or by trifluoromethyl, or is the radical R.sub.2 --(O--CH.sub.2 --CH.sub.2 --)n wherein R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl and n is a number from 1 to 3, as active ingredients for controlling nematodes that parasitise plants and for preventing damage to cultivated plants caused by nematode attack.

摘要翻译： 式（I）的新型化合物，其中R 1是未被取代或被卤素，苯基，C 1 -C 3烷氧基或羟基取代的C 1 -C 12烷基，被羰基，O-烷基羧基，氨基或被烷基取代的C 1 -C 3烷基 未取代或未取代的或未取代的或未被取代的C 3 -C 7炔基，未被取代的或被卤素取代的C 3 -C 7炔基，在核中未被取代或单，二或三取代的苄基 或C 1 -C 4烷基，卤素，硝基，氰基或三氟甲基，或其中R 2为氢或C 1 -C 4烷基且n为1至3的数的基团R 2 - （O-CH 2 -CH 2 - ）n作为活性成分 用于控制寄生植物的线虫和防止由线虫攻击引起的对栽培植物的损害。

公开(公告)号：US4262012A

公开(公告)日：1981-04-14

申请号：US751918

申请日：1976-12-17

申请人： Ernst Beriger ,  Manfred Boger ,  Jozef Drabek ,  Odd Kristiansen

发明人： Ernst Beriger ,  Manfred Boger ,  Jozef Drabek ,  Odd Kristiansen

IPC分类号： A01N57/10 ,  A01N57/14 ,  A01N57/16 ,  C07F9/12 ,  C07F9/18 ,  A61K31/385 ,  A61K31/39 ,  C07D327/04 ,  C07D339/08

CPC分类号： C07F9/18 ,  A01N57/10

摘要： The invention relates to O,S-dialkyl-O-phenyl-thiophosphates and dithiophosphates of the formula ##STR1## wherein R.sub.1 represents methyl or ethyl,R.sub.2 represents n-propyl, i-butyl or sec.-butyl,R.sub.3 and R.sub.4 each represents hydrogen, chlorine, bromine, methyl or ethyl,R.sub.5 represents a group of the formula ##STR2## X represents oxygen or sulfur, which compounds possess useful pesticidal, in particular acaricidal and insecticidal properties.

摘要翻译： 本发明涉及下式的O，S-二烷基-O-苯基 - 硫代磷酸酯和二硫代磷酸酯，其中R 1表示甲基或乙基，R 2表示正丙基，异丁基或仲丁基，R 3和R 4各自代表 氢，氯，溴，甲基或乙基，R 5表示下式的基团：X表示氧或硫，该化合物具有有用的杀虫剂，特别是杀螨和杀虫性质。

公开(公告)号：US4150160A

公开(公告)日：1979-04-17

申请号：US867651

申请日：1978-01-06

申请人： Jozef Drabek ,  Ernst Beriger ,  Manfred Boger

发明人： Jozef Drabek ,  Ernst Beriger ,  Manfred Boger

IPC分类号： A01N47/34 ,  C07C275/54 ,  C07C275/56 ,  A01N9/20 ,  C07C127/00

CPC分类号： C07C275/56 ,  A01N47/34

摘要： Carbimidocarbonylphenylformamidines of the formula ##STR1## wherein each of R.sub.1 to R.sub.6 represents hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl or cyano, a process for their production and their use in pest control.

摘要翻译： 其中R 1至R 6各自表示氢，卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，三氟甲基或氰基，其生产方法及其在病虫害防治中的用途。

公开(公告)号：US4017612A

公开(公告)日：1977-04-12

申请号：US578960

申请日：1975-05-19

申请人： Ernst Beriger ,  Manfred Boger ,  Jozef Drabek ,  Odd Kristiansen

发明人： Ernst Beriger ,  Manfred Boger ,  Jozef Drabek ,  Odd Kristiansen

IPC分类号： A01N57/10 ,  C07F9/18 ,  A01N9/36

CPC分类号： A01N57/10 ,  C07F9/18

摘要： Thiophosphoric and dithiophosphoric acid esters of the formula ##STR1## wherein R.sub.1 represents methyl or ethyl, R.sub.2 represents n-propyl, isobutyl or sec, butyl, R.sub.3 and R.sub.4 each represents chlorine, bromine, methyl or ethyl, R.sub.5 represents--OCOCH.sub.3, --O--C.sub.3 --C.sub.5 --alkenyl, --O--C.sub.3 --C.sub.5 --alkinyl, --O--C.sub.1 --C.sub.4 --alkylene-O--C.sub.1 --C.sub.4 --alkyl, --O--CH.sub.2 --CCl=CH.sub.2, --O--CH.sub.2 --CH=CHCl, ##STR2## --S--C.sub.3 --C.sub.5 --alkenyl, SCN, --CH.sub.2 --CCl=CH.sub.2, --CH.sub.2 CH=CHCl, --CHO, ##STR3## ##STR4## AND X represents oxygen or sulphur, processes for their manufacture and their use in pest control.

摘要翻译： 其中R 1表示甲基或乙基，R 2表示正丙基，异丁基或仲丁基，R 3和R 4各自表示氯，溴，甲基或乙基，R 5表示-OCOCH 3，-O -C 3 -C 5 - 烯基，-O-C 3 -C 5 - 炔基，-O-C 1 -C 4亚烷基-O-C 1 -C 4烷基，-O-CH 2 -CCl = CH 2，-O-CH 2 -CH = CHCl ，图像-S-C3-C5-烯基，SCN，-CH2-CCl = CH2，-CH2CH = CHCl，-CHO，

公开(公告)号：US3933945A

公开(公告)日：1976-01-20

申请号：US496423

申请日：1974-08-09

申请人： Ernst Beriger

发明人： Ernst Beriger

IPC分类号： A01N57/12 ,  C07F9/16 ,  A01N9/36

CPC分类号： A01N57/12

摘要： S-carbamoylalkyl-O-ethyl-S-(n)-propyldithiophosphoric esters having the formula ##EQU1## wherein R.sub.1 respresents hydrogen, methyl or allyl and R.sub.2 represents --CH.sub.2 OCH.sub.3, --C.sub.2 H.sub.4 OCH.sub.3, --C.sub.3 H.sub.6 OCH.sub.3, --CH.sub.2 CN, C.sub.2 H.sub.4 CH, --OCH.sub.3 or allyl a process for their manufacture and their use in pest control.

摘要翻译： 具有式O C2H5O的S-氨基甲酰基烷基-O-乙基-S-（n） - 丙基二硫代磷酸酯平均值R1 ANGLE PS-CH2-CO-N ANGLE（n）C3H7SR2其中R1表示氢，甲基或烯丙基，R2表示-CH2OCH3， -C 2 H 4 OCH 3，-C 3 H 6 OCH 3，-CH 2 CN，C 2 H 4 CH，-OCH 3或烯丙基，其制备方法及其在害虫防治中的用途。