摘要:
The polycondensation disrupting effects of the impurities in an impure N-dichlorophosphoryltrichlorophosphazene, P.sub.2 NOCl.sub.5, or oligomer thereof, are avoided by polycondensing such impure P.sub.2 NOCl.sub.5 into a high molecular weight uncrosslinked poly(dichlorophosphazene) in the presence of an effective impurity-inhibiting, polymerization-controlling amount of phosphorous pentachloride, PCl.sub.5.
摘要:
The molecular weights of the poly(dichlorophosphazenes), and of the poly(organophosphazenes) produced therefrom, are controlledly regulated by heating such poly(dichlorophosphazenes) in the presence of an effective molecular weight-regulating amount of phosphorus oxychloride.
摘要:
Polychlorophosphazene [Cl.sub.2 (O)P[NPCl.sub.2 ].sub.n Cl] is more rapidly produced by polycondensing N-(dichlorophosphoryl)-trichlorophosphazene [P.sub.2 NOCl.sub.5 ] in the presence of a catalytically effective amount of a tertiary amine.