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1.发明授权Method for treating the radiant tubes of a fired heater in a thermal cracking process 失效在热裂解过程中处理燃烧加热器的辐射管的方法
公开(公告)号：US5656150A
公开(公告)日：1997-08-12
申请号：US296198
申请日：1994-08-25
申请人： Larry E. Reed , Ronald E. Brown , James P. Degraffenried , Timothy P. Murtha , Gil J. Greenwood , Timothy P. Harper , Mark D. Scharre
发明人： Larry E. Reed , Ronald E. Brown , James P. Degraffenried , Timothy P. Murtha , Gil J. Greenwood , Timothy P. Harper , Mark D. Scharre
CPC分类号： C10G9/16 , Y10S585/95
摘要： A novel method for treating the radiant tubes of a fired pyrolysis heater with an antifoulant composition for inhibiting the formation and deposition of coke thereon. Such novel method includes introducing the antifoulant into the crossover conduit between the convection tubes and radiant tubes of the fired pyrolysis heater.
摘要翻译： 一种用于用于防止焦炭在其上形成和沉积的防污组合物来处理燃烧的热解加热器的辐射管的新方法。 这种新方法包括将防污剂引入到燃烧的热解加热器的对流管和辐射管之间的交叉导管中。
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2.发明授权公开(公告)号：US06464858B1
公开(公告)日：2002-10-15
申请号：US08296292
申请日：1994-08-25
申请人： Ronald E. Brown , Larry E. Reed , James P. Degraffenried , Timothy P. Murtha , Gil J. Greenwood , Timothy P. Harper , Mark D. Scharre
发明人： Ronald E. Brown , Larry E. Reed , James P. Degraffenried , Timothy P. Murtha , Gil J. Greenwood , Timothy P. Harper , Mark D. Scharre
IPC分类号： C10G912
CPC分类号： C10G9/203 , C10G9/16 , Y10S585/95
摘要： The incremental yield of hydrocarbons having five or more carbon atoms in a cracked product from a thermal cracking process is increased by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.
摘要翻译： 通过将热裂解炉的管与包含锡和硅的组合物接触或处理，来提高来自热裂解过程的裂化产物中具有五个或更多个碳原子的烃的增量。
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3.发明授权
公开(公告)号：US6056870A
公开(公告)日：2000-05-02
申请号：US296307
申请日：1994-08-25
申请人： Larry E. Reed , Ronald E. Brown , Timothy P. Murtha , Timothy P. Harper , James P. Degraffenried , Mark D. Scharre , Gil J. Greenwood
发明人： Larry E. Reed , Ronald E. Brown , Timothy P. Murtha , Timothy P. Harper , James P. Degraffenried , Mark D. Scharre , Gil J. Greenwood
CPC分类号： C10G9/16 , Y10S585/95
摘要： For a given percentage decomposition, the decomposition temperature of an organosilicon compound is reduced by admixing with the organosilicon compound a decomposition promoting organotin compound. The amount of decomposition promoting organotin compound admixed with the organosilicon compound is sufficient to effectively lower the decomposition temperature of the organosilicon required for a given percentage decomposition.
摘要翻译： 对于给定的百分比分解，通过与有机硅化合物混合分解促进的有机锡化合物来降低有机硅化合物的分解温度。 与有机硅化合物混合的分解促进有机锡化合物的量足以有效降低给定百分比分解所需的有机硅的分解温度。
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4.发明授权
公开(公告)号：US5616236A
公开(公告)日：1997-04-01
申请号：US656796
申请日：1996-05-31
CPC分类号： C10G9/14 , C10G9/16 , C10G2400/20 , Y10S585/95
摘要： The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.
摘要翻译： 通过使用在含有锡化合物，硅化合物和硫化合物的防污剂处理的裂化管中，在热裂解管表面形成碳的速率和烃热裂解过程中的一氧化碳的产生被抑制， 还原气体如氢气。 此外，通过用具有浓度为硫化合物的还原气体处理这种方法的热裂解管，热解裂解过程产物流中的一氧化碳浓度降低。
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5.发明授权
公开(公告)号：US5565087A
公开(公告)日：1996-10-15
申请号：US409292
申请日：1995-03-23
CPC分类号： C10G9/14 , C10G9/16 , C10G2400/20 , Y10S585/95
摘要： The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.
摘要翻译： 通过使用在含有锡化合物，硅化合物和硫化合物的防污剂处理的裂化管中，在热裂解管表面形成碳的速率和烃热裂解过程中的一氧化碳的产生被抑制， 还原气体如氢气。 此外，通过用具有浓度为硫化合物的还原气体处理这种方法的热裂解管，热解裂解过程产物流中的一氧化碳浓度降低。
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公开(公告)号：US5435904A
公开(公告)日：1995-07-25
申请号：US300672
申请日：1994-09-01
IPC分类号： C10G9/16
CPC分类号： C10G9/16
摘要： A method of injecting a liquid tin-containing antifoulant into a saturated hydrocarbon feed stream for a thermal cracking reactor comprises providing a first open-ended tube, a second open-ended tube which concentrically surrounds the first tube, and a third tube which concentrically surrounds the first and second tubes; passing a liquid antifoulant stream through the first tube, a dispersing gas stream through the second tube, and a hydrocarbon gas stream (preferably containing ethane and steam) through the third tube; injecting the liquid antifoulant through the open end of the first tube and the dispersing gas through the open end of the second tube into the hydrocarbon gas stream; and passing the mixture of dispersed antifoulant, dispersing gas and hydrocarbon gas into a thermal cracking reactor.
摘要翻译： 将含液体锡的防污剂注入到用于热裂解反应器的饱和烃进料流中的方法包括提供第一开口管，同心地围绕第一管的第二开口管，以及同心围绕的第三管 第一和第二管; 使液体防污剂流通过第一管，通过第二管的分散气流和通过第三管的烃气流（优选含有乙烷和蒸汽）; 将液体防污剂通过第一管的开口端和分散气体通过第二管的开口端注入烃气流中; 并将分散的防污剂，分散气体和烃气体的混合物通入热裂解反应器中。
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7.发明授权公开(公告)号：US06497809B1
公开(公告)日：2002-12-24
申请号：US08548241
申请日：1995-10-25
IPC分类号： C10G916
摘要： Process for prolonging the effectiveness of a pyrolytic cracking tube which has been treated with an antifoulant for inhibiting the formation of coke during the cracking of hydrocarbons. The benefits of such treatment are enhanced by the desulfurization of a sulfur-containing feedstock prior to charging it to the treated pyrolytic cracking tube.
摘要翻译： 用于延长已经用防污剂处理以在烃裂解期间抑制焦炭形成的热解裂解管的有效性的方法。 在将含硫原料装入处理的热解裂解管之前，通过硫化脱硫来增强这种处理的益处。
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