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公开(公告)号：US5446093A
公开(公告)日：1995-08-29
申请号：US150929
申请日：1993-11-10
IPC分类号： C08G81/02 , C08L53/02 , C08F297/04
CPC分类号： C08G81/022
摘要： A process is disclosed for producing six-armed and eight-armed asymmetric radial block copolymers. The process comprises anionically polymerizing a diene and/or a vinyl aromatic hydrocarbon to create living polydiene and/or vinyl aromatic hydrocarbon arms, sequentially anionically polymerizing a vinyl aromatic hydrocarbon and a diene to create living block copolymer arms and coupling the two sets of arms together in one step with a coupling agent that will couple six or eight arms, wherein the molar ratio of the vinyl aromatic hydrocarbon-diene arms to the polydiene arms is sufficient to produce a statistical blend with less than 5 weight percent homopolydiene.
摘要翻译： 公开了一种用于生产六臂和八臂不对称径向嵌段共聚物的方法。 该方法包括阴离子聚合二烯和/或乙烯基芳烃以产生活性聚二烯和/或乙烯基芳族烃臂，依次阴离子聚合乙烯基芳族烃和二烯以产生活性嵌段共聚物臂并将两组臂结合在一起 在一步中与偶联剂可以连接6或8个臂，其中乙烯基芳族烃 - 二烯臂与聚二烯臂的摩尔比足以产生具有小于5重量％均聚二烯的统计学共混物。
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2.发明授权Dissimilar arm asymmetric radial or star block copolymers for adhesives and sealants 失效用于粘合剂和密封剂的异种臂不对称的径向或星形嵌段共聚物
公开(公告)号：US5393841A
公开(公告)日：1995-02-28
申请号：US149595
申请日：1993-11-09
IPC分类号： C08F8/00 , C08F8/04 , C08F8/08 , C08F8/46 , C08F297/04 , C08L53/02 , C09J153/02
CPC分类号： C08L53/025 , C08F297/044 , C09J153/025 , Y10T428/28 , Y10T428/2839 , Y10T428/2852 , Y10T428/2861 , Y10T428/31855 , Y10T428/31931 , Y10T428/31938
摘要： Radial or star asymmetric block copolymer of the following formulae and improved adhesive and sealant compositions containing them(I) (A--HD).sub.x --Y--(UD).sub.z or (II) (UD--A--HD).sub.x --Y or (III) ((UD).sub.y --A--HD).sub.x --Y--(UD).sub.zwherein A is a vinyl aromatic hydrocarbon block having a molecular weight of from 4000 to 20,000, HD is a hydrogenated conjugated diene block having a molecular weight of from 10,000 to 100,000, Y is a multifunctional coupling agent, UD is an unhydrogenated conjugated diene block having a molecular weight of from 1000 to 80,000, x is an integer from 2 to 20, y is 0 or 1, z is an integer from 1 to 10, and x+z ranges from 3 to 30.
摘要翻译： （I）（A-HD）xY-（UD）z或（II）（UD-A-HD）xY或（III）（（（A-HD））的径向或星形不对称嵌段共聚物， UD）yA-HD）xY-（UD）z其中A是分子量为4000至20,000的乙烯基芳族烃嵌段，HD是分子量为10,000至100,000的氢化共轭二烯嵌段，Y为 多官能偶联剂UD是分子量为1000〜80,000，x为2〜20的整数，y为0或1，z为1〜10的整数，x + z范围的未氢化共轭二烯嵌段 从3到30。
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3.发明授权Dissimilar arm asymmetric radical or star block copolymers for adhesives and sealants 失效用于粘合剂和密封剂的异种臂不对称的径向或星形嵌段共聚物
公开(公告)号：US5486574A
公开(公告)日：1996-01-23
申请号：US336632
申请日：1994-11-09
IPC分类号： C08F8/00 , C08F8/04 , C08F8/08 , C08F8/46 , C08F297/04 , C08L53/02 , C09J153/02
CPC分类号： C08L53/025 , C08F297/044 , C09J153/025 , Y10T428/28 , Y10T428/2839 , Y10T428/2852 , Y10T428/2861 , Y10T428/31855 , Y10T428/31931 , Y10T428/31938
摘要： Radial or star asymmetric block copolymer of the following formulae and an improved tape assembly using the copolymers and improved adhesive and sealant compositions containing them(I) (A--HD).sub.x --Y--(UD).sub.z or (II) (UD--A--HD).sub.x --Y or (lII) ((UD).sub.y --A--HD).sub.x --Y-(UD).sub.z wherein A is a vinyl aromatic hydrocarbon block having a molecular weight of from 4000 to 20,000, HD is a hydrogenated conjugated diene block having a molecular weight of from 10,000 to 100,000, Y is a multifunctional coupling agent, UD is a partially hydrogenated conjugated diene block having a molecular weight of from 1000 to 80,000, x is an integer from 2 to 30, y is 0 or 1, z is an integer from 1 to 20, and x+z ranges from 3 to 30.
摘要翻译： （I）（A-HD）xY-（UD）z或（II）（UD-A-HD）的改进的粘合剂和密封剂组合物 ）xY或（III）（（UD）yA-HD）xY-（UD）z其中A是分子量为4000〜20,000的乙烯基芳烃嵌段，HD是氢化共轭二烯嵌段，其分子量为 Y为多功能偶联剂，UD为分子量为1000〜80,000的部分氢化共轭二烯嵌段，x为2〜30的整数，y为0或1，z为 1〜20，x + z为3〜30。
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4.依法登记的发明Method for preparing asymmetric radial copolymers having two first arms and two second arms 失效制备具有两个第一臂和两个第二臂的不对称径向共聚物的方法
公开(公告)号：USH1464H
公开(公告)日：1995-07-04
申请号：US149596
申请日：1993-11-09
IPC分类号： C08F293/00 , C08C19/44 , C08F297/02 , C08G81/02 , C08L9/00
CPC分类号： C08C19/44 , C08G81/021
摘要： A method for preparing asymmetric radial polymers wherein the different polymeric arms are contacted sequentially with a coupling agent. The method narrows the relative arm distribution of the several asymmetric radial polymers produced and significantly increases the amount of total product having the desired ratio of polymeric arms. Any coupling agent known in the prior art to be useful in the production of asymmetric radial polymers may be used in the method of this invention but coupling agents having from three to about twelve functional groups are most effective.
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5.发明授权Dissimilar arm asymmetric radial or star block copolymers for adhesives and sealants 失效用于粘合剂和密封剂的异种臂不对称的径向或星形嵌段共聚物
公开(公告)号：US5610238A
公开(公告)日：1997-03-11
申请号：US537498
申请日：1995-10-02
IPC分类号： C08F8/00 , C08F8/04 , C08F8/08 , C08F8/46 , C08F297/04 , C08L53/02 , C09J153/02
CPC分类号： C08L53/025 , C08F297/044 , C09J153/025 , Y10T428/28 , Y10T428/2839 , Y10T428/2852 , Y10T428/2861 , Y10T428/31855 , Y10T428/31931 , Y10T428/31938
摘要： Radial or star asymmetric block copolymer of the following formulae and improved adhesive and sealant compositions containing them(I) (A--HD).sub.x --Y--(UD).sub.z or (II) (UD--A--HD).sub.x --Y or (lII) ((UD).sub.y --A--HD).sub.x --Y --(UD).sub.xwherein A is a vinyl aromatic hydrocarbon block having a molecular weight of from 4000 to 20,000, HD is a hydrogenated conjugated diene block having a molecular weight of from 10,000 to 100,000, Y is a multifunctional coupling agent, UD is a partially hydrogenated conjugated diene block having a molecular weight of from 1000 to 80,000, x is an integer from 2 to 30, y is 0 or 1, z is an integer from 1 to 20, and x+z ranges from 3 to 30.
摘要翻译： （I）（A-HD）xY-（UD）z或（II）（UD-A-HD）xY或（IIII）（（（II））的径向或星形不对称嵌段共聚物和改进的粘合剂和密封剂组合物 UD）yA-HD）xY - （UD）x其中A是分子量为4000至20,000的乙烯基芳族烃嵌段，HD是分子量为10,000至100,000的氢化共轭二烯嵌段，Y为 多官能偶联剂UD是分子量为1000〜80,000的部分氢化共轭二烯嵌段，x为2〜30的整数，y为0或1，z为1〜20的整数，x + z 范围从3到30。
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公开(公告)号：US5576395A
公开(公告)日：1996-11-19
申请号：US435067
申请日：1995-05-08
IPC分类号： C08F36/04 , C08F297/02 , C08F297/04 , C09J153/00 , C09J153/02 , C08G81/02
CPC分类号： C08F297/044 , C09J153/02
摘要： A low viscosity adhesive composition which comprises:(a) an asymmetric radial block copolymer of a vinyl aromatic hydrocarbon and at least one conjugated diene having from 3 to 6 polymer arms, which:(i) contains from 33 to 85% by weight of polyvinyl aromatic hydrocarbon block/polydiene block copolymer arms and the balance polydiene homopolymer arms,(ii) has vinyl aromatic hydrocarbon blocks with block molecular weights of from 8000 to 30,000,(iii) has conjugated diene blocks in the copolymer arms with a molecular weight of at least 6000, and(iv) has a polyvinyl aromatic hydrocarbon content of from 10 to 40% by weight; and(b) from 20 to 400 parts per hundred parts of polymer of a tackifying resin.The invention also encompasses the polymers used in the adhesive.
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公开(公告)号：US5550196A
公开(公告)日：1996-08-27
申请号：US336458
申请日：1994-11-09
IPC分类号： C08F36/04 , C08F297/02 , C08F297/04 , C09J153/00 , C09J153/02 , C08G81/02
CPC分类号： C08F297/044 , C09J153/02
摘要： A low viscosity adhesive composition which comprises:(a) an asymmetric radial block copolymer of a vinyl aromatic hydrocarbon and at least one conjugated diene having from 3 to 6 polymer arms, which:(i) contains from 33 to 85% by weight of polyvinyl aromatic hydrocarbon block/polydiene block copolymer arms and the balance polydiene homopolymer arms,(ii) has vinyl aromatic hydrocarbon blocks with block molecular weights of from 8000 to 30,000,(iii) has conjugated diene blocks in the copolymer arms with a molecular weight of at least 6000, and(iv) has a polyvinyl aromatic hydrocarbon content of from 10 to 40% by weight; and(b) from 20 to 400 parts per hundred parts of polymer of a tackifying resin.The invention also encompasses the polymers used in the adhesive.
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8.发明授权Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones 失效通过从官能化聚烯烃骨架生长阴离子聚合物链来制备接枝嵌段共聚物的方法
公开(公告)号：US5543458A
公开(公告)日：1996-08-06
申请号：US381242
申请日：1995-01-31
IPC分类号： C08F8/42 , C08F255/00 , C08F275/00
CPC分类号： C08F275/00 , C08F255/00 , C08F8/42
摘要： A graft block copolymer is comprised of a completely saturated olefinic backbone with pendant anionic polymer side chains. The polymer is produced by copolymerizing an .alpha.-olefin with a monomer which contains a functional group which can be metallated so an anionic monomer can be polymerized therefrom, metallating the copolymer by reaction with metal alkyl or aryl compound and a metallation activator, and growing anionic polymer side chains from the copolymer backbone by reacting an anionically polymerized monomer with the metallated copolymer.
摘要翻译： 接枝嵌段共聚物由具有侧阴离子聚合物侧链的完全饱和的烯属主链组成。 该聚合物是通过使α-烯烃与含有可被金属化的官能团的单体共聚制备的，因此阴离子单体可从其中聚合，通过与金属烷基或芳基化合物和金属化活化剂的反应使共聚物金属化，并且阴离子生长 聚合物侧链通过使阴离子聚合的单体与金属化共聚物反应而由共聚物主链形成。
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公开(公告)号：US5447995A
公开(公告)日：1995-09-05
申请号：US250409
申请日：1994-05-27
IPC分类号： C08F297/02 , C08F297/04 , C08G81/02
CPC分类号： C08F297/044 , C08F297/026 , C08F297/046
摘要： A method for producing asymmetric radial polymers which comprises anionically polymerizing an anionically polymerizable monomer to form a first set of living polymer arms, coupling the first set of living polymer arms with a silicon-based coupling agent, substantially completing the coupling reaction, anionically polymerizing, in the presence of the coupled first set of polymer arms, a different anionically polymerizable monomer(s) to form a second set of living polymer arms, and adding a coupling activator and coupling the second set of living polymer arms to the coupled first set of polymer arms to form the asymmetric radial polymer.
摘要翻译： 一种制备不对称放射状聚合物的方法，其包括阴离子聚合阴离子聚合单体以形成第一组活性聚合物臂，将第一组活性聚合物臂与硅基偶联剂偶联，基本上完成偶联反应，阴离子聚合， 在耦合的第一组聚合物臂的存在下，形成不同的阴离子可聚合单体以形成第二组活性聚合物臂，并加入偶联活化剂并将第二组活性聚合物臂与第一组聚合物臂 聚合物臂形成不对称的径向聚合物。
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10.发明授权Process for making graft block copolymers by grafting anionic polymer chains onto functionalized polyolefins 失效通过将阴离子聚合物链接枝到官能化聚烯烃上制备接枝嵌段共聚物的方法
公开(公告)号：US5550194A
公开(公告)日：1996-08-27
申请号：US381453
申请日：1995-01-31
IPC分类号： C08L87/00 , C08F299/00 , C08G81/02 , C08L101/00 , C08F287/00
CPC分类号： C08G81/021 , C08F299/00
摘要： A graft block copolymer is comprised of a saturated olefinic backbone with pendent anionic polymer side chains. The polymer is produced by copolymerizing an .alpha.--olefin with a 1-alkenyl monomer containing a functional group to which an anionically polymerized polymer can be grafted to produce graft block copolymer, anionically polymerizing at least one anionically polymerizable monomer to form living polymer chains, and then grafting the living polymer chains onto the copolymer to form the graft block copolymer.
摘要翻译： 接枝嵌段共聚物由具有侧链阴离子聚合物侧链的饱和烯烃主链组成。 该聚合物通过使α-烯烃与含有可以接枝阴离子聚合的聚合物的官能团的1-链烯基单体共聚以制备接枝嵌段共聚物，阴离子聚合至少一种阴离子聚合性单体以形成活性聚合物链，以及 然后将活性聚合物链接枝到共聚物上以形成接枝嵌段共聚物。
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