公开(公告)号：US08697292B2

公开(公告)日：2014-04-15

申请号：US13636954

申请日：2011-03-25

申请人： Ryoji Kanno ,  Masaaki Hirayama ,  Yuki Kato ,  Koji Kawamoto ,  Shigenori Hama ,  Takamasa Otomo ,  Kunihiro Nobuhara

发明人： Ryoji Kanno ,  Masaaki Hirayama ,  Yuki Kato ,  Koji Kawamoto ,  Shigenori Hama ,  Takamasa Otomo ,  Kunihiro Nobuhara

IPC分类号： H01M6/18

CPC分类号： C01B25/14 ,  C01B17/20 ,  C01G17/006 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  H01B1/10 ,  H01M10/0562 ,  H01M2300/0068

摘要： The problem of the present invention is to provide a sulfide solid electrolyte material having excellent ion conductivity. The present invention solves the problem by providing a sulfide solid electrolyte material comprising an M1 element (such as a Li element), an M2 element (such as a Ge element and a P element), and an S element; having a peak in a position of 2θ=29.58°±0.50° in an X-ray diffraction measurement using a CuKα line; and having an IB/IA value of less than 0.50 when a diffraction intensity at the peak of 2θ=29.58°±0.50° is represented by IA and a diffraction intensity at a peak of 2θ=27.33°±0.50° is represented by IB.

摘要翻译： 本发明的问题在于提供具有优异的离子传导性的硫化物固体电解质材料。 本发明通过提供包含M1元素（例如Li元素），M2元素（例如Ge元素和P元素）和S元素的硫化物固体电解质材料来解决该问题， 在使用CuKα线的X射线衍射测定中，在2θ的位置具有峰值= 29.58°±0.50°; 并且当IA的峰值处的衍射强度= 29.58°±0.50°时，IB / IA值小于0.50，并且峰值处的衍射强度= 27.33°±0.50°由 IB。

公开(公告)号：US20130040208A1

公开(公告)日：2013-02-14

申请号：US13636954

申请日：2011-03-25

申请人： Ryoji Kanno ,  Masaaki Hirayama ,  Yuki Kato ,  Koji Kawamoto ,  Shigenori Hama ,  Takamasa Otomo ,  Kunihiro Nobuhara

发明人： Ryoji Kanno ,  Masaaki Hirayama ,  Yuki Kato ,  Koji Kawamoto ,  Shigenori Hama ,  Takamasa Otomo ,  Kunihiro Nobuhara

IPC分类号： H01M10/0562

CPC分类号： C01B25/14 ,  C01B17/20 ,  C01G17/006 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  H01B1/10 ,  H01M10/0562 ,  H01M2300/0068

摘要： The problem of the present invention is to provide a sulfide solid electrolyte material having excellent ion conductivity. The present invention solves the problem by providing a sulfide solid electrolyte material comprising an M1 element (such as a Li element), an M2 element (such as a Ge element and a P element), and an S element; having a peak in a position of 2θ=29.58°±0.50° in an X-ray diffraction measurement using a CuKα line; and having an IB/IA value of less than 0.50 when a diffraction intensity at the peak of 2θ=29.58°±0.50° is represented by IA and a diffraction intensity at a peak of 2θ=27.33°±0.50° is represented by IB.

摘要翻译： 本发明的问题在于提供具有优异的离子传导性的硫化物固体电解质材料。 本发明通过提供包含M1元素（例如Li元素），M2元素（例如Ge元素和P元素）和S元素的硫化物固体电解质材料来解决该问题， 在使用CuKα线的X射线衍射测定中，在2θ的位置具有峰值= 29.58°±0.50°; 并且当IA的峰值处的衍射强度= 29.58°±0.50°时，IB / IA值小于0.50，并且峰值处的衍射强度= 27.33°±0.50°由 IB。

公开(公告)号：US20100248086A1

公开(公告)日：2010-09-30

申请号：US12294900

申请日：2007-03-28

申请人： Kunihiro Nobuhara ,  Hideaki Kasai ,  Hiroshi Nakanishi ,  Wilson Agerico Tan Dino

发明人： Kunihiro Nobuhara ,  Hideaki Kasai ,  Hiroshi Nakanishi ,  Wilson Agerico Tan Dino

IPC分类号： H01M4/92 ,  H01M4/36 ,  G06F19/00

CPC分类号： H01M4/86 ,  H01M4/90 ,  H01M4/9041 ,  H01M4/921 ,  H01M4/926 ,  H01M2008/1095

摘要： A method for accurately evaluating the performance of fuel-cell electrode catalysts, a method of search for fuel-cell electrode catalysts having excellent performance, and fuel-cell electrode catalysts having new and excellent catalytic activity searched for by the above method. In a method for evaluating the performance of fuel-cell electrode catalysts composed of conductive carriers on which catalytic metal is supported, the oxygen atom adsorption energy on the catalytic metal surface obtained through a molecular simulation analysis is used as an indicator of the performance evaluation. Suitable catalysts consist of Pt—Au or Pt—Au—B, wherein B is one or more metal chosen from the group of chrome (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), rhodium (Rh) and palladium (Pd) and wherein the content of Au is 6 atom % or less.

摘要翻译： 用于精确评价燃料电池用电极催化剂的性能的方法，具有优异性能的燃料电池用电极催化剂的研究方法以及通过上述方法搜索的具有新的和优异的催化活性的燃料电池用电极催化剂。 在用于评价由其上负载有催化金属的导电载体构成的燃料电池电极催化剂的性能的方法中，使用通过分子模拟分析获得的催化金属表面上的氧原子吸附能力作为性能评估的指标。 合适的催化剂由Pt-Au或Pt-Au-B组成，其中B是一种或多种选自铬（Cr），锰（Mn），铁（Fe），钴（Co），镍（Ni） ，铑（Rh）和钯（Pd），Au的含量为6原子％以下。

公开(公告)号：US20130108924A1

公开(公告)日：2013-05-02

申请号：US13807390

申请日：2011-07-14

申请人： Hideki Nakayama ,  Tomoya Matsunaga ,  Kunihiro Nobuhara ,  Makio Kon

发明人： Hideki Nakayama ,  Tomoya Matsunaga ,  Kunihiro Nobuhara ,  Makio Kon

IPC分类号： H01M4/58 ,  H01M4/38

CPC分类号： H01M4/58 ,  C01B3/0042 ,  H01M4/364 ,  H01M4/38 ,  H01M4/383 ,  H01M4/62 ,  H01M4/625 ,  H01M10/052 ,  Y02E60/327

摘要： An anode material for use in a metal secondary battery contains MgH2, and a metal catalyst which is in contact with the MgH2 and improves the reversibility of a conversion reaction. The metal secondary battery includes a cathode active material layer, an anode active material layer, and an electrolyte layer that is formed between the cathode active material layer and the anode active material layer, and the anode active material layer contains the anode material. A method for the production of an anode material for use in a metal secondary battery includes a contacting step of contacting MgH2 with a metal catalyst which improves the reversibility of a conversion reaction.

摘要翻译： 用于金属二次电池的负极材料包含MgH 2和与MgH 2接触的金属催化剂，并提高转化反应的可逆性。 金属二次电池包括阴极活性物质层，负极活性物质层和形成在正极活性物质层和负极活性物质层之间的电解质层，负极活性物质层含有阳极材料。 用于生产用于金属二次电池的负极材料的方法包括使MgH 2与金属催化剂接触的接触步骤，其提高了转化反应的可逆性。