公开(公告)号：US20230021046A1

公开(公告)日：2023-01-19

申请号：US17778694

申请日：2020-11-05

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Akhlaq MOMAN ,  Vladimir Aleksandrovich ZAKHAROV ,  Sergei Andreevich SERGEEV ,  Artem BARABANOV

IPC: C08F110/06 ,  C08F4/651 ,  C08F4/656

Abstract: The present invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, said process comprising the steps of: Step A) providing or preparing a Grignard compound; Step B) contacting the Grignard compound with a silane compound to give a solid support; Step C) activating said solid support, comprising two sub steps: Step C1) contacting the solid support obtained in step B) with at least one first activating compound and a second activating compound; and Step C2) a second activation step by contacting the partly activated solid support obtained in step C1) with an activating electron donor; to obtain an activated solid support; Step D) reacting the activated solid support obtained in step C) with a halogen-containing Ti compound, optionally an activator and at least one internal electron donor in several sub steps to obtain said procatalyst. The invention moreover relates to a procatalyst, a catalytic system comprising said procatalyst and to a process to prepare polyolefins using said catalyst system and the polyolefins obtained therewith.

公开(公告)号：US20240010759A1

公开(公告)日：2024-01-11

申请号：US18038610

申请日：2021-11-25

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Akhlaq MOMAN ,  Vladimir Aleksandrovich ZAKHAROV ,  Sergei Andreevich SERGEEV ,  Artem A. BARABANOV

IPC: C08F4/50 ,  C08F110/06

CPC classification number: C08F4/50 ,  C08F110/06

Abstract: A process for the preparation of a solid support for a procatalyst for olefin polymerization includes: providing a compound R4zMgX42-z wherein: R4 is independently a linear, branched or cyclic hydrocarbyl independently selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, or combinations thereof; X4 is independently fluoride, chloride, bromide or iodide; and 0

公开(公告)号：US20210292448A1

公开(公告)日：2021-09-23

申请号：US17260669

申请日：2019-07-22

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Henrica Norberta Alberta Maria STEENBAKKERS-MENTING ,  Patrick Elisabeth Luc VOETS ,  Desiree Marie Louise SEEGERS ,  Erik DELSMAN ,  Ibrahim Mohammad ALSUGAL ,  Musaad AL-SADHAN ,  Martin Alexander ZUIDEVELD ,  Akhlaq MOMAN

IPC: C08F210/06 ,  C08F210/02 ,  C08F210/14 ,  F16L9/12

Abstract: The invention relates to a polypropylene composition comprising a terpolymer containing propylene, ethylene and 1-hexene wherein the polypropylene composition (i) has a content of ethylene derived units of at least 1.5 wt %; (ii) has a content of 1-hexene derived units of at least 1.5 wt %; (iii) has a melt flow rate of 0.10 to 0.70 g/10 min determined by ISO 1133-1:2011 (230° C., 2.16 kg); and (iv) has a ratio of weight average molecular weight (Mw) to numeric average molecular (Mn) weight of the terpolymer of 7.0 to 20.0, wherein Mw and Mn are measured according to ASTM D6474-12.