公开(公告)号：US11472895B2

公开(公告)日：2022-10-18

申请号：US17267663

申请日：2019-08-29

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Coen Hendriksen ,  Nicolaas Hendrika Friederichs ,  Jaiprakash Brijlal Sainani ,  Anamitra Chatterjee ,  Vyatcheslav Izmer ,  Dmitry Kononovich ,  Alexander Voskoboynikov ,  Vincenzo Busico ,  Roberta Cipullo ,  Antonio Vittoria ,  Oleg V. Samsonov

IPC: C08F210/16 ,  C08F4/6592 ,  C08F4/659

Abstract: The present invention provides a compound according to formula (I): (I) wherein: •R2 is abridging moiety containing at least one sp2 hybridised carbon atom; •each R4, R4′, R7 and R7′ are hydrogen or moieties comprising 1-10 carbon atoms, wherein each R4, R4′, R7 and R7′ are the same; •each R5, R5′, R6 and R6′ are moieties comprising 1-10 carbon atoms, wherein each R5, R5′, R6 and R6′ are the same; and •Z is a moiety selected from ZrX2, HfX2, or TiX2, wherein X is selected from the group of halogens, alkyls, aryls and aralkyls. Such compound allows for the preparation of catalyst systems that provide improved olefin reactivity, such as ethylene reactivity, increased molecular weight in olefin polymerisation, such as increased Mw in ethylene polymerisation, and increased comonomer incorporation in copolymerisation reactions of olefins, such as in copolymerisation reactions of ethylene with 1-hexene.

公开(公告)号：US12180309B2

公开(公告)日：2024-12-31

申请号：US17622232

申请日：2020-06-23

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Francisco Perez Valencia ,  Coen Hendriksen

IPC: C08L23/06 ,  C08F10/02 ,  C08F210/16 ,  C08F110/02 ,  C08L23/08

Abstract: The invention relates to an ethylene polymer comprising a low molecular weight component and a high molecular weight component, wherein—the ethylene polymer has a density of 955 to 977 kg/m3 and a viscosity value η100 of at most 1500 Pa·s and a strain hardening as determined according to ISO18488 of at least 25 MPa, for example 30 to 40 MPa,—the amount of the low molecular weight component with respect to the total ethylene polymer is at least 60 wt %,—the low molecular weight component has a Mw of 10,000 to 50,000 g/mol, a ratio of Mw/Mn of 2.5 to 4.5 and a density of 965 to 985 kg/m3 and—the high molecular weight component has a Mw of 100,000 to 1,000,000, a ratio of Mw/Mn of 2.5 to 4.0 and a density of 920 to 950 kg/m3.

公开(公告)号：US11691998B2

公开(公告)日：2023-07-04

申请号：US17985254

申请日：2022-11-11

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Coen Hendriksen ,  Nicolaas Hendrika Friederichs ,  Alexander Z. Voskoboynikov ,  Antonio Vittoria ,  Vincenzo Busico ,  Roberta Cipullo ,  Dmitry Y. Mladentsev ,  Bogdan A. Guzeev ,  Dmitry V. Uborsky

IPC: C07F17/00 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/76 ,  C08F10/02

CPC classification number: C07F17/00 ,  C08F4/65927 ,  C08F4/76 ,  C08F10/02 ,  C08F210/16

Abstract: The invention relates to a metallocene complex according to formula (I), (I) wherein R1 and R2 are independently selected from H, an alkyl or an aryl group, wherein R3 is a C1-C10 alkyl group, wherein R′ is selected from H, an alkyl group, an aryl group and wherein different R′ substituents can be connected to form a ring structure and wherein B is a 1,2 phenylene bridging moiety, which can be optionally substituted, wherein Mt is selected from Ti, Zr and Hf, X is an anionic ligand, z is the number of X groups and equals the valence of Mt minus 2. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerisation process of olefinic monomers.

公开(公告)号：US20220363787A1

公开(公告)日：2022-11-17

申请号：US17622232

申请日：2020-06-23

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Francisco Perez Valencia, Sr. ,  Coen Hendriksen

IPC: C08F10/02 ,  C08L23/06

Abstract: The invention relates to an ethylene polymer comprising a low molecular weight component and a high molecular weight component, wherein—the ethylene polymer has a density of 955 to 977 kg/m3 and a viscosity value η100 of at most 1500 Pa·s and a strain hardening as determined according to ISO18488 of at least 25 MPa, for example 30 to 40 MPa,—the amount of the low molecular weight component with respect to the total ethylene polymer is at least 60 wt %,—the low molecular weight component has a Mw of 10,000 to 50,000 g/mol, a ratio of Mw/Mn of 2.5 to 4.5 and a density of 965 to 985 kg/m3 and—the high molecular weight component has a Mw of 100,000 to 1,000,000, a ratio of Mw/Mn of 2.5 to 4.0 and a density of 920 to 950 kg/m3.