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公开(公告)号:US11279824B2
公开(公告)日:2022-03-22
申请号:US16497547
申请日:2018-03-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Eylem Tarkin-Tas , Huseyin Tas
Abstract: A solution of a poly(phenylene ether) copolymer derived from 2-methyl-6-phenylphenol and a dihydric phenol in a non-halogenated solvent is useful in curable compositions. The copolymer has less than 0.5 weight percent monohydric phenols having identical substituents in the 2- and 6-positions of the phenolic ring, and an absolute number average molecular weight of 1,000 to 10,000 grams/mole. A solution of a poly(phenylene ether) copolymer derived from 2-methyl-6-phenylphenol, 2,6-dimethylphenol, and a dihydric phenol in a non-halogenated solvent is also useful in curable compositions. This copolymer has an absolute number average molecular weight of 1,000 to 5,000 grams/mole. A cured composition is obtained by heating curable compositions composed of the poly(phenylene ether) copolymer solutions and thermoset resins for a time and temperature sufficient to evaporate the non-halogenated solvent and effect curing. The compositions can be used for preparation of composites for printed circuit boards.
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公开(公告)号:US20200172729A1
公开(公告)日:2020-06-04
申请号:US16497547
申请日:2018-03-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Eylem Tarkin-Tas , Huseyin Tas
Abstract: A solution of a poly(phenylene ether) copolymer derived from 2-methyl-6-phenylphenol and a dihydric phenol in a non-halogenated solvent is useful in curable compositions. The copolymer has less than 0.5 weight percent monohydric phenols having identical substituents in the 2- and 6-positions of the phenolic ring, and an absolute number average molecular weight of 1,000 to 10,000 grams/mole. A solution of a poly(phenylene ether) copolymer derived from 2-methyl-6-phenylphenol, 2,6-dimethylphenol, and a dihydric phenol in a non-halogenated solvent is also useful in curable compositions. This copolymer has an absolute number average molecular weight of 1,000 to 5,000 grams/mole. A cured composition is obtained by heating curable compositions composed of the poly(phenylene ether) copolymer solutions and thermoset resins for a time and temperature sufficient to evaporate the non-halogenated solvent and effect curing. The compositions can be used for preparation of composites for printed circuit boards.
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公开(公告)号:US20190330424A1
公开(公告)日:2019-10-31
申请号:US16377935
申请日:2019-04-08
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Eylem Tarkin-Tas , Huseyin Tas
Abstract: A phenylene ether oligomer has repeating units of the structure and less than 30 weight percent of repeating units derived from a monohydric phenol having identical substituents in the 2- and 6-positions, wherein the phenylene ether oligomer includes a vinyl benzene ether end group, an amine end group, maleimide end group, a norbornene end group, an anhydride end group, or a combination comprising at least one of the foregoing. The phenylene ether oligomer can be used to provide a curable composition. The curable composition can be cured to provide a thermoset composition. Articles comprising the thermoset composition are also described.
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公开(公告)号:US11505699B2
公开(公告)日:2022-11-22
申请号:US16434715
申请日:2019-06-07
Applicant: SABIC Global Technologies B.V
Inventor: Huseyin Tas , Eylem Tarkin-Tas , Alvaro Carrillo
IPC: C08L71/12 , C08G65/44 , C09D171/12 , C09J171/12 , C09K3/10 , C08J5/24 , C08G101/00
Abstract: A poly(arylene ether) copolymer is the product of oxidative copolymerization of monomers including a monohydric phenol and a dihydric phenol of the formula wherein R3, R4, R5, and R6 are as defined herein. The poly(arylene ether) copolymer includes less than 0.1 weight percent of incorporated amine groups. A method of the manufacture of a poly(arylene ether) copolymer is also disclosed. A curable composition including the poly(arylene ether) copolymer and cured products derived therefrom are also described.
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公开(公告)号:US10662288B2
公开(公告)日:2020-05-26
申请号:US16255470
申请日:2019-01-23
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Eylem Tarkin-Tas , Huseyin Tas
Abstract: A capped poly(arylene ether) copolymer having the formula wherein Y is a divalent linking group of the formula each occurrence of D is independently a group of the formula each occurrence of Z is independently of the formula and Q1a, Q1b, R1, R2, R3, R4, R5, z, x, y, e, Ra, Rb, Rc, Rd, Re, Wa, R, R′, and m are as defined herein.
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公开(公告)号:US10995182B2
公开(公告)日:2021-05-04
申请号:US16377935
申请日:2019-04-08
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Eylem Tarkin-Tas , Huseyin Tas
Abstract: A phenylene ether oligomer has repeating units of the structure and less than 30 weight percent of repeating units derived from a monohydric phenol having identical substituents in the 2- and 6-positions, wherein the phenylene ether oligomer includes a vinyl benzene ether end group, an amine end group, maleimide end group, a norbornene end group, an anhydride end group, or a combination comprising at least one of the foregoing. The phenylene ether oligomer can be used to provide a curable composition. The curable composition can be cured to provide a thermoset composition. Articles comprising the thermoset composition are also described.
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公开(公告)号:US20190225748A1
公开(公告)日:2019-07-25
申请号:US16255470
申请日:2019-01-23
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Eylem Tarkin-Tas , Huseyin Tas
Abstract: A capped poly(arylene ether) copolymer having the formula wherein Y is a divalent linking group of the formula each occurrence of D is independently a group of the formula each occurrence of Z is independently of the formula and Q1a, Q1b, R1, R2, R3, R4, R5, z, x, y, e, Ra, Rb, Rc, Rd, Re, Wa, R, R′, and m are as defined herein.
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