摘要:
The invention relates to a catalyst for olefin polymerization represented by the general formula (1): wherein; M is a transition metal; X1 and X2 are independently selected from the group consisting of halide, alkyl group, aryl group, alkyl amine group, or alkyl aryl group, and are directly bond to M, R1 and R2 are independently selected from the group consisting of hydrogen, alkyl group or aryl group; and Cp is a cyclopentadienyl group.
摘要翻译:本发明涉及由通式(1)表示的用于烯烃聚合的催化剂:其中: M是过渡金属; X 1和X 2独立地选自卤素,烷基,芳基,烷基胺基或烷基芳基,并且直接与M键合,R 1和R 2独立地选自氢,烷基 或芳基; Cp是环戊二烯基。
摘要:
The invention relates to a catalyst for olefin polymerization represented by the general formula (1): wherein; M is a transition metal; X1 and X2 are independently selected from the group consisting of halide, alkyl group, aryl group, alkyl amine group, or alkyl aryl group, and are directly bond to M, R1 and R2 are independently selected from the group consisting of hydrogen, alkyl group or aryl group; and Cp is a cyclopentadienyl group. R1R2C═N—OMCPX1X2 (I)
摘要翻译:本发明涉及由通式(I)表示的烯烃聚合催化剂:ƒ€ƒ€ƒ€ƒ€ƒR 1 R 2 C = N-OMC P X 1 X 2其中; M是过渡金属; X 1和X 2独立地选自卤素,烷基,芳基,烷基胺基或烷基芳基,并且直接与M键合,R 1和R 2独立地选自 氢,烷基或芳基; Cp是环戊二烯基。
摘要:
Unsymmetrical metallocene compounds based on cyclopentadienyl ligands are disclosed, as well as catalytic compositions comprising the compounds supported on solid support materials. The compounds and compositions are useful as catalysts in the polymerisation of olefins. In particular, the compounds and compositions are useful catalysts in the preparation of low molecular weight polyethylene (e.g. polyethylene wax) and copolymers formed from the polymerisation of ethylene and other α-olefins.
摘要:
The present invention relates to a process for the preparation of a polyethylene wax, the process comprising the steps of providing a catalyst solution, wherein the catalyst solution comprises at least one activating compound, an alkylaluminoxane and a me-tallocene complex, wherein the molar ratio of the activating compound to aluminum comprised in the alkylaluminoxane is from 0.0005 to 0.20; and polymerizing ethylene, by contacting the ethylene and the catalyst solution.